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In the present research, glass and basalt fiber-reinforced polypropylene composites' behaviour in quasi-static and dynamic conditions is studied. Composites were fabricated by vacuum assisted Compression molding method. Composites failure under quasi-static tension and compressive conditions was studied along with its failure behaviour under low-velocity impact and super-sonic shock loading under dynamic conditions. The study results showed that basalt fiber-reinforced polypropylene (Basalt/PP) composite's tensile and compressive strength is higher than glass fiber-reinforced polypropylene (Glass/PP). The Basalt/PP showed no penetration against low velocity impact (LVI) with negligible deformations till 50 J. However, the Glass/PP perforated at 50 J with various failure patterns occurring at back side. The fiber-matrix interface adhesion plays an important role in super-sonic shock loading by absorbing shock wave energy due to ductile nature of polypropylene and the two composites absorbed energy via matrix and fibers failure, no brittle failure of laminates occurred under shock loading. [ABSTRACT FROM AUTHOR]

Abstract: In this second part of a two-part paper, the failure mechanism of polypropylene (PP)/nanoclay composite under fracture loads is presented. The PP/nanoclay composite was prepared via melt compounding in a twin-screw extruder. Maleic anhydride grafted polypropylene (MA-g-PP) was used as a compatibilizer to improve the dispersability of the clay. The PP/clay nanocomposite was characterized by XRD and SEM. XRD results show possibilities of exfoliation, and SEM studies rule out large-scale particle agglomeration. Fractographic observations of PP/clay nanocomposite at lower loading rates reveal that excessive fibrillation and impregnated fibrils arrest crack propagation, and the fracture occurs by void initiation at larger clay particles. As the loading rate increases, crazes combined with voids to accelerate crack propagation. At higher loading rates, cleavage type brittle fracture is observed. [Copyright &y& Elsevier]

Abstract: Polypropylene (PP)/Montmorillonite (MMT) nanoclay based composite was prepared by melt compounding with maleic anhydride grafted polypropylene (MA-g-PP) as a compatibilizer in a twin-screw extruder, and the test specimens were injection molded. Mechanical properties such as tensile modulus, flexural modulus, yield strength and maximum percent strains were measured for pure PP and PP based nanocomposite to establish the effect of clay platelet reinforcement. The fracture properties were measured by using the essential work of fracture (EWF) method. PP/clay nanocomposite shows 25% improvement in specific EWF compared to pure PP. The variation of EWF parameters with loading rate is discussed, whilst the mechanisms of fracture are considered in a subsequent paper. [Copyright &y& Elsevier]

In this study, the influence of hybridization on the compression response of thermoplastic matrix-based composites under high strain rate loading was investigated. The intra-ply and inter-ply hybrid composites were manufactured with Kevlar/Basalt yarns as the reinforcements with Polypropylene as a matrix. Cylindrical composite specimens were laser cut from the flat compression moulded laminates. The composite specimens were loaded under high strain rate using split-Hopkinson pressure bar setup at strain rates ranging from 2815/s to 5481/s. The study revealed differences in the rate-dependent growth of peak stress, peak strain and toughness with the strain rate. Intra-ply hybrid composites with alternate weaving of Kevlar and basalt yarns exhibited highest peak stress as compared to the Inter-ply hybrid composites (alternate layers of Kevlar and basalt fabrics) and another intra-ply composite containing Kevlar in the warp and basalt in the weft direction. Whereas in inter-ply hybrid composite, with Kevlar as the loading face attained higher stress, while composite with Basalt as the loading face attained higher strain. SEM micrographs revealed that Kevlar on the loading face can bear the impact with lesser delamination as compared to the Basalt on the loading face. Damage studies revealed that Kevlar fiber surface loading results in higher stress as compared to basalt (brittle) surface loading with lower overall damage. • The influence of hybization on the high strain rate resposne of thermoplastic composites. • Intra-ply hybridization excels over inter-ply hybridization. • Placement and direction of yarns is crucial in intra-ply hybridization. • Higher areal density fabrics are replacable with hybrid fabrics of lower areal density. [ABSTRACT FROM AUTHOR]

This paper presented an experimental and numerical investigation on the low velocity impact response of thermoplastic hybrid composites reinforced with Kevlar/basalt fabrics. Two hybrid and one Kevlar homogeneous composite laminates were manufactured with polypropylene as a resin. In the hybrid composites, one hybrid composite (H-1) was manufactured with alternate stacking of four layers of basalt and four layers of Kevlar and the second hybrid composite (H-2) was manufactured with four Kevlar layers on front face and four basalt layers on back face. Low velocity impact tests were performed using a drop-weight impact equipment at three different energies (25J, 50J and 75J). Among the two hybrid composites H-1 hybrid composite exhibited 15.58-20.79% and 13.47-20.47% improvement in the peak force and energy absorption, respectively, than the H-2 hybrid composite. The peak force and energy absorption of Kevlar homogeneous composite was also improved by 10.07-14.37% and 5.38-11.29%, respectively, due to hybridization. A three dimensional (3D) dynamic finite element software, Abaqus/Explicit, was implemented to simulate the experimental results of low velocity impact tests. A user-defined material subroutine (VUMAT) based on Chang-Chang linear-orthotropic damage model was implemented into the finite element code. The predictions from numerical simulation were found to be in good agreement with the experimental results. [ABSTRACT FROM AUTHOR]

As a major challenge, development of light-weight fibre reinforced polymer (FRP) composite body armour, characterization of candidate matrix polymers at high strain rate impact is the focus in this research. Polypropylene (PP) and the nano-composites with 1-5% by weight of NC (nanoclay) platelets are the candidates considered. In the characterization phase, high strain rate impact and quasi-static loading tests were performed to figure out the limiting (failure) responses. Comparison between the material systems is, subsequently, made to nominate one matrix configuration. Enhancements of mechanical properties with increase in weight percentage of the nanoparticles are observed at both quasi-static and dynamic loadings. Observations of dispersed imposed failure modes, development of novel model for failure modulus and evaluation of peak strength values are also attempted. [ABSTRACT FROM AUTHOR]

In the present work, dynamic compression response of polypropylene (PP) based composites reinforced with Kevlar/Basalt fabrics was investigated. Two homogeneous fabrics with Kevlar (K3D) and Basalt (B3D) yarns and one hybrid (H3D) fabric with a combination of Kevlar/Basalt yarns were produced. The architecture of the fabrics was three-dimensional angle-interlock (3D-A). Three different composite laminates were manufactured using vacuum-assisted compression molding technique. The high strain rate compression loading was applied using a Split-Hopkinson Pressure Bar (SHPB) set-up at a strain rate regime of 3633–5235/s. The results indicated that the dynamic compression properties of thermoplastic 3D-A composites are strain rate sensitive. In all the composites, the peak stress, toughness and modulus were increased with strain rate. However, the strain at peak stress of Basalt reinforced composites (B3D, H3D) decreased approximately by 25%, while for K3D specimens it increased approximately by 15%. The K3D composites had a higher strain rate as compared to the B3D and H3D composites. In the case of K3D composite, except strain at peak stress, remaining dynamic properties were lower than the B3D composite, however, hybridization increased these properties. The failure mechanisms of 3D-A composites were characterized through macroscopic and scanning electron microscopy (SEM). [ABSTRACT FROM AUTHOR]

Kevlar ® fabric reinforced plastics (KFRPs) are specialized composites with multiple layers of fabrics (∼ranging from 20 to 50 layers) designed for high impact applications. In this work, Kevlar-129 fiber was reinforced with polyetherimide (PEI) and polypropylene (PP) to obtain two groups of laminates in three configurations i.e. 16, 24 and 30 layers. Holes of diameter 11.6 mm were profile cut using fiber laser machining system operating at 1070 nm wavelength. Effects of polymeric matrix on the failure of the Kevlar – polyetherimide (K-PEI) and Kevlar – polypropylene (K-PP) laminates were characterized by studying the following: (i) threshold laser power required to make the holes (ii) surface morphology using scanning electron microscopy (iii) damage zone along the laser cut path using scanning acoustic microscopy and optical microscopy. K-PEI laminates underwent material separation at much lesser line energy (ratio of laser power to velocity) than K-PP laminates during laser machining. Scanning electron microscopy (SEM) was used to further analyze the laser cut surfaces. A prominent observation on the laser-irradiated surface was: less recast/resolidified polymer covered the Kevlar fabric in K-PEI as compared to a thicker polymeric layer in K-PP. Heat affected zone and damage factors were evaluated using scanning acoustic microscopy (SAM). Surface roughness and kerf width were also analyzed to understand the effect of laser machining of Kevlar laminates. [ABSTRACT FROM AUTHOR]

The present work reported the mechanical characterization of novel polypropylene (PP) composites reinforced with three-dimensional angle-interlock (3D-A) Kevlar/basalt fabrics. Two homogeneous fabrics with Kevlar (K3D) and basalt yarns (B3D), and a hybrid fabric (H3D) with a combination of both Kevlar and basalt yarns were produced. Three types of two layer 3D-A composites were manufactured using vacuum-assisted compression molding method. Static tensile and in-plane compression tests were carried out on the manufactured composites. The mechanical behavior of the three 3D-A composites was compared in terms of stress-strain response, elastic modulus, strength and failure strain. Influence of hybridization on the mechanical behavior of the 3D-A composites was also studied. Significant improvement in the tensile behavior of 3D-A homogeneous composites was observed due to hybridization. Meanwhile, there was no considerable improvement in in-plane compression behavior. The damage patterns for in-plane compression loading were examined through scanning electron microscopy (SEM) to explore the possible damage patterns such as matrix cracking, fiber failure, delamination and deformation. Numerical simulations were carried out using ABAQUS/Standard, by implementing a user-defined material subroutine (VUMAT) based on the Chang-Chang linear orthotropic damage model. Good agreement between experimental and numerical simulations was achieved in terms of damage patterns. [ABSTRACT FROM AUTHOR]

Experimental and numerical investigations are carried out to determine the low velocity impact (LVI) response of three different polypropylene (PP) composites. Three dimensional (3D) angle-interlock fabrics with Kevlar, basalt and a hybrid combination of both are produced. 3D composites are manufactured with these three fabrics using vacuum-assisted compression molding process with PP resin. LVI tests are conducted using a drop-weight impact equipment at the energy level of 240 J. The LVI response of the three 3D-PP composites is compared in terms of peak force, energy absorption and damage modes. The experimental results indicate that the basalt 3D composites showed 6.62–13.73% higher peak force and H3D composites absorbed 7.67-48.49% more energy than the remaining composites. Results indicate that there is a considerable enhancement in the energy absorbing capability of hybrid composites as compared to Kevlar/PP and basalt/PP composites. Numerical simulations are carried out using the commercial finite element (FE) code ABAQUS/Explicit. A user-defined material subroutine (VUMAT) based on Chang-Chang linear orthotropic damage model, is implemented into the FE code. Good agreement between experimental and numerical simulations is achieved in terms of impact response characteristics. [ABSTRACT FROM AUTHOR]

In this study, low velocity impact (LVI) behaviors of composite laminates reinforced with fabrics of different architecture are investigated. Three kinds of fabric architecture, namely, two-dimensional plain woven (2D-P), three-dimensional orthogonal (3D-O) and three-dimensional angle interlock (3D-A), are prepared with Kevlar 29 (Kevlar) yarns. Composite laminates are manufactured with Kevlar fabrics and polypropylene (PP) resin. These composites are impact tested at 4 m/s and 6 m/s impact velocities. The post-impact response of the composites of different fabric architecture is studied. The results revealed that the impact resistance is mainly dependent on the in-plane stiffness of the laminates. The energy absorption ability is predominantly influenced by the existence of yarns in the thickness direction. The 3D composites absorbed 14–26% higher energy than the 2D laminates. Especially, 3D-A laminates exhibited a higher peak load (14.21–30.25%), more energy absorption (12.7–26.2%) and lower cone formation at the back of the target (25–39%) as compared to 3D-O and 2D-P composites. [ABSTRACT FROM AUTHOR]

The ballistic impact response of thermoplastic-based composite armors made from Kevlar ® fabric and polypropylene (PP) matrix has been investigated against ballistic test standard NIJ-STD 0106.01 Type IIIA. Kevlar ® fabrics of different architectures, namely 2D plain woven, 3D orthogonal and 3D angle interlock fabrics, were produced and used as reinforcements to fabricate composite armor panels, using compression molding technology. Interfacial property between PP and Kevlar ® was improved by adding a coupling agent called maleic anhydride grafted PP. Reduced density was observed in Kevlar ® thermoplastic-based composites as compared to that of the thermoset-based laminates. Ballistic impact tests were imparted with 9 mm full metal jacket (FMJ) on armor panels having different fabric architecture. Ballistic test results revealed that 2D armor was 2.4–7% more susceptible to damage than 3D armors. Hydrocode simulations were carried out using ANSYS AUTODYN v. 14.0 to obtain an estimate for the ballistic limit velocity and simulate failure modes. Post-impact damage patterns obtained from the simulations were compared with the experimental results to assess the performance of the simulations. Good correlation between the hydrocode simulations and experiments was found, both in terms of failure modes and damage patterns. 3D composite armors were able to confront the 9 mm FMJ projectile; however, the 2D plain woven armors failed. The increase in the ballistic limit from 2D plain woven armor to 3D orthogonal and 3D angle interlock armors was 16.44% and 20%, respectively, indicating the effect of fabric architecture. [ABSTRACT FROM AUTHOR]

Abstract Nanocomposites with platelet reinforcements are emergent materials whose deformation mechanisms still need to be carefully investigated. In this study, we first present the studied class of nanocomposites (Polypropylene reinforced by Montmorillonite clay nanoplatelets). From uniaxial tensile tests, it is shown that some mechanical characteristics of the nanocomposite (Young's modulus, yield stress) significantly increase compared to the matrix even for very low volume fraction of reinforcements (maximum of 7% mass fraction for our tested specimen). The Ponte Castañeda and Willis [6] bound is adopted to account for the evolution of the elastic behavior of the material [71. Adapting the Hill-type incremental method [13] allows the simulation of the non linear behaviour of the material. However, it is shown that this scheme requires careful choice of the aspect ratio, in the plastic domain, to provide good predictions of plasticity. [ABSTRACT FROM AUTHOR]