1. Using 69/71Ga solid-state NMR and 127I NQR as probes to elucidate the composition of “GaI”
- Author
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Widdifield, Cory M., Jurca, Titel, Richeson, Darrin S., and Bryce, David L.
- Subjects
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GALLIUM compounds , *NUCLEAR magnetic resonance spectroscopy , *SOLID state chemistry , *NUCLEAR quadrupole resonance spectroscopy , *REACTIVITY (Chemistry) , *IODIDES , *MAGNETIC fields - Abstract
Abstract: While the synthetic utility and reactivity of the so-called “GaI” species is reasonably well established, its exact composition remains unknown. Using primarily multinuclear magnetic resonance techniques (and supported with powder X-ray diffraction measurements), we offer some new insights into the composition of “GaI”. Using 127I nuclear quadrupole resonance (NQR) experiments, it is clearly demonstrated that gallium diiodide (GaI2) is a significant component of this material, while GaI3 is not. This finding is in contrast with a prior literature account, which noted that Ga2I3 (i.e., one equivalent of GaI3 per equivalent of Ga metal) was present in significant amounts. Additional solid-state nuclear magnetic resonance (SSNMR) experiments using the 69/71Ga probe nuclei in multiple magnetic fields clearly establish, via its diagnostic Knight-shifted resonance, the presence of Ga0 metal, which is in agreement with prior literature. Taken together, a composition may be tentatively offered: that “GaI” is, to a large extent, two equivalents of Ga0 metal with two equivalents of GaI2, where the latter is composed of Ga+ and ions. This composition may be represented as [Ga0]2[Ga]+[GaI4]−. [Copyright &y& Elsevier]
- Published
- 2012
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