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By using a perturbation approach, we investigate dynamic effects on nonlinear alternating current (ac) responses in electrorheological (ER) fluids under an ac or a direct current electric field. We show that the dynamic effect due to a shear flow plays a significant role in the responses. Our results can be well interpreted in the dielectric dispersion spectral representation, and they offer a convenient method to determine the relaxation time and rotation velocity of ER particles by measuring the nonlinear ac responses. [ABSTRACT FROM AUTHOR]

Particle rotation leads to a steady-state which is different from the equilibrium state in the absence of rotational motion. The change of the polarization of the particle due to the rotational motion is called the dynamic electrorheological effect (DER). There are three cases to be considered: rotating particles in a dc field, particle rotation due to a rotating field and spontaneous rotation of particle in dc field (Quincke rotation). In the DER of rotating particles, the particle rotational motion generally reduces the interparticle force between the particles. The effect becomes pronounced when the frequency is on the order of the relaxation rate of the surface charges. In the electrorotation of particles, the mutual interaction between approaching particles will change the electrorotation spectrum significantly. The electrorotation spectrum depends strongly on the medium conductivity as well as the conductivity contrast between the particle and the medium. In the collective behaviors of Quincke rotors, the mutual interactions between the individual rotors lead to the assembly of chain-like structures which make an angle with the applied field. This has an implication of a new class of material. [ABSTRACT FROM AUTHOR]

To understand the dynamic rheological behavior of polar molecular electrorheological (PMER) fluids, the shear stress and viscosity of the colloids are compared with the parameters of their lamellar structures which are obtained simultaneously with the rheological characteristics using an electrorheoscope. The results of the experiments and molecular dynamics simulation indicate that the shear stress is mainly contributed by the moving particle rings, and there is an inverse correlation between the width of the moving particle rings and the shear stress. [ABSTRACT FROM AUTHOR]