1. Post-crosslinking of triptycene-based Tröger's base polymers with enhanced natural gas separation performance.
- Author
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Zhang, Caili, Fu, Linxiang, Tian, Zhikang, Cao, Bing, and Li, Pei
- Subjects
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TRIPTYCENES , *CROSSLINKING (Polymerization) , *SEPARATION of gases , *NATURAL gas , *DIAMINES , *CHEMICAL synthesis , *CARBOXYLIC acids - Abstract
A novel triptycene-based diamine, 2,6-diaminotriptycene-14-carboxylic acid, was synthesized and used for preparing carboxylic acid containing triptycene-based Tröger's base copolymers, CoPIM-TB-1 and CoPIM-TB-2, with another diamine monomer, 2,6-diaminotriptycene. The copolymers were subsequently post - crosslinked by glycidol to form C-CoPIM-TB-1 and C-CoPIM-TB-2. Glycidol crosslinking greatly impeded inter-chain mobility of the triptycene-based copolymers and subsequently restricted both physical aging rate and CO 2 induced plasticization. Gas permeabilities of 40 days old C-CoPIM-TB-2 film decreased by 7%, 5%, and 9%, to gases H 2 , CO 2 , and O 2 , respectively, which were slower than those of the uncrosslinked PIM-Trip-TB polymer of which permeabilities decreased by 21%, 42%, and 30%, respectively. Mixed gas permeation results showed no CO 2 induced plasticization at a CO 2 partial pressure up to 20 atm. Moreover, separation performance of C-CoPIM-TB-1 and C-CoPIM-TB-2 went over the Robeson 2008 upper bounds for gas pairs including O 2 /N 2 , CO 2 /CH 4 , CO 2 /N 2 and H 2 /N 2 . All these results indicated a great potential for the post-crosslinked Triptycene-Based Tröger's Base polymers for natural gas sweetening. [ABSTRACT FROM AUTHOR]
- Published
- 2018
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