1. Microstructure and formation mechanism in a surface carburized tungsten heavy alloy.
- Author
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Hu, Ke, Wang, Guanghong, Li, Xiaoqiang, and Qu, Shengguan
- Subjects
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TUNGSTEN alloys , *TUNGSTEN , *CRYSTAL lattices , *MICROSTRUCTURE , *CARBURIZATION , *MICROPORES , *GRAIN - Abstract
Abstract A 95W–3.5Ni–1.0Fe–0.5Co heavy alloy was surface modified by pack carburization. A new carburized layer consisting of outside surface layer and inner surface layer was formed. The double layered microstructure showed porous WC aggregates in the outside surface layer and W grains coated by shell-like (Ni, Co, Fe) 6 W 6 C carbides in the inner surface layer. There were two paths for C atoms diffusion and reaction through W grains and matrix phase. Co changed the formation orders of carbides and acted as a medium for promoting C atoms reaction with Ni, Fe, Co and W in the matrix to form shell-like (Ni, Co, Fe) 6 W 6 C carbides in the inner surface layer. Meanwhile, C atoms diffused in the W grains and reacted with W in an order of W→W 2 C→WC. WC nucleated and grew in carburized W grains and micropores produced in the growing WC crystals due to the lattice expansion from W→W 2 C→WC. As the carburization process continued, the shell-like (Ni, Co, Fe) 6 W 6 C carbide was also carburized to WC, and finally the whole W grain was carburized into porous WC aggregates in the outside surface layer. Graphical abstract Image 1 Highlights • A pack carburized 95W–3.5Ni–1.0Fe–0.5Co heavy alloy was characterized using XRD, SEM, EPMA and TEM. • A new carburized layer consisting of outside surface layer and inner surface layer was formed. • Porous WC aggregates formed in the outside surface layer. • W grains coated by shell-like (Ni, Co, Fe) 6 W 6 C carbides were obtained in the inner surface layer. • The new carburized microstructure was found to be related to the Co addition. [ABSTRACT FROM AUTHOR]
- Published
- 2019
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