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Near‐infrared (NIR) luminescence of Pr3+ and Tm3+ ions in titanate‐germanate glasses has been studied for laser and fiber amplifier applications. The effect of the molar ratio GeO2:TiO2 (from 5:1 to 1:5) on spectroscopic properties of glass systems was studied by absorption, luminescence measurements, and theoretical calculations using the Judd–Ofelt theory. It was found that independent of the TiO2 concentration, intense NIR emissions at 1.5 and 1.8 μm were observed for glasses doped with Pr3+ and Tm3+ ions, respectively. Moreover, several spectroscopic and NIR laser parameters for Pr3+ and Tm3+ ions, such as emission bandwidth, stimulated emission cross‐section, quantum efficiency, gain bandwidth, and figure of merit, were determined. The results were discussed in detail and compared to the different laser glasses. Systematic investigations indicate that Pr3+‐doped system with GeO2:TiO2 = 2:1 and Tm3+‐doped glass with GeO2:TiO2 = 1:2 present profit laser parameters and could be successfully applied to NIR lasers and broadband optical amplifiers. [ABSTRACT FROM AUTHOR]

The near-infrared luminescence properties of Pr3+/Yb3+: PLZT ferroelectric ceramics have been examined for the first time. Independently, upon either 450 nm (Pr3+) or 980 nm (Yb3+) excitation, luminescence centered at 1340 nm was observed, which corresponds to the 1G4→3H5 transition of Pr3+. Several spectroscopic parameters for the 1G4→3H5 transition of Pr3+ ions were determined. The average product of emission cross section and radiative lifetime were relatively large for all x/65/35 PLZT samples ( x=6-10) studied, with values close to 105±2 (×10−26 cm2·s). These spectroscopic investigations indicate that Pr3+/Yb3+: PLZT ferroelectric ceramics are promising candidate for efficient sources emitting near-infrared radiation at 1340 nm. [ABSTRACT FROM AUTHOR]