1. Microcrystalline cellulose and by-products from the pulp and paper industry as reinforcing fibres for polybutylene succinate-based composites: A comparative study.
- Author
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Sousa, Francisco JPM, Jesus, Carolina F, Góis, Joana R, Pereira, Nelson AM, and Antunes, Filipe E
- Subjects
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SEWAGE disposal plants , *CHEMICAL purification , *MODULUS of elasticity , *PAPER industry , *CIRCULAR economy - Abstract
This study focussed on the development of fully biodegradable composites based on polybutylene succinate (PBS) in combination with raw materials from different processing stages of the pulp and paper industry. Sulfite pulp (SP), kraft pulp (KP) and screened sludge residue (SL) from wastewater treatment plants (WWTP) were investigated as reinforcing fibres contributing to a circular economy. We report a comparative study of the physicochemical properties and mechanical performance of PBS composites reinforced with these cellulosic raw fibres and commercial pure microcrystalline cellulose (MC). The composites were characterised in tensile strength, elongation at break, modulus of elasticity, water absorption and wettability. The incorporation of the fibres into the polymer matrix was also investigated using torque rheometry. Critical concentrations were obtained with maximum incorporation in the range of 15–20 wt% for SP/KP and 25–30 wt% for SL. SP and KP composites showed at least as good physicochemical and mechanical properties as MC at the concentrations studied (0–20 wt%). SP-composites showed the highest tensile strength and modulus of elasticity. It was shown that these fibres from the pulp and paper industry can be used as reinforcement for PBS matrices without additional chemical purification and provide a valuable alternative to commercial microcrystalline cellulose. [ABSTRACT FROM AUTHOR]
- Published
- 2024
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