Search

Your search keyword '"Yakovenko, Andrey"' showing total 1 results
Start Over Author "Yakovenko, Andrey" Topic gas absorption & adsorption Topic metal-organic frameworks Database Academic Search Index Publisher royal society of chemistry

Refine your results

1 results on '"Yakovenko, Andrey"'

1. Selective gas adsorption and unique phase transition properties in a stable magnesium metal-organic framework constructed from infinite metal chains.

Author

Liu, Yangyang, Chen, Ying-Pin, Liu, Tian-Fu, Yakovenko, Andrey A., Raiff, Aaron M., and Zhou, Hong-Cai

Subjects
*METAL-organic frameworks, *MAGNESIUM, *GAS absorption & adsorption, *PHASE transitions, *THERMAL expansion, *X-ray diffraction
Abstract

A 3D Magnesium MOF PCN-72 has been synthesized from the solvothermal reaction of Mg(NO3)2 and a linear ligand. This MOF has a unique structure with 1-dimensional (1D) channel as well as infinite metal chains, which resembles the topology of MIL-53. It is thermally and moisture stable. In situ powder X-ray diffraction studies reveal its interesting phase transitions under temperature change. Calculation shows that each phase of PCN-72 exhibits unique and unusual thermal expansion properties. After removing coordinated solvent at Mg chains, PCN-72 can selectively adsorb CO2 over N2. [ABSTRACT FROM AUTHOR]

Published
2013
Full Text
View/download PDF

Catalog

Books, media, physical & digital resources
See catalog results