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Start Over Author "Yakovenko, Andrey" Topic anthracene derivatives Database Academic Search Index Publisher royal society of chemistry

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1 results on '"Yakovenko, Andrey"'

1. Sensitized photon upconversion in anthracene-based zirconium metal–organic frameworks.

Author

Rowe, Jennifer M., Zhu, Jie, Soderstrom, Erin M., Xu, Wenqian, Yakovenko, Andrey, and Morris, Amanda J.

Subjects
*PHOTON upconversion, *ANTHRACENE derivatives, *ZIRCONIUM compounds, *METAL-organic frameworks, *FLUORESCENCE
Abstract

Sensitized upconversion is explored in three metal–organic frameworks (MOFs) constructed from the anthracene dicarboxylate (ADC) derivatives and zirconium nodes, 9,10-ADC (9,10-MOF), 2,6-ADC (2,6-MOF) and 1,4-ADC (1,4-MOF). Selective excitation of surface-bound Pd(ii) mesoporphyrin IX (PdMP) gives rise to delayed fluorescence (τ = 370 ± 30 ns) from anthracene in the 9,10-MOF. The overall upconversion efficiency of the Pd@9,10-MOF is 0.46 ± 0.05% with a threshold intensity of 104 ± 26 mW cm−2. [ABSTRACT FROM AUTHOR]

Published
2018
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