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This study aimed to investigate the impact of as-received biomass fly ashes (BFA) and green liquor dregs obtained from a pulp and paper plant in Brazil as substitutes for metakaolin in geopolymeric formulations. The properties of this type of waste material vary widely between different industrial plants. This study refrains from subjecting the waste materials to any form of pretreatment, taking into account their organic matter and particle size heterogeneity, requiring extensive characterization to evaluate their influence on the compressive strength, apparent open porosity, and water absorption of the geopolymeric samples. The objective was to assess their potential for upcycling purposes as an alternative to energy-intensive materials, such as ordinary Portland cement (OPC) and advanced ceramics. This potential arises from the ability of alkali-activated materials (AAM) to undergo curing at ambient temperatures, coupled with the possibility of compositions primarily derived from waste materials. To improve the sustainability of the products, the amorphous content of the raw material, which is more reactive than crystalline phases, was quantified and used as the base for mixture ratios. This approach aimed to reduce the requirement for alkaline activators, which have significant environmental impacts, while also increasing the waste content in the formulation. The incorporation of waste materials into the geopolymer matrix generally led to a reduction in the compressive strength compared to the benchmark metakaolin sample (19.4 MPa) but did not present a trend. The dregs led to values of 4.1 MPa at 25 wt% and 7.1 MPa at 50 wt%, a behavior that is somewhat counterintuitive, and BFA at 10 wt% presented 5.7 MPa. Nevertheless, the apparent open porosity remained at high levels for all the samples, close to 50%, and the compressive strength of most of them was over the values obtained for the metakaolin-only samples with mixture ratios calculated from the total composition instead of the amorphous composition. The decrease in strength and the increase in porosity were attributed to the specific characteristics of the waste materials, such as their high crystallinity, presence of organic matter, heterogeneous particle composition, and size. Overall, this study provides insight into the variations in geopolymerization based on the bulk and amorphous content of the aluminosilicate sources and how the characteristics of the waste materials influence the geopolymer matrix. It also highlights how calculating mixture ratios based on the amorphous composition improves the possibility of waste valorization through alkali activation. Additionally, it suggests that BFA and dregs might be effectively utilized in applications other than OPC substitution, such as adsorption, filtration, and catalysis. [ABSTRACT FROM AUTHOR]

In this paper, based on the gneiss outcrop of Bozhong 196 gas field in China, uniaxial compression and Brazil splitting tests were conducted by using cores of different orientations. The following compression properties were studied: the elastic compression modulus, Poisson's ratio and compressive strength of the gneiss outcrop. The following tensile properties were studied: the tensile modulus, the tensile strength and peak energy rate of gneiss outcrop. The results demonstrate the following: (1) The elastic compression modulus, compressive strength, tensile strength and peak energy rate of gneiss specimens with horizontal core-taking are greater than those with vertical core-taking. (2) The elastic compression modulus, Poisson's ratio and compressive strength of horizontally cored gneiss specimens are 29.688–45.760 GPa, 0.186–0.386, and 174.94–147.80 MPa, respectively; the elastic compression modulus, Poisson's ratio and compressive strength of the vertical gneiss specimens are 26.541–32.602 GPa, 0.429–0.476 and 169.37–134.46 MPa. (3) The tensile modulus of the horizontal gneiss specimens is 4.93–5.98 GPa. The tensile modulus of the vertical gneiss specimens is 0.96–2.11 GPa. The tensile modulus of the horizontal gneiss specimens is five times that of the vertical gneiss specimens. The elastic compression modulus of gneiss is 5–20 times that of the tensile modulus. (4) The tensile strength and peak energy rate of horizontally cored gneiss specimens are 14.33–17.55 MPa and 2598.67–4049.53 J/m2, respectively. The tensile strength of the vertical gneiss specimens is 6.12–9.65 MPa, and the peak energy rate is 715.74–1515.30 J/m2. (5) There is a good linear relationship between the peak energy rate and tensile strength of gneiss. The research results can provide a scientific and reasonable reference for in situ fracturing of Bozhong 196 gas field. [ABSTRACT FROM AUTHOR]