1. Efficient optical gain media comprising binary blends of poly(3-hexylthiophene) and poly(9,9-dioctylfluorene-co-benzothiadiazole).
- Author
-
Xia, R., Stavrinou, P. N., Bradley, D. D. C., and Kim, Y.
- Subjects
- *
POLYMERS , *OPTICAL fiber communication , *WAVELENGTHS , *OPTICAL fibers , *METALLIC films - Abstract
We report the results of a study of the optical gain properties of binary blend films of regioregular poly(3-hexylthiophene) (RR-P3HT) and poly(9,9-dioctylfluorene-co-benzothiadiazole) (F8BT). Efficient optical gain is observed in the 10-20 wt. % RR-P3HT composition range and can be tuned to the ∼650 nm window utilised for polymer optical fibre data-communications, with maximum gain ∼50 cm-1. At higher P3HT fractions, gain thresholds increase substantially, consistent with the observed concomitant improvement in photocharge generation. Distributed feed back lasers with one-dimensional gratings exhibit pump pulse thresholds as low as 8 nJ (26 μJ cm-2, 2.17 kW cm-2), lower than many other polymer-based gain media in this wavelength range. They also provide relatively high slope efficiencies >2%. The confluence of efficient optical gain with electronic properties that are conducive to charge carrier injection and transport is relatively novel and is expected to be a necessary requirement for the achievement of electrically pumped lasing. [ABSTRACT FROM AUTHOR]
- Published
- 2012
- Full Text
- View/download PDF