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Electrodeposited Invar alloy film is highly desirable for manufacturing fine metal masks (FMMs) used in Organic Light-Emitting Diodes (OLEDs). However, its development is limited by the high coefficient of thermal expansion (CTE). In this study, we successfully obtained a coarse-grained electrodeposited Invar alloy film with near-zero thermal expansion and inclusions smaller than 300 nm, achieved through abnormal grain growth (AGG) induced by second-phase particles. Our experiments confirmed that these second-phase particles are composed of (Fe, Ni)1-xS. During AGG, the aggregation and coarsening of these second-phase particles lead to changes in local strain energy, and the combined effects of surface and strain energies results in the rapid preferential growth of (110)-oriented grains. The matrix grains are engulfed by large-sized grains and transformed into sub-grains, which merge with the abnormally growing grains through grain rotation. An inverse relationship was found between CTE and grain size. Following vacuum annealing at 800 °C for 2 h and hydrogen annealing for 1 h, the average grain size increased to approximately 400 µm, while the CTE was reduced to 0.3 × 10–6/ °C. This study provides a new method for obtaining electrodeposited Invar alloy films that meet commercial applications criteria for and are suitable for FMM fabrication for high-definition OLEDs. [ABSTRACT FROM AUTHOR]

Plant–microbe interactions are key to nutrient-use efficiency. Root microbes are influenced by rhizosphere soil and plant cultivars. The impact of cultivar-by-nitrogen (N) interactions on the maize-root microbiome remains unclear, yet it is crucial for understanding N use efficiency in maize. This study evaluated the effects of maize cultivars and N forms, along with their interactions, on the diversity and composition of root bacteria and fungi. Additionally, we examined correlations between soil microbes and root metabolites. The maize cultivar Zhengdan 958 (ZD958) showed a positive response to the mixture of nitrate and ammonium N, resulting in increased in biomass, grain yield, shoot N content, grain N content, and root area. In contrast, the cultivar Denghai605 (DH605) did not exhibit a similar response. The diversity and composition of root bacteria and fungi differed between ZD958 and DH605. The N form primarily affected the community structure of rhizospheric fungi in ZD958 and rhizospheric bacteria in DH605, rather than endophytic microbes. A mixed N supply increased the relative abundance of Basidiomycota, which was positively correlated with ZD958 yield. For DH605, a mixed N treatment enhanced nitrification functions involving Bacteroidetes and Proteobacteria, while it reduced the effects of ammonium N supply. The dominant rhizospheric microbes in DH605 showed a stronger response to changes in root metabolites compared to those in ZD958. A mixed N supply increased the content of palmitoleic acid in ZD958 root exudates, facilitating the recruitment of beneficial rhizospheric microbes, which promotes maize growth. In DH605, a mixed N supply decreased the concentration of sphinganine, which is significantly correlated with Acidobacteria (negatively), Proteobacteria (negatively), Bacteroidetes (positively), and TM7 (positively). Our findings suggest that different maize cultivars respond differently to N forms, causing distinct rhizospheric microbial effects, and that root metabolites send metabolic signals to regulate and recruit key bacterial and fungal communities. [ABSTRACT FROM AUTHOR]

Emotional support on social media has become a popular way for people to seek comfort when facing failures and frustrations. This paper investigates the social practice of comforting strangers on the Chinese social media platform Douban. The emotional labour framework was adopted to examine the ways in which the comforting practice managed the emotions of both the comfortee and the comforter. A dataset of 400 replies was collected from Douban to analyse the use of comforting strategies and whether the conversation topic influenced their use. The study showed that comforters employed various strategies to manage distressed others’ emotions and their own emotions. The results showed a dichotomy between explicit and implicit comfort in managing comfortee emotions. Three types of replies for managing the comforter's emotions were observed, namely, a concealed reply, a projective reply, and a comparative reply. The study also revealed a correlation between conversation topics and the use of these replies. [ABSTRACT FROM AUTHOR]

This study introduces a novel fluxgate current sensor with a compact, ring-shaped configuration that exhibits improved performance through the integration of magnetization residence times and neural networks. The sensor distinguishes itself with a unique magnetization profile, denoted as M waves, which emerge from the interaction between the target signal and ambient magnetic interference, effectively enhancing interference suppression. These M waves highlight the non-linear coupling between the magnetic field and magnetization residence times. Detection of these residence times is accomplished using full-wave rectification circuits and a Schmitt trigger, with a digital output provided by timing sequence detection. A dual-layer feedforward neural network deciphers the target signal, exploiting this non-linear relationship. The sensor achieves a linearity error of 0.054 % within a measurement range of 15 A. When juxtaposed with conventional sensors utilizing the residence-time difference strategy, our sensor reduces linearity error by more than 40-fold and extends the effective measurement range by 150 % . Furthermore, it demonstrates a significant decrease in ambient magnetic interference. [ABSTRACT FROM AUTHOR]

One of the main pathological features noted in Alzheimer's disease (AD) is the presence of plagues of aggregated β-amyloid (Aβ1–42)-peptides. Excess deposition of amyloid-β oligomers (AβO) are known to promote neuroinflammation. Sequentially, following neuroinflammation astrocytes become activated with cellular characteristics to initiate activated astrocytes. The purpose of this study was to determine whether total flavonoids derived from Dracocephalum moldavica L. (TFDM) inhibited Aβ1–42-induced damage attributed to activated C8-D1A astrocytes. Western blotting and ELISA were used to determine the expression of glial fibrillary acidic protein (GFAP), and complement C3 to establish the activation status of astrocytes following induction from exposure to Aβ1–42. Data demonstrated that stimulation of C8-D1A astrocytes by treatment with 40 μM Aβ1–42 for 24 hr produced significant elevation in protein expression and protein levels of acidic protein (GFAP) and complement C3 accompanied by increased expression and levels of inflammatory cytokines. Treatment with TFDM or the clinically employed drug donepezil in AD therapy reduced production of inflammatory cytokines, and toxicity initiated following activation of C8-D1A astrocytes following exposure to Aβ1–42. Therefore, TFDM similar to donepezil inhibited inflammatory secretion in reactive astrocytes, suggesting that TFDM may be considered as a potential compound to be utilized in AD therapy. [ABSTRACT FROM AUTHOR]

Mn–Co–Ni–O ceramics are promising negative temperature coefficient (NTC) thermistor materials. However, the high sintering temperatures and long sintering time of Mn–Co–Ni–O ceramics are not favorable to grain size control which is closely related to the electric properties of the ceramics. In this work, Mn 1.5 Co 1.2 Ni 0.3 O 4 (MCN) ceramics were prepared via reactive flash sintering (RFS) of a mixture of Mn 3 O 4 , Co 2 O 3 and NiO powders at the current density of 0.2–1.6 A mm−2, sintering time of 30–120 s and sintering temperature of 300 °C (far below the conventional sintering temperature of 1450 °C). The average grain size of the fabricated ceramics was 1.71–3.77 μm, being much smaller than that achieved via conventional sintering (10–12 μm). As a result, the room-temperature resistivity of the ceramics (3.6–25.5 kΩ cm) exceeded that reported in other study (1.7 kΩ cm), and B values (2958–4075 K) were in comparable to that reported in literature (3676 K). Moreover, the enhanced grain boundary diffusion was considered as the predominant mechanism for the RFSing of MCN ceramics. [ABSTRACT FROM AUTHOR]

Sharing experience via social media communication has been examined in psychology, sociology, communication and linguistic studies. While this research has mostly examined consumption experience and health issues, how people make meanings and develop interactions while sharing mundane matters needs more investigation. This paper reports on a pragmatic investigation into individuals sharing their exam experiences in social media groups. Data were collected from two support groups on Douban , a Chinese social networking site that encourages users to share their thoughts, interests and experiences. A total of 400 original posts, 200 each from a group sharing experiences of failure in examinations and a group sharing their success in examinations, were collected and analysed both quantitatively and qualitatively. The findings showed that the two groups were significantly different in the ways they voluntarily disclosed their identities and in the types of expressions they employed to refer to different participants. In addition, they differed significantly in how they sought or offered support in interactions. Similarities and differences between the two groups' sharing are discussed in relation to the instructions of the two groups, their identity construction, the affordances of social media, and the importance of politeness and face in Chinese culture. • This paper reports on a pragmatic investigation into individuals sharing their exam experiences in social media groups. • The failure and the success groups were significantly different in the ways they voluntarily disclosed their identities. • They were also significantly different in the types of expressions used to refer to different participants. • They differed significantly in how they sought or offered support in interactions. [ABSTRACT FROM AUTHOR]

Simple Summary: Osteoporosis is a major global health problem with substantial economic and psychosocial repercussions. Underdiagnosis of osteoporosis is prevalent. The dual-energy absorptiometry (DEXA) scan is the gold standard for bone mineral density (BMD) measurement but its accessibility is limited. Radiographs are ubiquitous in healthcare and represent a promising avenue for opportunistic osteoporosis screening. Historically, this has been associated with high labor and time costs but several recent studies have demonstrated that BMD can be estimated from radiographs in a cost-effective manner utilizing deep learning techniques. This review aims to summarize the existing evidence supporting the utility of artificial intelligence (AI) methods for osteoporosis classification using radiographs. Osteoporosis is a complex endocrine disease characterized by a decline in bone mass and microstructural integrity. It constitutes a major global health problem. Recent progress in the field of artificial intelligence (AI) has opened new avenues for the effective diagnosis of osteoporosis via radiographs. This review investigates the application of AI classification of osteoporosis in radiographs. A comprehensive exploration of electronic repositories (ClinicalTrials.gov, Web of Science, PubMed, MEDLINE) was carried out in adherence to the Preferred Reporting Items for Systematic Reviews and Meta-Analyses 2020 statement (PRISMA). A collection of 31 articles was extracted from these repositories and their significant outcomes were consolidated and outlined. This encompassed insights into anatomical regions, the specific machine learning methods employed, the effectiveness in predicting BMD, and categorizing osteoporosis. Through analyzing the respective studies, we evaluated the effectiveness and limitations of AI osteoporosis classification in radiographs. The pooled reported accuracy, sensitivity, and specificity of osteoporosis classification ranges from 66.1% to 97.9%, 67.4% to 100.0%, and 60.0% to 97.5% respectively. This review underscores the potential of AI osteoporosis classification and offers valuable insights for future research endeavors, which should focus on addressing the challenges in technical and clinical integration to facilitate practical implementation of this technology. [ABSTRACT FROM AUTHOR]

Simple Summary: This study investigates the impact of DNA methylation on collagen deposition in the skin of Dezhou donkeys, a breed valued for its thick, flexible skin with medicinal properties. Utilizing whole genome bisulfite sequencing (WGBS) and RNA sequencing (RNA-seq), the research analyzes the epigenetic landscape and gene expression profiles across three developmental stages of Dezhou donkeys. The study identifies numerous differentially methylated genes related to collagen deposition, such as COL1A1, COL1A2, and MMPs, highlighting an inverse relationship between gene expression and DNA methylation near transcription start sites. The findings of our study reveal the significant regulatory role of DNA methylation in skin collagen deposition, offering insights for genetic improvement and selective breeding to enhance skin quality in Dezhou donkeys. Our current research adds to the foundational knowledge of collagen deposition mechanisms, contributing to the fields of molecular biology and animal husbandry. DNA methylation represents a predominant epigenetic modification with broad implications in various biological functions. Its role is particularly significant in the process of collagen deposition, a fundamental aspect of dermal development in donkeys. Despite its critical involvement, the mechanistic insights into how DNA methylation influences collagen deposition in donkey skin remain limited. In this study, we employed whole genome bisulfite sequencing (WGBS) and RNA sequencing (RNA-seq) to investigate the epigenetic landscape and gene expression profiles in the dorsal skin tissues of Dezhou donkeys across three developmental stages: embryonic (YD), juvenile (2-year-old, MD), and mature (8-year-old, OD). Our analysis identified numerous differentially methylated genes that play pivotal roles in skin collagen deposition and overall skin maturation, including but not limited to COL1A1, COL1A2, COL3A1, COL4A1, COL4A2, GLUL, SFRP2, FOSL1, SERPINE1, MMP1, MMP2, MMP9, and MMP13. Notably, we observed an inverse relationship between gene expression and DNA methylation proximal to transcription start sites (TSSs), whereas a direct correlation was detected in regions close to transcription termination sites (TTSs). Detailed bisulfite sequencing analyses of the COL1A1 promoter region revealed a low methylation status during the embryonic stage, correlating with elevated transcriptional activity and gene expression levels. Collectively, our findings elucidate key genetic markers associated with collagen deposition in the skin of Dezhou donkeys, underscoring the significant regulatory role of DNA methylation. This research work contributes to the foundational knowledge necessary for the genetic improvement and selective breeding of Dezhou donkeys, aiming to enhance skin quality attributes. [ABSTRACT FROM AUTHOR]

Intrinsic water use efficiency (WUEi) reflects the trade‐off between photosynthetic carbon gain and water loss through stomatal conductance and is key for understanding dryland plant responses to climate change. Stipa tenacissima is a perennial tussock C3 grass with an opportunistic, drought‐avoiding water use strategy that dominates arid and semiarid steppes across the western Mediterranean region. However, its ecophysiological responses to aridification and woody shrub encroachment, a major land‐use change in drylands worldwide, are not well‐understood.We investigated the variations in leaf stable isotopes (δ18O, δ13C, δ15N), nutrient concentrations (N, P, K), and culm water content and isotopic composition (δ18O, δ2H) of paired pure‐grass and shrub‐encroached S. tenacissima steppes along a 350 km aridity gradient in Spain (10 sites, 160 individuals).Culm water isotopes revealed that S. tenacissima is a shallow‐rooted grass that depends heavily on recent rainwater for water uptake, which may render it vulnerable to increasingly irregular rainfall combined with faster topsoil drying under climate warming and aridification. With increasing aridity, S. tenacissima enhanced leaf‐level WUEi through more stringent stomatal regulation of plant water flux and carbon assimilation (higher δ13C and δ18O), reaching exceptionally high δ13C values (−23‰ to −21‰) at the most arid steppes. Foliar N concentration was remarkably low across sites regardless of woody shrub encroachment, evidencing severe water and N co‐limitation of photosynthesis and productivity. Shrub encroachment decreased leaf P and K but did not affect S. tenacissima water status. Perennial grass cover decreased markedly with both declining winter rainfall and shrub encroachment suggesting population‐level rather than individual‐level responses of S. tenacissima to these changes.The fundamental physiological constraints of photosynthetic C3 metabolism combined with low foliar N content may hamper the ability of S. tenacissima and other drought‐avoider species with shallow roots to achieve further adaptive improvements in WUEi under increasing climatic stress. A drought‐avoiding water use strategy based on early stomatal closure and photosynthesis suppression during prolonged rainless periods may thus compromise the capacity of semiarid S. tenacissima steppes to maintain perennial grass cover, sustain productivity and cope with ongoing climate aridification at the drier parts of their current distribution. Read the free Plain Language Summary for this article on the Journal blog. [ABSTRACT FROM AUTHOR]

N2-fixing legumes can strongly affect ecosystem functions by supplying nitrogen (N) and improving the carbon-fixing capacity of vegetation. Still, the question of how their leaf-level N status and carbon metabolism are coordinated along leaf ageing remains unexplored. Leaf tissue carbon isotopic composition (δ13C) provides a useful indicator of time-integrated intrinsic water use efficiency (WUEi). Here, we quantified the seasonal changes of leaf δ13C, N content on a mass and area basis (Nmass, Narea, respectively), Δ18O (leaf 18O enrichment above source water, a proxy of time-integrated stomatal conductance) and morphological traits in an emblematic N2-fixing legume tree, the black locust (Robinia pseudoacacia L.), at a subtropical site in Southwest China. We also measured xylem, soil and rainwater isotopes (δ18O, δ²H) to characterize tree water uptake patterns. Xylem water isotopic data reveal that black locust primarily used shallow soil water in this humid habitat. Black locust exhibited a decreasing δ13C along leaf ageing, which was largely driven by decreasing leaf Nmass, despite roughly constant Narea. In contrast, the decreasing δ13C along leaf ageing was largely uncoupled from parallel increases in Δ18O and leaf thickness. Leaf N content is used as a proxy of leaf photosynthetic capacity; thus, it plays a key role in determining the seasonality in δ13C, whereas the roles of stomatal conductance and leaf morphology are minor. Black locust leaves can effectively adjust to changing environmental conditions along leaf ageing through LMA increases and moderate stomatal conductance reduction while maintaining constant Narea to optimize photosynthesis and carbon assimilation, despite declining leaf Nmass and δ13C. [ABSTRACT FROM AUTHOR]

Compared with conventional displacement modal analysis, the strain modal analysis has remarkable advantages in structural damage detection. Identifying the operational strain modal parameters directly from only dynamic strain time–history response measurements of a structure under operational conditions is a challenging issue. In this paper, the strain power spectrum density transmissibility (SPSDT)-based approach is presented to identify the operational strain modal parameters. The SPSDT is first defined by selecting a strain response measurement point as a reference. It is then theoretically proved that the defined SPSDT converges to the ratio of strain mode amplitudes at the system poles. Based on this unique property, the SPSDT matrix is constructed by selecting different strain response measurement points as the references. Singular value decomposition (SVD) is implemented in the matrix at the system pole. The first left singular vector is used to estimate strain mode shape. A simulated three-span continuous beam, a simply supported beam model tested in the laboratory and a full-size arch bridge tested in field are employed to verify the applicability and effectiveness of the proposed SPSDT-based operational strain modal identification method. The obtained results are compared with those of other available methods. It is found that a good agreement is achieved. It is demonstrated that the proposed SPSDT-based method is capable of identifying the operational strain modal parameters of a structure where only the dynamic strain time–history responses are measured. The proposed SPSDT-based method does not need white noise assumption under a single load condition. [ABSTRACT FROM AUTHOR]

Mandarin Chinese, as the national lingua franca in China, has gained increasing importance in bilingual education in ethnic minority areas in the country. However, little research has explored ethnic minority children’s pragmatic competence. Therefore, this study investigates ethnic Uyghur children’s written pragmatic performance of advice-giving through a brief note in Mandarin and the possible effects of proficiency and gender on their advice-giving. Data were collected from 300 ethnic Uyghur children across three proficiency levels with a balanced gender split. In addition, 100 Han children were also recruited as a comparison group. The advice produced by the children was coded in terms of speech act strategies and supportive moves. The findings showed that the Uyghur children with higher proficiency provided more reasons and fewer affective expressions when giving advice than the two lower proficiency groups, reflecting the performance of the Han children. On the other hand, the results also revealed gender differences in certain advice-giving strategies and supportive moves. The study discusses the findings in relation to national lingua franca and second language pragmatics. Some pedagogical implications for multilingual education in ethnic minority areas are also provided. [ABSTRACT FROM AUTHOR]

Comprehension of implicature may be challenging for L2 learners, which may be further influenced for by learners' L2 grit and emotions. However, few studies have endeavored to determine the predictive impact of L2 grit, along with its closely associated emotional factors, such as enjoyment and anxiety, and investigate how these psychological factors jointly influence pragmatic comprehension. Therefore, this study attempts to investigate the relationship between L2 grit and pragmatic comprehension, along with the mediating roles of enjoyment and anxiety in their interactions. The data were collected from 171 Chinese non‐English major postgraduate learners, a population that has been less pronounced in L2 pragmatics. The findings revealed that the perseverance of effort (PE) of L2 grit predicted pragmatic comprehension instead of the consistency of interest of L2 grit. Pragmatic comprehension was positively but weakly linked to enjoyment and shared negative and moderate associations with anxiety. Only anxiety mediated the interaction between PE and pragmatic comprehension. Implications for pragmatic instruction and suggestions for future research are discussed. [ABSTRACT FROM AUTHOR]

Furfuryl alcohol as reactant, NaBr as electrolyte and methanol as solvent, 2,5-dimethoxy-2,5-dihydrofuranmethanol, the intermediate of pyromellic acid, was synthesized by electrochemical method. The influence of reaction time, NaBr addition and reaction temperature on the yield was investigated. The results showed that the reaction time and rection temperature had a significant impact on the yield, while the amount of NaBr added had no significant impact on the yield. When furfuryl alcohol 3 g(24 mmol) was added, constant pressure was 15 V, the optimal conditions were reaction time 2.4 h, NaBr addition 1.76 g, reaction temperature - 10 °C, the average current was 0.93 A, and the yield of 2,5-dimethoxy-2, 5-dihydrofuranmethanol is 67.9%. [ABSTRACT FROM AUTHOR]

The structural and optical properties of the indium-doped β -Ga 2 O 3 films were investigated. Doping the film with more indium alleviates the film strain, leading to the reduction of the size and amount of the holes in the films. The increase of annealing temperature enlarges the holes and makes the film surface flatter. For luminescence performance, addition of more indium slightly inhibits deep ultraviolet (275 nm) light emission of the films and greatly inhibits the near-infrared emission (720 nm). Annealing the β -Ga 2 O 3 film at higher temperature improve its ultraviolet and near-infrared emission. The mechanisms were revealed. • Various annealing temperatures are investigated on indium-doped Ga 2 O 3. • Deep UV and Near-infrared photoluminescence emission of Ga 2 O 3 are improved. • Conductive behavior and carrier mobility of the films are measured. [ABSTRACT FROM AUTHOR]

[Display omitted] • ZVI and magnetite enhanced the MCFAs carbon-flow distribution by 26 % and 52 %. • Main function contributor are Massilibacterium and Tidjanibacter with ZVI. • Main function contributor are Petrimonas and Candidatus_Microthrix with magnetite. • Microbial metabolism and ABC transporters are promoted with iron-based CMs. • CE bacteria adjust TCS and QS to adapt to the biotoxicity of ZVI and magnetite. Despite the increased research efforts aimed at understanding iron-based conductive materials (CMs) for facilitating chain elongation (CE) to produce medium chain fatty acids (MCFAs), the impact of these materials on microbial community functions and the adaptation mechanisms to their biotoxicity remain unclear. This study found that the supply of zero-valent iron (ZVI) and magnetite enhanced the MCFAs carbon-flow distribution by 26 % and 52 %, respectively. Metagenomic analysis revealed the upregulation of fatty acid metabolism, pyruvate metabolism and ABC transporters with ZVI and magnetite. The predominant functional microorganisms were Massilibacterium and Tidjanibacter with ZVI, and were Petrimonas and Candidatus_Microthrix with magnetite. Furthermore, it was demonstrated that CE microorganisms respond and adapt to the biotoxicity of iron-based CMs by adjusting Two-component system and Quorum sensing for the first time. In summary, this study provided a new deep-insight on the feedback mechanisms of CE microorganisms on iron-based CMs. [ABSTRACT FROM AUTHOR]

[Display omitted] • First study on caproate biosynthesis from soybean dreg. • Optimized parameters for the conversion of soybean dreg to caproate. • Ethanol and lactate yielded from soybean dreg as co-ED enhancing caproate production. • Biochar shortens the lag phase and upregulates pivotal genes' relative abundance. • Lysinibacillus and Pseudomonas cooperation may play a crucial role in CE process. To address the environmental hazards posed by high-yield soybean dreg (SD), a high-value strategy is firstly proposed by synthesizing caproate through chain elongation (CE). Optimized conditions for lactate-rich broth as intermediate, utilizing 50 % inoculum ratio, 40 g/L substrate concentration, and pH 5, resulting in 2.05 g/L caproate from direct fermentation. Leveraging lactate-rich broth supplemented with ethanol, caproate was optimized to 2.76 g/L under a refined electron donor to acceptor of 2:1. Furthermore, incorporating 20 g/L biochar elevated caproate production to 3.05 g/L and significantly shortened the lag phase. Mechanistic insights revealed that biochar's surface-existed quinone and hydroquinone groups exhibit potent redox characteristics, thereby facilitating electron transfer. Moreover, biochar up-regulated the abundance of key genes involved in CE process (especially fatty acids biosynthesis pathway), also enriching Lysinibacillus and Pseudomonas as an unrecognized cooperation to CE. This study paves a way for sustainable development of SD by upgrading to caproate. [ABSTRACT FROM AUTHOR]

[Display omitted] • Zn 0.5 Cd 0.5 S are synthesized by hydrothermal, solvothermal and ion-exchange methods. • Photocatalytic activity is varied with the microstructural change. • Zn and S vacancies can respectively capture the photogenerated holes and electrons. • Lactic acid can be oxidized to pyruvic acid, with H+ releasing. As an excellent photocatalytic material, Zn x Cd 1-x S is widely used in photocatalytic H 2 production due to its good visible light response and suitable band position. Based on our previous studies, this paper systematically studies the relationship of Zn 0.5 Cd 0.5 S (ZCS) material between microstructure and photocatalytic activity. By controlling the synthesized temperature, S sources and solvents, a series of ZCS nanomaterials with different morphology and crystalline phase have been prepared by hydrothermal, solvothermal and ion-exchange methods. When several sacrificial agents are added in photocatalytic H 2 production, ZCS performs the highest activity synthesized by solvothermal method, about 12.15 mmol g−1 under 4 h's visible light illumination. To explore the difference of ZCS samples in photocatalytic performance, many factors are considered, such as crystal size, crystallinity, separation of photogenerated charge carriers (PCCs), specific surface area and defect sites, which play important roles in the improving photocatalytic activity. This work provides a new direction for the design of photocatalyst from the microstructural regulation to achieve highly efficient activity. [ABSTRACT FROM AUTHOR]

In this study, a novel and facile one-step synthesis route was conducted to prepare semi-aromatic polyamide elastomer (PAPXD/1214-PEA) with p-phenylenediamine, dodecane diamine, dodecanedioic acid and polyether amine (PEA) as monomers. A systematic investigation has been conducted into the effect of hard segment content on the thermal, mechanical and solvent resistance of polymers when semi-aromatic polyamides are used as hard segments. It was found that the melting point of the copolymers gradually increased from 191.2 °C to 231.5 °C with the hard segment content increased from 39 % to 76 %, while the Vicat softening temperature (VST) enhanced from 103.2 °C to 192.2 °C. Compared with the commercial polyamide elastomer Pebax@ (produced by Arkema Inc) with similar hard segment contents, the VST of PAPXD14/1214-PEA were 17.4–66.2 °C higher. The mechanical performance of these elastomers was also largely improved with tensile strength increasing from 15.1 to 40.6 MPa, Young's modulus from 28.2 to 168.7 MPa, toughness from 91.1 to 170.7 MJ/m3. In addition, the solvent resistance properties of PAPXD14/1214-PEA was compared with the commercial polyamide elastomer Pebax@. After soaking in hydrochloric acid for 24 h, the tensile strength of PAPXD/1214-PEA with the hard segment content increased from 50 % to 63 % decreased down to 9.4 and 14.4 MPa, respectively. While the commercial polyamide elastomer Pebax@ (with similar hard segment content) decreased down to 1.5 and 4.3 MPa, indicating the commercial polyamide elastomer products were deteriorated. This suggests the corrosion resistance of the synthesized PAPXD/1214-PEA is much better than that of commercial product, and these semi-aromatic polyamide elastomers can be potentially applied in some harsh service environment especially for high temperature and corrosion sealing. [Display omitted] • Polyamide elastomers were synthesized with a facile one-step method. • Polyamide elastomers have good thermal, mechanical properties than past elastomers. • Polyether amines increase corrosion resistance of polyamide elastomers. [ABSTRACT FROM AUTHOR]

Contamination of agricultural soil with Cadmium (Cd) poses life-threatening risks to human health via the food chain. To alleviate Cd toxicity, biochar is a safe and efficient technique to reduce their availability in soil and subsequently their uptake by roots and translocation towards edible parts of plants. This study provides an in-depth understanding of the biochar underlying mechanisms for Cd-contaminated soils. Biochar improves soil's physicochemical properties and microbial community structure due to its unique properties including large surface area, porosity, aromatic hydrocarbons, diverse functional groups, nutrient potential, and variable pH. Based on its general and specific characteristics, Cd adsorption and immobilization in soil occur by the mechanisms of improving soil pH, ion exchange, electrostatic interactions, complexation, precipitation, surface adsorption, and activation of microorganisms. Simultaneously, biochar regulates several non-selective channels that are responsible for Cd uptake into the roots, distribute it, and redistribute it to the shoots/grains, thereby reducing their accumulation in edible parts of plants. Finally, the use of biochar may reduce the risk of Cd exposure to humans from food crops. Conclusively, this study gives a detailed account of biochar-induced Cd immobilization in soil, its absorption by roots, and accumulation in edible parts of plants. [Display omitted] • The presence of cadmium in agricultural soil poses a serious threat to human health. • Biochar could be a suitable strategy to reduce Cd availability in soil for plants. • Biochar improves soil physical and chemical adsorption of Cd on their surface. • It regulates channels that are responsible for Cd uptake and translocation in plants. [ABSTRACT FROM AUTHOR]

This paper studies the stabilization problem of networked control systems (NCSs) with random packet dropouts caused by stochastic channels. To describe the effects of stochastic channels on the information transmission, the transmission times are assumed to be deterministic, whereas the packet transmission is assumed to be random. We first propose a stochastic scheduling protocol to model random packet dropouts, and address the properties of the proposed stochastic scheduling protocol. The proposed scheduling protocol provides a unified modelling framework for a general class of random packet dropouts due to different stochastic channels. Next, the proposed scheduling protocol is embedded into the closed-loop system, which leads to a stochastic hybrid model for NCSs with random packet dropouts. Based on this stochastic hybrid model, we follow the emulation approach to establish sufficient conditions to guarantee uniform global asymptotical stability in probability. In particular, an upper bound on the maximally allowable transmission interval is derived explicitly for all stochastic protocols satisfying Lyapunov conditions that guarantee uniform global asymptotic stability in probability. Finally, two numerical examples are presented to demonstrate the derived results. [ABSTRACT FROM AUTHOR]

The age-based digital divide is emerging as a major challenge with the integrated development of population aging and digital transformation. This study examines the dynamics of multifaceted age-based digital divides (perceived Internet importance, Internet access, and learning-oriented Internet use) as well as their socioeconomic differentials (urban-rural residence, gender, and education). Using longitudinal data from China Family Panel Survey (CFPS) from 2010 to 2020, the study found that despite increases in perceived importance and physical access, learning-oriented use showed a downward trend. Moreover, the age-based divides regarding importance and access persisted over time while the divides in learning-oriented use by age fluctuated, and these dynamics varied across different social groups. The largest difference was observed between high-educated and low-educated groups: while the age-based divides in perceived importance and access have widened among the low-educated, these gaps have been bridged among the high-educated populations. For the usage gap, this contrasting developmental trend was only observed between middle-aged and young people, but not for the elderly. • The paper focused on the evolution of age-based digital divides among Chinese from 2010 to 2020. • The age-based divides in attitude, access, and learning-oriented use persisted over years. • The dynamics of age-based divides varied across different social groups. • The age-based Internet perception and access divides have widened among the less-educated populations. [ABSTRACT FROM AUTHOR]

Halide perovskites have received an immense attention in the field of optoelectronics due to their outstanding photophysical properties. But so far, lead‐based halide perovskites still account for most of the research, which raises concerns due to lead toxicity. Herein, a new design strategy is proposed utilizing a super large, energetically higher singlet and triplet energy levels aromatic organic cation to incorporate into the perovskite structure, forming ultra‐stable high‐performance 2D/3D (quasi‐2D) perovskite. The judicious molecular design of connecting all the phenyl groups at their meta sites ensures the simultaneous achievement of a large molecular weight and high singlet and triplet energy levels. The resulting quasi‐2D perovskite thin films not only exhibits excellent emission properties but also, surprisingly, show long‐term waterproof‐level stability. The robustness of these perovskites is confirmed by their extraordinary emission stability upon direct water immersion and almost undetectable lead release in water. Proof‐of‐concept of a water‐resistant color conversion‐type perovskite near‐infrared (NIR) light‐emitting diode (LED) is demonstrated, showing high external quantum efficiency (EQE) and power conversion efficiency (PCE) of 20.5% and 13.3%, respectively. It is believed these results and strategy pave a new way for realizing environmentally friendly lead halide materials and devices. [ABSTRACT FROM AUTHOR]

An impedance analysis for optically induced dielectrophoresis is presented. A circuit model is developed for this purpose. The model parameters are fully defined in terms of the geometrical and material properties of the system. It is shown that trapping force can only be generated when the material properties follow certain impedance matching conditions. The impedance match factor is introduced to succinctly quantify the phenomenon. It is used to calculate bounds on the allowed electrical conductivity of the suspension medium. Results from the proposed model are found to be in good agreement with full-wave numerical simulations. By computing the acceptable set of material parameters with little computational cost, the presented analysis can streamline ODEP system design for various applications. [ABSTRACT FROM AUTHOR]

The precast concrete segments of wind turbine hybrid towers are usually lifted and installed using the pre-installed lifting anchors with supplementary reinforcements. The lifting anchors are made of steel plate and the supplementary reinforcements are often arranged near the lifting anchors to enhance their anchoring performance. This lifting system including the reinforcement configuration is presented in existing design codes, but the design recommendation and calculation method of ultimate capacity are not provided. It is necessary to explore the pull-out behavior of the lifting anchor considering the effects of reinforcements. Therefore, a comprehensive investigation on the pull-out behavior of the lifting anchor is conducted in this paper, by using the precast concrete segments of hybrid tower as a carrier. Four specimens based on the actual dimension of precast concrete segment of hybrid tower were tested under cyclic pull-out loading, and the failure modes as well as the ultimate capacity were analyzed. The verified finite element (FE) models were established based on the test results, and mechanical analysis were performed to reveal the pull-out mechanism of the lifting anchor. Subsequently, the parametric analysis was conducted to explore the sensitive parameters of the lifting anchor's pull-out performance. The accuracy and applicability of the calculation methods for ultimate pull-out capacity in existing design codes and literatures were evaluated based on the test results. Lastly, a practical calculation method for the ultimate pull-out capacity of lifting anchor was proposed based on theoretical model and regression analysis. The proposed method can provide a reference for the lifting design of precast concrete segments of wind turbine hybrid towers. • 4 specimens with the specialized lifting anchor based on the actual size of precast concrete segment were tested under cyclic pull-out loading. • The verified FE models were established, and mechanical analysis were performed to reveal the pull-out mechanism of the lifting anchor. • The parametric analysis was conducted to explore the sensitive parameters of the lifting anchor's pull-out performance. • The accuracy and applicability of the existing calculation methods for ultimate pull-out capacity were evaluated based on the test results. • A practical calculation method for the pull-out capacity of lifting anchor was proposed based on theoretical model and regression analysis. [ABSTRACT FROM AUTHOR]

The utilization of natural clay minerals for the adsorption of endocrine‐disrupting chemicals (EDCs) presents a cost‐effective and environmentally friendly approach. However, the hydrophilic nature of clay minerals' surface limits their efficacy in removing these hydrophobic pollutants. To overcome these limitations, this study employed two cationic surfactants, cetylpyridinium chloride (CPC) and cetyltrimethylammonium chloride (CTAC), to modify kaolin minerals to enhance their capacity to adsorb a specific type of EDCs, bisphenol A (BPA), and its analogs. The experimental results validated that the surfactant‐modified kaolin exhibited remarkable efficiency in removing BPA from water. The equilibrium adsorption capacities of CPC‐K and CTAC‐K for BPA were determined to be 11.4 mg/g (pH = 2.0–8.0) and 13.4 mg/g (pH = 2.0–6.5), respectively. Kinetic analysis revealed that the BPA adsorption followed a pseudo‐second‐order kinetic process, while isotherm analysis suggested that the BPA adsorption was better described by the Freundlich model (R2 = 0.993–0.998). The surfactant‐modified kaolin demonstrated a retention of over 70% of its initial adsorption capacity after five cycles of desorption and regeneration, further confirming its potential for recycling. Additionally, these modified adsorbents exhibited excellent compatibility in removing bisphenol analogs. These findings provide valuable insights into the practical application of surfactant‐modified clay minerals for the elimination of hydrophobic organic pollutants from water. [ABSTRACT FROM AUTHOR]

The purpose of this paper is to study the adaptability and enhancement methods of ignition chips in complex electromagnetic environments. In this paper, combined with simulation and calculation technology, we first establish the electromagnetic–electrical–thermal coupling simulation model of ignition chips and analyze the influence of two electromagnetic environments, continuous electromagnetic wave and nuclear electromagnetic pulse, on the electrical–thermal coupling in the bridge area of the ignition chip. The results show that a continuous electromagnetic wave field strength of 1200 V/m, irradiated for 5 s, a nuclear electromagnetic pulse with a rise time of 5 ns, a half-height width of 24 ns, and a leg wire length of 350 mm will cause the ignition chip to fire accidently. In order to suppress its accidental firing, the electromagnetic protection is enhanced by using parallel Transient Voltage Suppressor (TVS) diodes. It has been shown that parallel TVS diodes provide good protection against both continuous electromagnetic waves and nuclear electromagnetic pulses. In particular, the peak induced current decreases by more than 64.7% during the action of continuous electromagnetic waves, and the maximum temperature in the bridge area decreases by 54.34% during the action of nuclear electromagnetic pulses. [ABSTRACT FROM AUTHOR]

As a nutrient-rich multigrain crop, buckwheat is a typical "medicinal food homology" crop that is rich in flavonoids, including rutin and various vitamins. It has positive anti-oxidant and anti-tumour properties and lowers blood pressure. However, due to strict self-crossing characteristics, slow progress has been made in Tartary buckwheat (TB) cross-breeding, resulting in the slow breeding of new varieties of new TB varieties, which has limited the improvement of yield and quality. Therefore, mutant breeding is a rapid and effective technique for broadening and innovating TB breeding. In recent years, improving qualities related to yield, lodging resistance, and stability have become key points in TB breeding. Based on the above findings, excellent, potentially valuable TB lines with rich phenotypes were obtained for the TB mutation library via ethyl methanesulfonate (EMS), laying a foundation for creating new TB germplasms. In this study, we systematically investigated more than 10 agronomic traits of JQ2 and JQ4 mutants, including plant type, leaf colour, grain type, grain colour, grain number per plant, grain length, grain width, grain weight per plant, and 1000-grain weight. The results show that the maximum number of grains per plant was 1956, the weight was 32.84 g, and the 1000-grain weight was 30.89 g. The maximum number of grains per JQ4 plant was 2308, and the weight was 44.82 g. The maximum 1000-grain weight was 24.7 g. Among the 295 JQ2 mutants and 153 JQ4 mutants, 10 flavonoids (orientin, morin, quercetin, kaempferol, luteolin, naringin, hesperetin, myricetin, hesperidin, and rutin) were detected with near infrared spectroscopy (NIR). The mutants were divided into five groups according to the flavonoid content of the JQ2 mutants, of which the first group included 31 individual lines. and the second to fifth groups included 70, 69, 72, and 53 lines, respectively. The JQ4 mutants were divided into four classes, of which 41, 50, 32, and 30 were individual lines, respectively, with the highest rutin content being 82.06 mg/g. In summary, through systematic analysis and screening of the agronomic traits and flavonoid contents of JQ2 and JQ4 mutant seeds, we obtained three lines with a high 1000-grain weight, including two JQ2 mutant lines (30.89 g) and one JQ4 mutant line, which reached 24.70 g and ten lines with high grain weight per plant. This included 8 JQ2 mutants and 2 JQ4 mutants, as well as 72 high-rutin mutants (including 31 lines from JQ2 and 41 lines from JQ4 mutants). These elite lines provide the material basis for creating TB germplasms with excellent qualities and cultivation characteristics. [ABSTRACT FROM AUTHOR]

For the speed-tracking control of permanent magnet synchronous motor (PMSM) systems, fast dynamic response and high reference speed require a large transient current to provide sufficient electromagnetic torque. However, the excessive transient current may damage the drive circuit and threaten the system safety. Besides, it is also important to pay attention to the influence of multiple disturbances including system parameter uncertainties and unknown load torque variation. To solve these problems, we propose a nonlinear speed-tracking control approach for uncertain PMSM systems. More specifically, based on the cascade control structure and by introducing auxiliary smooth function, we first develop a nonlinear current-constrained controller (CCC) to guarantee the speed tracking, disturbance rejection, and overcurrent protection simultaneously. In order to improve the robustness of the desired performances, we further implement extended state observer (ESO) techniques to propose an ESO-based CCC (ESO-CCC). Finally, comparative experiments are implemented in a 5.5 kW PMSM platform to verify the performance of the proposed two controllers. [ABSTRACT FROM AUTHOR]

A scheme that combines optoelectronic tweezers (OET) with spectroscopic analysis is presented. Referred to as spectral tweezers, the approach uses a single focused light beam that acts both as the trapping beam for OET and the probe beam for spectroscopy. Having simultaneous manipulation and spectral characterization ability, the method is used to isolate single micro-samples from clusters and perform spectral measurements. Experimental results show that a characteristic spectral signature can be obtained for a given sample. The proposed approach can be easily integrated into the optical setups used for conventional OETs with only a few additional optical components, making it a convenient tool for bio-analytical applications. [ABSTRACT FROM AUTHOR]

While extensive research has explored translanguaging practices online in relation to named languages, written signs, such as punctuation, are under-researched despite their creative, multifunctional, and playful potential. This study investigates the use of parentheses on a Chinese micro-blogging site, Weibo with a translanguaging lens. We explore how online users exploited parentheses for innovative meanings and functions and how creative adoptions of parentheses facilitate the translanguaging practices featured with trans-boundary communication. Data were collected using Python with keywords “parenthesis literature” – a cyberliteracy in which parentheses are often used in ways that deviate from its conventional usages, along with manual data cleaning. We identified four types of trans-semiotic practices, including trans-scenarios, trans-semiotizing for new punctuation marks, trans-modality for stylizing emoticons, and conventionalizing parentheses for indicating speech acts. We argue that online users engage in trans-semiotic practices via fluid controls of parentheses, during which they turn a conventional punctuation into translanguaging cues, rendering extra-linguistic resources important components in meaning-making in digital communication. [ABSTRACT FROM AUTHOR]

Biometric-based authentication methods have been widely used, for example on portable devices (e.g., Android and iOS devices). However, there are several known limitations in existing authentication methods based on biometrics (e.g., those using facial, iris, and fingerprint). For example, in a healthcare context, a user may be physically incapable of completing the authentication due to his/her medical conditions. Hence, as a complementary authentication mechanism, there have been attempts to also utilize electrocardiogram (ECG). In this work, we propose an ECG authentication system that leverages deep learning. Specifically, to achieve generalization ability, complementary ensemble empirical decomposition (CEEMD) is introduced in our design. Moreover, a 1-D Multi-scale Convolutional Neural Network (1-D MCNN) is implemented to achieve accurate authentication. To evaluate the usability of our proposed approach, we have performed extensive experiments on eight databases, and the findings show that our proposed approach achieves good performance even on abnormal databases and can be adapted for different application environments. In addition, our adopted data from eight public databases requires theoretical statistical treatment for practical applications in real authentication scenarios. [ABSTRACT FROM AUTHOR]

This study reports a modified Haldane model that supports transitions between valley and Chern topological phases in photonic crystals. Berry curvatures of this system can be flexibly diffused, converged, or flipped by endowing different model parameters, thus exhibiting exotic topological interface/edge behaviors, such as topological bound states with ideally zero dispersion. Importantly, the coexistence of chiral and antichiral edge states preserved simultaneously by valley and Chern topological phases is achieved by splicing together two kinds of topological structures as an entirety. It further employs a honeycomb lattice comprising gyromagnetic and ceramic cylinders at microwave frequencies, where inversion and time‐reversal symmetries can be flexibly manipulated. Topological interface transport is demonstrated, including two opposite signs of group velocities jointly protected by topologically distinct regimes. These results bridge the gap between valley and Chern topological physics and shed light on developing reconfigurable integrated device applications for classical (quantum) information processing and photonic computing. [ABSTRACT FROM AUTHOR]

The orientation and rearrangement of water on a gold electrode significantly influences its physicochemical heterogeneous performance. Despite numerous experimental and theoretical studies aimed at uncovering the structural characteristics of interfacial water, the orientational behavior resulting from electrode-induced rearrangements remains a subject of ongoing debate. Here, we employed molecular dynamics simulations to investigate the adaptive structure and dynamics properties of interfacial water on Au(111) and Au(100) surfaces by considering a polarizable model for Au atoms in comparison with the non-polarizable model. Compared to the nonpolarizable systems, the polarization effect can enhance the interaction between water molecules and the gold surface. Unexpectedly, the rotational dynamics directly associated with the orientational behavior of water adjacent to the gold surface is accelerated, thereby reducing the hydrogen bond lifetime. The underlying mechanism for this anomalous phenomenon originates from the polarization effect, which induces the attraction of the positive hydrogen atoms to the surface by the negative image charge. This leads to a change in orientation that disrupts the hydrogen bonds in the first water layer and subsequently accelerates reorientation dynamics of water molecules adjacent to the gold surface. These results shed light on the intricate interplay between polarization effects and water molecule dynamics on metal surfaces, establishing the foundation for the rational regulation of the orientation of interfacial water. [ABSTRACT FROM AUTHOR]

Background: The effect of omentum preservation (OP) on locally advanced gastric cancer (LAGC) remains controversial. This study aimed to investigate the long-term prognosis of LAGC patients with OP versus omentum resection (OR). Methods: A comprehensive search of databases including PubMed, Web of Science, Embase, and Cochrane Library was conducted up until February 2024. Statistical analysis was performed using Stata 12.0 software. The primary outcome was to assess the impact of OP on the long-term prognosis of patients with LAGC, including overall survival (OS) and recurrence-free survival (RFS). Results: A total of six case-control studies were included, encompassing a cohort of 1897 patients. The OP group consisted of 844 patients, while the OR group comprised 1053 patients. The study results showed that the OS (HR = 0.72, 95% CI: 0.58–0.90, P = 0.003) and 5-year RFS (HR = 0.79, 95% CI: 0.63–0.99, P = 0.038) in the OP group were superior to those observed in the OR group. Subgroup analysis indicated that 5-year OS (HR = 0.64, P = 0.003) and 5-year RFS (HR = 0.69, P = 0.005) in the OP group were also better than those in the OR group in Korea. However, the subgroup analysis conducted on stage T3-T4 tumors revealed no statistically significant differences in OS (P = 0.083) and 5-year RFS (P = 0.173) between the two groups. Conclusion: Compared with OR, OP shows non-inferiority in patients with LAGC and can be considered a potential treatment option for radical gastrectomy. [ABSTRACT FROM AUTHOR]

In recent years, the development of environmentally friendly, lead-free ferroelectric films with prominent electrostrictive effects have been a key area of focus due to their potential applications in micro-actuators, sensors, and transducers for advanced microelectromechanical systems (MEMS). This work investigated the enhanced electrostrictive effect in lead-free sodium bismuth titanate-based relaxor ferroelectric films. The films, composed of (Bi0.5Na0.5)0.8−xBaxSr0.2TiO3 (BNBST, x = 0.02, 0.06, and 0.11), with thickness around 1 μm, were prepared using a sol-gel method on Pt/TiO2/SiO2/Si substrates. By varying the Ba2+ content, the crystal structure, morphology, and electrical properties, including dielectric, ferroelectric, strain, and electromechanical performance, were investigated. The films exhibited a single pseudocubic structure without preferred orientation. A remarkable strain response (S > 0.24%) was obtained in the films (x = 0.02, 0.06) with the coexistence of nonergodic and ergodic relaxor phases. Further, in the x = 0.11 thick films with an ergodic relaxor state, an ultrahigh electrostrictive coefficient Q of 0.32 m4/C2 was achieved. These findings highlight the potential of BNBST films as high-performance, environmentally friendly electrostrictive films for advanced microelectromechanical systems (MEMS) and electronic devices. [ABSTRACT FROM AUTHOR]

Chitosan was used to change the surface charge of alum sludge into negative charge so as to realize the flocculation removal of algae. The effects of pH, ratio of chitosan and alum sludge, dosage of chitosan and algae density on algal removal performance of modified alum sludge were evaluated by response surface method, and a mathematical model was established. Using the optimization function of response surface software, the parameters of pH, the ratio of alum sludge to chitosan, chitosan dosage, algal density were 7.51, 53.28, 4.51 mg/L and 4.36 x 106 cells/mL, respectively. The removal rate of algae density measured under the optimal conditions was 100. 0%, which was consistent with the predicted results of the model. The flocculation mechanism was mainly that algae cells and modified alum sludge formed floes through electrostatic adsorption, revealed by Zeta potential and SEM. [ABSTRACT FROM AUTHOR]

Introduction and hypothesis: Urinary incontinence (UI) is relatively common among middle-aged and elderly women and can have significant impacts on patients' physiological, psychological, and quality-of-life aspects. A higher level of autonomy can encourage better health behaviors in patients, so as to promote rehabilitation of the disease and improve their quality of life. The study is aimed at exploring the level of autonomy and influencing factors among middle-aged and elderly women with UI. Methods: A cross-sectional study was conducted at a tertiary hospital in Shenzhen, China. Middle-aged and elderly women were asked to complete the Index of Autonomous Functioning scale (IAF), the International Consultation on Incontinence Questionnaire—Urinary Incontinence Short Form (ICIQ-UI SF), and the Urinary Incontinence Quality of Life (I-QOL) scale. Data were collected in January 2024 to March 2024. Descriptive statistics, univariate analysis, bivariate correlation and multivariate linear regression were used to analyze data. Results: A total of 646 women completed the questionnaire. The means and standard deviations (SD) of the IAF section were 45.40 ± 8.92, those of the ICIQ-UI SF section were 11.54 ± 3.67, and those of the I-QOL section were 43.95 ± 9.83. Multivariate linear regression models for the IAF revealed that questionnaire scores were independently associated with family's monthly income, education level, regular exercise, UI severity, and I-QOL score (p < 0.05). Conclusions: The factors influencing the level of autonomy among middle-aged and elderly women with UI include family's monthly income, education level, regular exercise, UI severity, and I-QOL score. Higher levels of autonomy were observed among women with high family income, high education level, regular exercise habits, mild to moderate UI, and high quality of life. [ABSTRACT FROM AUTHOR]

Flexible thermoelectric materials have drawn significant attention from researchers due to their potential applications in wearable electronics and the Internet of Things. Despite many reports on these materials, it remains a significant challenge to develop cost-effective methods for large-scale, patterned fabrication of materials that exhibit both excellent thermoelectric performance and remarkable flexibility. In this study, we have developed an Ag2Se-based ink with excellent printability that can be used to fabricate flexible thermoelectric films by screen printing and low-temperature sintering. The printed films exhibit a Seebeck coefficient of −161 μV/K and a power factor of 3250.9 μW/m·K2 at 400 K. Moreover, the films demonstrate remarkable flexibility, showing minimal changes in resistance after being bent 5000 times at a radius of 5 mm. Overall, this research offers a new opportunity for the large-scale patterned production of flexible thermoelectric films. [ABSTRACT FROM AUTHOR]

The graphite/Al2O3 composite was prepared using plasma spray technology, the material design, experimental methods, and process flow are introduced. The microstructure, chemical composition, and complex permittivity of the composite are investigated, and its performance to absorb electromagnetic waves is studied. The mechanism of interaction between chemical composition, microstructure, complex permittivity, and absorption performance is analyzed. Furthermore, a microwave absorber composed of graphite/Al2O3 and sheet resistance, and performance is discussed. The reflectivity of the composite coating with different periods and sizes and resistances is analyzed. The impedance and reflectivity of the designed absorber that contains sheet resistance are discussed, and its absorption mechanism is explained in detail. The results demonstrate that the microwave absorption performance of graphite/Al2O3 coating is enhanced by electromagnetic resonance of the sheet resistance. The designed absorber exhibits good wave‐absorbing performance and stability at the frequency of the 8.2–18 GHz range. When the sample thickness is 2.3 mm, the absorber achieves a reflection loss (RL) value of −16.8 dB at 9.8 GHz and a wide effective absorption bandwidth (EAB) of 9.8 GHz. It means that the RL below −10 dB can be obtained in the whole X band and Ku bands. These results proved that the EAB can be tuned and enhanced by manipulating sheet resistance. [ABSTRACT FROM AUTHOR]

The introduction of nitrogen‐containing functional groups to chiral polymer backbones enables the tailoring of physical properties and offers opportunities for further post‐polymerization modification. However, the substrate scope of such polymers is extremely limited because monomers having nitrogen‐containing groups can change coordination state with respect to the metal centers, thus decreasing the activity and enantioselectivity and even poisoning the catalyst completely. In this paper, we report our attempts to carry out the asymmetric copolymerization of meso‐epoxide with highly reactive isocyanates. In particular, we found that biphenol‐linked bimetallic Co(III) complexes with multiple chiral centers are very efficient in catalyzing this asymmetric copolymerization reaction, affording optically active polyurethanes with a completely alternating nature and a high enantioselectivity of up to 94 % ee. Crucially, we identified that the steric hindrance at the phenolate ortho position of the ligand strongly influences the catalytic activity and product enantioselectivity. In addition, density functional theory calculations revealed that the highly sterically bulky substituents change the mechanism from bimetallic to monometallic, and result in the unexpected inversion of the chiral induction direction. Moreover, the high stereoregularity of the produced polyurethanes enhances their thermal stability, and they can be selectively decomposed into oxazolidinones. This study offers a versatile methodology for the synthesis of chiral polymers containing nitrogen functionalities. [ABSTRACT FROM AUTHOR]

The introduction of nitrogen‐containing functional groups to chiral polymer backbones enables the tailoring of physical properties and offers opportunities for further post‐polymerization modification. However, the substrate scope of such polymers is extremely limited because monomers having nitrogen‐containing groups can change coordination state with respect to the metal centers, thus decreasing the activity and enantioselectivity and even poisoning the catalyst completely. In this paper, we report our attempts to carry out the asymmetric copolymerization of meso‐epoxide with highly reactive isocyanates. In particular, we found that biphenol‐linked bimetallic Co(III) complexes with multiple chiral centers are very efficient in catalyzing this asymmetric copolymerization reaction, affording optically active polyurethanes with a completely alternating nature and a high enantioselectivity of up to 94 % ee. Crucially, we identified that the steric hindrance at the phenolate ortho position of the ligand strongly influences the catalytic activity and product enantioselectivity. In addition, density functional theory calculations revealed that the highly sterically bulky substituents change the mechanism from bimetallic to monometallic, and result in the unexpected inversion of the chiral induction direction. Moreover, the high stereoregularity of the produced polyurethanes enhances their thermal stability, and they can be selectively decomposed into oxazolidinones. This study offers a versatile methodology for the synthesis of chiral polymers containing nitrogen functionalities. [ABSTRACT FROM AUTHOR]

Asiatic acid (AA) is a pentacyclic triterpene derived from the traditional medicine Centella asiatica. It is known for its anti-inflammatory, antioxidant, and lipid-regulating properties. Though previous studies have suggested its potential therapeutic benefits for atherosclerosis, its pharmacological mechanism is unclear. The objective of this study was to investigate the molecular mechanism of AA in the treatment of atherosclerosis. Therefore, network pharmacology was employed to uncover the mechanism by which AA acts as an anti-atherosclerotic agent. Furthermore, molecular docking, molecular dynamics (MD) simulation, and in vitro experiments were performed to elucidate the mechanism of AA's anti-atherosclerotic effects. Molecular docking analysis demonstrated a strong affinity between AA and PPARγ. Further MD simulations demonstrated the favorable stability of AA-PPARγ protein complexes. In vitro experiments demonstrated that AA can dose-dependently inhibit the expression of inflammatory factors induced by lipopolysaccharide (LPS) in RAW264.7 cells. This effect may be mediated through the PPARγ/NF-κB signaling pathway. This research underscores anti-inflammation as a crucial biological process in AA treatments for atherosclerosis, with PPARγ potentially serving as a key target. [ABSTRACT FROM AUTHOR]

Background: Despite the success of PD-1 blockade in recurrent/metastatic nasopharyngeal carcinoma (NPC), its effect for locoregionally advanced NPC (LANPC) remains unclear. This study aimed to evaluate the benefit of adding PD-1 blockade to the current standard treatment (gemcitabine and cisplatin IC plus cisplatin CCRT ) for LANPC patients. Methods: From January 2020 to November 2022, 347 patients with non-metastatic high-risk LANPC (stage III-IVA, excluding T3-4N0) were included. Of the 347 patients, 268 patients were treated with standard treatment (IC-CCRT), and 79 received PD-1 blockade plus IC-CCRT (PD-1 group). For the PD-1 group, PD-1 blockade was given intravenously once every 3 weeks for up to 9 cycles (3 induction and 6 adjuvant). The primary endpoint was disease-free survival (DFS) (i.e. freedom from local/regional/distant failure or death). The propensity score matching (PSM) with the ratio of 1:2 was performed to control confounding factors. Results: After PSM analysis, 150 patients receiving standard treatment and 75 patients receiving additional PD-1 blockade remained in the current analysis. After three cycles of IC, the PD-1 group had significantly higher rates of complete response (defined as disappearance of all target lesions; 24% vs. 9%; P = 0.006) and complete biological response (defined as undetectable cell-free Epstein-Barr virus DNA, cfEBV DNA; 79% vs. 65%; P = 0.046) than that in the standard group. And the incidence of grade 3–4 toxicity during IC was 47% in the PD-1 group and 41% in the standard group, with no significant difference (P = 0.396). During follow-up period, additional PD-1 blockade to standard treatment improved 3-year DFS from 84 to 95%, with marginal statistical significance (HR, 0.28; 95%CI, 0.06-1.19; P = 0.064). Conclusion: Additiaonl PD-1 blockade to gemcitabine and cisplatin IC and adjuvant treatment results in significant improvement in tumor regression, cfEBV DNA clearance, superior DFS, and comparable toxicity profiles in high-risk LANPC patients. [ABSTRACT FROM AUTHOR]

• A bridge dynamic response analysis method considering the spatial dependency of uncertain parameters. • The uncertain parameter is described by a non-probabilistic interval field model. • The spatial dependency of the interval field is quantified by the Karhunen-Loève expansion. • The proposed method significantly reduces the computational effort and improves the computational efficiency. Uncertain parameters with spatial dependency exist in actual bridges inevitably, which significantly affect the bridge dynamic response. However, such spatial dependency is often neglected when investigating its influence on bridge response. This study proposes a bridge dynamic response analysis method considering the spatial dependency of uncertain parameters. Firstly, the bridge uncertain parameter is described by a non-probabilistic interval field model, and the spatial dependency between adjacent values of the interval field is quantified by the Karhunen-Loève like expansion. Thus the bridge is transformed into a system with multidimensional interval parameters by finite element method. Then, the system with multidimensional interval parameters is decomposed into several one-dimensional subsystems with only one interval parameter. Finally, the interval parameters of each one-dimensional system are divided into several subintervals with small uncertainties, and the dynamic response is obtained by combining analysis of subinterval results. Numerical examples are used to verify the accuracy and efficiency of the proposed method, and the results indicate that the proposed method significantly reduces the computational effort and improves the computational efficiency. Higher level of spatial dependency of the interval field, larger subinterval number, and lower uncertainty level of the non-probabilistic interval field leads to higher dynamic analysis accuracy. [ABSTRACT FROM AUTHOR]

To ensure structural safety and integrity, a novel framework is developed for detecting the loosening of multi-bolt connections using wavelet entropy of vibro-acoustic modulation (VAM) signals. Wavelet entropy is employed as the dynamic index to capture the intricate time-frequency characteristics that are indicative of the connection status. Taking the wavelet entropy vectors as input, the proposed framework distinguishes itself by integrating a Transformer model for high-dimensional feature extraction with the recursive feature elimination (RFE) for essential feature selection, followed by a support vector machine (SVM) model for classification. Specifically, the Transformer model with innovative positional encoding capability helps to extract the time-dependent transient features that are sensitive to the bolt loosening. The RFE process reduces the data dimensionality while discerning the diagnostic information for more accurate classification. Through the experiment on a four-bolt joint, the identification results with cross-validation showed high accuracy and robustness of the proposed framework across various loosening cases. It outperformed the traditional SVM, long short-term memory network (LSTM), convolutional neural network (CNN)-SVM models without and with RFE, as well as the Transformer-SVM model without RFE, achieving an accuracy increase of 15.72%, 11.74%, 9.47%, 5.49%, and 5.06%, respectively. The proposed framework was demonstrated to be able to learn the damage-sensitive features more effectively from wavelet entropy data, marking a significant advancement in the health monitoring of engineering structures with high-strength bolt connections. [ABSTRACT FROM AUTHOR]

This study presents the first high-temperature measurements of cyclopentene + OH → k 1 Products reaction over 856 – 1258 K and 1.03 – 4.33 bar. The determined rate coefficients of k 1 exhibited Arrhenius temperature dependence with an activation energy ∼ 3.3 k cal mol−1 and negligible pressure dependence. Rate coefficients of OH + cyclopentene are faster than OH + 1-pentene but comparable to OH + 2-pentene, highlighting the significance of allylic C H bonds in these reactions. At 1258 K, our rate coefficient is ∼ 30 % slower than the average room-temperature measurement, indicating the role of OH-addition pathways at low temperatures. Site-specific rate coefficients and branching ratios are determined, with H-abstraction at the allylic C H site accounting for ∼68 % of the reaction and alkylic C H bond contributing ∼22 %. Our measured k 1 may be given as (unit: cm3molecule−1s−1): k 1 = 1.64 × 10 − 10 e (− 1660 T) Cyclopentene decomposition reaction (cyclopentene → k 2 cyclopentadiene + H 2) is studied over 1186–1472 K and 1.17 – 1.38 bar. Time-resolved yields of the product, cyclopentadiene, are monitored using a sensitive UV laser diagnostic near 220 nm. Absorption cross-sections of cyclopentadiene, measured in two separate mixtures, showed weak positive temperature dependence (8.7 – 9.8 × 10−18 cm2molecule−1) over 961 – 1326 K. Our rate coefficients of k 2 exhibited a positive Arrhenius temperature dependence with an activation energy of ∼ 54.7 k cal mol−1. At 1300 K, the decomposition of cyclopentene proceeds 5.5 and 28 times faster than that of cyclopentadiene and cyclopentane, respectively. Our measured k 2 may be expressed as (unit: s−1): k 2 = 2.55 × 10 12 e (− 27 , 527.6 T) The pentagonal structure of cyclopentene influences its H-abstraction and decomposition reactions distinctively. While H-abstraction by OH follows a mechanism akin to cyclohexene and linear alkenes, with comparable rate coefficients at allylic C H bonds, the penta-ring structure significantly impacts the decomposition mechanism. Cyclopentene decomposition predominantly produces cyclopentadiene and H 2 in a ring-conserving manner, differing from the cleavage of allylic-alkylic C C bonds in the decompositions of 1-alkenes and cyclohexene. [Display omitted] [ABSTRACT FROM AUTHOR]