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Schiff bases are produced through condensation reactions between aldehydes or ketones and molecules containing an amine group. Given their multifaceted uses across diverse domains, they have gained prominence. Numerous studies have been conducted in this field due to the uncomplicated methods of manufacturing and the abundant range of applications. Investigations into DNA binding are essential for understanding the many interactions between drugs and DNA. DNA binding can be investigated via UV-binding, fluorescence quenching, and viscosity investigations. This study aims to offer several research papers on the DNA binding activity of Schiff base metal complexes and compare them. [ABSTRACT FROM AUTHOR]

Along with the developing of flexible electronics, there is a strong interest in high performance flexible energy storage materials. As natural carbohydrate polymer, cellulose fibers have potential applications in the area due to their biodegradability and flexibility. However, their conductive and electrochemical properties are impossible to meet the demands of practical applications. In this study, cellulose fibers were combined with polyaniline to develop novel paper-based supercapacitor electrode material. Cellulose fibers were firstly coordinated to Cu(II) and subsequently involved in polymerization of polyaniline. Not only the mass loading of polyaniline was significantly increased, but also an impressive area specific capacitance (2767 mF/cm2 at 1 mA/cm2) was achieved. The developed strategy is efficient, environmentally friendly, and has implications for the development of cellulosic paper-based advanced functional materials. [Display omitted] [ABSTRACT FROM AUTHOR]

This paper asks whether, and if so how, it is possible to design a system characterised by coordination across sectors and levels of governance aimed at governing AMR. The ambition is, firstly, to analyse how coordination problems materialise in the governing of the AMR problem, and secondly, with an emphasis on the structure of decision-making and communication processes, to probe into how coordination of AMR governance is achieved. The paper’s focus is on Norway, which stands out as one of the better performing countries for AMR governance. Drawing on literature on coordination and governance, the paper argues that effective coordination of AMR governance is more likely to follow a ‘bottom-up’ sequencing pattern. It thus provides a study of the systems for governing AMR in a multi-level setting. Through public documents, literature and interviews with key officials involved in AMR management, the paper illustrates the importance of – and organisational barriers to – inter-sectoral cooperation and coordinated strategies and actions at different levels of governance. [ABSTRACT FROM AUTHOR]

Background: The aim of the study was to investigate the effectiveness of telerehabilitation-based balance and coordination exercises on balance confidence, fall efficacy, and functional independence in stroke patients. Methods: A double-blind, randomized controlled trial was conducted on 30 stroke patients (15 in the telerehabilitation-based group and 15 in the paper-based control group). The telerehabilitation group received video-based exercise training, while the control group received paper-based exercise training. Fear of falling (FES-I), balance (ABC), self-management (SSEQ) and satisfaction with telemedicine (TSQ) were evaluated before and six weeks after treatment. Results: The results of the present study showed that both telerehabilitation-based video training and paperbased exercise prescription methods were effective in terms of balance confidence, fall efficiency and stroke-specific functional independence (p<0.05). Besides, telerehabilitation-based video training was more effective in balance confidence (p=0.042) and functional independence (0.018). In addition, the satisfaction of individuals in the telerehabilitation group with the telerehabilitation application was above average (59.73±8.15). Conclusion: Telerehabilitation-based video exercises in stroke patients may provide additional advantages in terms of balance confidence and fall efficiency. In addition, individuals with stroke were satisfied with the remote rehabilitation application. [ABSTRACT FROM AUTHOR]

A research gap exists in the understanding of multi-level governance for watersheds in Kenya under the current devolved framework. This paper uses the Migori River watershed as a case study to elaborate on the institutional arrangement in the management of the watershed and how it influences the nature and level of coordination among the actors involved. The data was collected through semi-structured interviews and content analysis of secondary data. The target institutions were selected based on existing policy and legal frameworks, press releases, and published administrative reports. Respondents for the semi-structured interviews were identified through purposive and snowball sampling techniques. The qualitative data was then analysed through content analysis. After analysis of the nature of coordination, a panel of experts rated each coordination dimension based on a comparison between the findings and the baseline indicators. The results on the structure and roles of institutions revealed adequate representation of the river basin management actors, but the associations among actors are weak due to overlapping mandates and gaps in the administration processes of river basin management programs. Coordination exists, but it is not all-encompassing; whereas efforts to collaborate were noted, they were inconsistent and tended to be on a per-need basis due to a lack of a common forum for stakeholder interactions and a common management plan for a clear vision and direction of actors' activities. There is an unclear delineation of roles in the institutional structure and thus causing institutional complexity, which further undermines coordination. To address the coordination gaps, the paper recommends the creation of a management council for the watershed to provide a central forum for the stakeholders' interaction, with a designated lead agency that organizes and facilitates meetings, oversees communications, and manages any emerging challenges, gaps and opportunities in collective actions. [ABSTRACT FROM AUTHOR]

AbstractThis paper deals with practices of personal mobility in public space, such as walking, passing-by and queuing, and their intelligible, recognizable and intersubjectively coordinated character. People co-exist in public places without having to explain their conduct in so-many-words; they smoothly navigate by coordinating their bodies and mobile trajectories without collisions; they queue without any instructions and differentiate between who joins the queue and who projects to butt in the queue. This article addresses the intelligibility of walking trajectories in public space, how they are bodily achieved and visibly interpreted. It reflects on mobility by relying on the notion of public in two different but complementary perspectives: a) by reference to mobility in the context of public places such as parks, squares, and streets; b) by reference to the public intelligibility and recognizability of mobile actions in social interaction. The convergence between these two notions of public enables us to investigate how mobile social actions are formed (made recognizable) and how they are ascribed (actually recognized) by co-present unacquainted persons in public space. The analysis draws on video recordings of mobile trajectories in streets, pathways, and squares. [ABSTRACT FROM AUTHOR]

Increasing resilience to flooding is a complex process that requires horizontal and vertical coordination between institutions in policy making and implementation. This paper explores the effect of institutional coordination on managing flood risk in two cities plagued by flooding. Our results show that efforts on building urban flood resilience can be undermined by lack of proper coordination between urban development, water management and land use planning. We find that this complexity is magnified by the emergence of the concept of resilience as an urban development goal that is increasingly pursued by various authorities, but that is inherently contested in practice. [ABSTRACT FROM AUTHOR]

Strategies based on performance measurement and feedback are commonly used to support quality improvement among nurses. These strategies require practice change, which, for nurses, rely to a large extent on their capacity to coordinate with each other effectively. However, the levers for coordinated action are difficult to mobilize. This discussion paper offers a theoretical reflection on the challenges related to coordinating nurses' actions in the context of practice changes initiated by performance measurement and feedback strategies. We explore how Jürgen Habermas' theory of Communicative Action may shed light on the issues underlying nurses' collective actions and self‐determination in practice change and the implications for the design of strategies based on performance measurement and feedback. Based on this theory, we propose differences between communicative and functional coordination according to the nature of the actions and the purposes involved. The domains of action underlying these coordination processes, which Habermas referred to as the lifeworld and the system, are then used to draw a parallel with aspects of nursing practice. Further exploration of these concepts allows us to consider the tensions between the demands of the system and the self‐determination of nurses within their practice. [ABSTRACT FROM AUTHOR]

AbstractThis paper documents an early fork in the development of macroeconomics, by examining a debate between the Dutch economists Jan Tinbergen and Johan Koopmans. In a 1932 paper, Tinbergen argued that two firms could be stuck in a “bad” equilibrium in the absence of a coordinated action to incrase employment. Koopmans replied with a paper demonstrating that multiple equilibria in an exchange economy could not be ranked on the basis of their productive efficiency. This debate contributed to a larger turn away from dynamising the general equilibrium model, towards the new field of macrodynamics, with long-ranging consequences for the field. [ABSTRACT FROM AUTHOR]

Living systems at any given moment enact a very constrained set of end‐directed and contextually appropriate actions that are self‐initiated from among innumerable possible alternatives. However, these constrained actions are not necessarily because the system has reduced its sensitivities to themselves and their surroundings. Quite the contrary, living systems are continually open to novel and unanticipated stimulations that require a physiology of coordination. To address these competing demands, this paper offers a novel heuristic model informed by neuroscience, systems theory, biology and sign study to explain how organisms situated in diverse, complex and ever‐changing environments might draw upon the sparse order made available by 'relevant noise'. This emergent order facilitates coordination, habituation and, ultimately, understanding of the world and its relevant affordances. Inspired by the burgeoning field of coordination dynamics and physiologist Denis Noble's concept of 'biological relativity', this model proposes a view of coordination on the neuronal level that is neither sequential nor stochastic, but instead implements a causal logic of phasic alignment, such that an organism's learned and inherited sets of diverse biological affinities and sympathies can be resolved into a continuous and complex range of patterns that will implement the kind of novel orientations and radical generativity required of such organisms to adaptively explore their environments and to learn from their experiences. [ABSTRACT FROM AUTHOR]

[Gd(HP‐DO3A)] (gadoteridol) as an active compound of ProHance® is a widely employed contrast agent in clinical MRI scans in the last 30 years. Recent concerns about the long‐term retention of gadolinium‐based contrast agents (GBCAs) led to a deeper investigation of the structural features underlying the integrity of the paramagnetic metal complex. Several human and nonclinical studies have noted marked differences among the macrocyclic GBCAs, with the least retention of Gd traces and most rapid elimination consistently being reported for [Gd(HP‐DO3A)]. It was deemed of interest to assess how minor structural/electronic changes associated to the ligand structure may affect basic properties of the metal complex with several [Gd(HP‐DO3A)] analogues synthesized and characterized in the last years. We recently reported that the closest homolog of [Gd(HP‐DO3A)], i. e.: [Gd(HB‐DO3A)], in which a (±)‐2‐hydroxy‐1‐propyl pendant arm is replaced by a (±)‐2‐hydroxy‐1‐butyl moiety, showed a significantly different retention behaviour in the model interaction with collagen, despite the apparently very minor structural difference. In this paper we report a comprehensive study of the structural, thermodynamic, kinetic and relaxation properties of [Gd(HB‐DO3A)], compared to the parent [Gd(HP‐DO3A)] and to other closely related macrocyclic GBCAs to assess whether very minor structural changes can modulate the physico‐chemical properties of Gd3+ complexes. [ABSTRACT FROM AUTHOR]

In this paper is present the procedure for introducing the coordination of light signals at five intersections on the Boulevard "St. Kliment Ohridski" in Skopje. The primary purpose of a traffic signal is to assign the right-of-way to intersecting traffic streams for the purpose of ensuring that all streams are served safely and without excessive delay. A properly designed and timed signalized intersection will minimize fuel consumption, delay, and stops without having an adverse effect on safety. Travelers will realize one or more of the following benefits at intersections where the traffic signal is needed, properly designed, and well timed: orderly movement of traffic, increase in the traffic-carrying capacity of the intersection, reduction in the frequency and severity of certain types of crashes, progressed traffic when traveling in a coordinated signal system, and interruption of heavy traffic flow to provide safe opportunities for minor movements. Coordinated signal timing synchronizes traffic movements and manages the progression speed of specific modes where uninterrupted flow is desired along a corridor. While traditionally applied to increase vehicular traffic flow and reduce peak-hour delay, coordinated signal timing can also be optimized for slower speeds, creating an uninterrupted flow for bicyclists or low vehicle progression speeds for a pedestrian-friendly downtown. Signals may also be timed to coordinate transit headways along routes where regular transit service is consistent and has low variability. Coordination of traffic signals can reduce the number of stops along a corridor and provide for a continuous flow of traffic at the target speed. Progression speeds should be set at or below the target speed, rather than existing 85th percentile speeds. [ABSTRACT FROM AUTHOR]

AbstractThe imperfect coordination of expectations and actions is a central theme running through Keynes’s General Theory. Incorporating this theme into mainstream macroeconomics, however, has proved to be a difficult endeavour. In particular, attempts to accommodate coordination failures within Dynamic Stochastic General Equilibrium (DSGE) models through multiple equilibria and “dynamic” indeterminacy, while promising in the 1990s, were gradually abandoned in the 2000s. Since then, the “New Keynesian” framework has come to dominate macroeconomic modelling. And since the coordination of agents is not at issue in this latter framework, mainstream macroeconomics has seemed to leave the coordination theme out of its focus, if not its scope. In this paper, we challenge this perception and argue that the coordination theme is actually alive and well. We especially present two recent research programmes which, while belonging to the DSGE paradigm, give pride of place to coordination failures and share a common objective: providing, within the class of DSGE models, an alternative to the New Keynesian framework that would involve the most important ideas emerging from Keynes’s General Theory. [ABSTRACT FROM AUTHOR]

• Country ownership is one of the four guiding principles for the Immunization Agenda 2030. • There is little practical guidance on what country ownership is and how to operationalize it. • Measles and rubella programs are used to illustrate country ownership in operation. • Five elements of country ownership - commitment, coordination, capacity, community participation, and accountability - are described. • Our work is a useful guide for immunization program strategy development. Country-owned, as opposed to donor-driven, is a principle within the development sector that recognizes the centrality of countries' leadership, systems, and resources in executing programs and achieving sustainable development. In alignment with this notion, the Immunization Agenda 2030 was developed with country ownership as one of four core principles of the ambitious ten-year plan. This means that the success of immunization programs, including those with eradication and elimination goals such as polio, measles, and rubella, and those with broader equity goals to "leave no one behind" on immunization, would be largely driven by country systems. In this paper we deconstruct country ownership into five operational principles: commitment, coordination, capacity, community participation, and accountability. Through this lens, we illustrate how two countries, Nepal and Nigeria, have exemplified country ownership in their measles and rubella elimination programs and we infer the ways in which country ownership drives system performance and sustains program efforts. [ABSTRACT FROM AUTHOR]

AbstractThis paper elaborates on four different reasons why the assumption of continual dynamic stochastic general equilibrium, which is now standard in mainstream macroeconomics but is not used in agent based macro, makes a macro model less useful: (1) it assumes away most coordination problems, (2) it hides possible instabilities, (3) it makes money look unimportant, and (4) it makes inflation look trivial. [ABSTRACT FROM AUTHOR]

With the penetration of distributed resources into power distribution networks, power distribution networks are transforming into active distribution networks with a high proportion of distributed generations and power electronic equipment. Efficient modeling and simulation methods are essential to perform dynamic response analysis. In order to satisfy the fast/steady/slow multiple time-scale simulation requirements of active distribution networks, a fast/medium/slow time partition model and a network decoupling method for short line characteristic lines is proposed in this paper. Through the decomposition coordination simulation method, the network is decomposed into multiple regions that can be simulated in parallel. Based on the interconnection of fiber optic network cards, a multi-rate parallel simulation and synchronization strategy is proposed, which significantly improves the simulation speed of active distribution networks while ensuring simulation accuracy. The numerical experiments have been conducted based on a modified IEEE 33-bus and a PG&E 69-bus, and simulation results show the feasibility of the proposed method. The verification results of the example show that using adaptive variable-step-size multi-rate parallel simulation technology can increase the subnet computation-time balance rate and simulation acceleration ratio to 119.90% and 121.31% in the same rate-parallel mode. [ABSTRACT FROM AUTHOR]

This paper focuses on the actions and partnerships established between members of the State Secretariats of Health and Social Assistance in Rio de Janeiro and other organizations in the health and assistance areas to respond to the health emergency triggered by the congenital Zika virus syndrome between 2015 and 2018. Some characteristics of the context were: a severe economic crisis, the erosion of the governance capacities of the state political authorities as well and scarce technicalscientific knowledge about the epidemic. The study was grounded on an analysis of documents related to the topic, 17 semi-structured interviews with managers and professionals from the two secretariats. Interview scripts focused on intersectoral actions and processes of cooperation and coordination within and between organizations. The analytical grid included aspects of the interpersonal, informational, and decision-making roles of managers and technicians. The results show that, despite the political and economic crisis, the Secretariat actors managed to create a flow of care for patients. Informal cooperation and coordination mechanisms were crucial for the creation of long-term intersectoral strategies [ABSTRACT FROM AUTHOR]

The transition from centralised, fossil fuel-powered generating units to distributed energy resources (DER) represents a significant step forward, offering numerous benefits. However, this shift also presents operational challenges for distribution network service providers (DNSPs) and the electricity markets. In this paper, we introduce our innovative solution for allocating network capacity in the form of operating envelopes, shaped to enhance customer participation in energy and reserve markets. Our approach also provides DNSPs with network support flexibility of DER which can be leveraged to either increase network throughput for market services or postpone network augmentation. This study outlines our initial findings from Project Converge 1 1 https://arena.gov.au/projects/project-converge-act-distributed-energy-resources-demonstration-pilot/. —a comprehensive real-world trial involving 1000 active customers (the largest participant cohort in Australia) located in the Australian Capital Territory. Within, we discuss the challenges we have encountered, the opportunities that have arisen, potential avenues for future expansion, and the invaluable insights gained during the pre-trial phase of the project. • Proposing shaped operating envelopes – a novel extension of dynamic operating envelopes to allocate network capacity amongst aggregators. • Enabling DER to participate in energy, FCAS and network support market while empowering DNSPs to postpone network augmentation. • Real-world implementation of our approach in a live trial in Australia with more that active 1000 customers. [ABSTRACT FROM AUTHOR]

• High penetration of Renewable Energy Sources (RESs) has reduced frequency stability in modern power systems. • Use of multiple Virtual Inertial (VI) units improves frequency stability. • Coordination of multiple VI units increases energy efficiency. • A comprehensive review of VI implementation methods has been done. • Coordination of VI units has been analyzed. The modern power system is progressing from a system based on synchronous generators toward systems with high penetration of renewable energy sources (RESs) such as photovoltaic (PV) and wind power generating units which are connected to the grid through inverters. RES units will represent a significant share of the power generation in near future; therefore, the conventional approach of integrating them into the grid may lead to frequency instability. Many researchers have suggested the use of inverters with virtual inertial control methods to act as synchronous generators in the grid and maintain and increase the frequency stability. This paper presents a comprehensive overview of virtual inertial strategies and current control strategies and makes a comprehensive comparison while describing their characteristics. Then, different types of stability analyses in the presented methods are examined and examples of each are presented. In continuation and in addition to the review studies conducted in this field, methods presented with the aim of improving the virtual inertial control are carefully examined and their characteristics according to the number of resources used, the adaptivity of parameters, the use of optimization methods, the issue of coordination between several resources and the type of communication network are studied. Moreover, a comprehensive review of multiple- virtual synchronous generator (VSG) methods to develop and implement the concept of virtual inertia in weak grids are presented. Finally, a discussion of challenges and research directions is presented, particularly pointing to the integration of multiple virtual inertial units at the system level. [ABSTRACT FROM AUTHOR]

Conservation interventions typically focus on protecting public goods, but they often also create private spillover co-benefits. For example, protecting open space may increase the values of adjacent properties and protecting a coral reef may increase fishing opportunities outside. These privately-captured co-benefits can confer substantial value, but are rarely tapped to help promote and expand conservation efforts. One reason, we argue, is that doing so is difficult: While co-beneficiaries are easily convinced of the benefits of the conservation intervention, they are not obliged to pay for it, and so usually free-ride and enjoy these benefits gratis. In this paper, we document and quantify the magnitude of co-benefits in the literature and identify the conditions under which co-benefits could be tapped to offset the cost of conservation for conservationists. In light of these conditions, we propose an approach that involves voluntary compensation for the provision of co-benefits to expand the total amount of resources available for conservation efforts. We show that taking advantage of these co-benefits lowers the cost of implementing conservation actions while being incentive compatible for all parties involved. [ABSTRACT FROM AUTHOR]

Coordination is an important aspect of group work. Previous studies have shown how collocated multi-user interfaces, such as interactive tabletops, support coordination by providing a shared space that enhances workspace awareness. However, only little is known about the coordination processes that occur during problem-solving on such shared devices and how the design of features and interaction techniques can impact coordination behaviour. In this paper we analyse users’ coordination mechanisms during joint manipulation tasks in Orbitia, an interactive tabletop-based problem-solving activity. The proposed design integrates a series of “breaches” seeking to challenge participants’ collaboration by confronting them to different limitations. We report on a case study with five groups of three users (N = 15), jointly solving tasks while facing different challenges related to the activity interface and the environment. By analysing 135 min of video material along with their transcripts, we identified nine different coordination mechanisms that relate to either coordination of information or coordination of actions. By exploring the occurrences of these mechanisms, we found that sharing unsolicited task-relevant information is a common coordination behaviour that can be observed at interactive tabletops, and that with breaches, more explicit coordination in the form of direct requests, orders, or shadowing is used. [ABSTRACT FROM AUTHOR]

The conventional HVAC system for multi-area buildings includes both centralized and in-situ equipment to collectively regulate indoor air temperature to meet the preferences of its occupants. However, due to the limited capacity of the total supply air mass rate in centralized equipment, maintaining comfortable indoor air temperature for all areas can face conflicts. The first conflict arises between satisfying diverse preferences and limited global resources, while the second conflict is between centralized air supply and distributed regulation. In this paper, a distributed zone model predictive control (DZMPC) with priority conflict resolution is proposed for the multi-area HVAC systems. This strategy is composed of a zone parameter optimization with dynamic priority as a coordinated upper layer and a lower DZMPC layer. In the upper layer, a zone parameter optimization with priority is presented to coordinate sub-controllers by adjusting variable references' bounds for DZMPC, to solve the resource competition when it occurs. In the lower layer, model predictive control with zone control is formed to mitigate the tension of the shared resource. By integrating dual decomposition and Augmented Lagrange function to address global constraints, a distributed solvable control structure is formed. The resulting optimization can be solved using a distributed primal–dual algorithm. The effectiveness of the proposed scheme is proved by simulation examples. [ABSTRACT FROM AUTHOR]

• The state-of-the-art research advances in power system restoration with large renewable penetration are reviewed from different system levels, i.e., transmission system, distribution system, and coordinated transmission and distribution system. • The methods of handling renewable power uncertainty during system restoration are summarized. • The laboratory validations and practical applications of the renewable power system restoration strategies are reviewed. • Promising research directions for renewable system restoration are provided, including uncertainty handling, artificial intelligence techniques, transient stability issues, cyber-physical interlinking, and multi-energy coupling. The catastrophic blackout events and ever-increasing penetration of renewable power generation highlight an advanced restoration strategy to effectively and reliably employ renewable power generation to contribute to renewable power system restoration. This paper reviews the research advances of power system restoration involving large renewable penetration, and the methods of handling renewable power uncertainty during restoration are also summarized. First, the transmission system restoration processes are divided into three sequential stages: a) black-start, b) network reconfiguration and c) load restoration, and the research advances of these three restoration stages involving large renewable generation are presented. Then, the distribution system restoration assisted by multiple flexible resources, such as renewable distributed generators, remotely-controlled switches, energy storage systems, and soft open points, are reviewed with emerging techniques, including micro-grids, multi-agent systems, repair crews, and mobile power sources. Furthermore, with the growing activeness and flexibility of the distribution system, the coordinated transmission and distribution system restoration and their information interactions are also discussed. Finally, for practical applications, the laboratory validations of restoration strategies using realistic power grid data, real-world restoration strategies, decision support systems, and field tests of black-start procedures are introduced to complete this literature review. Effectively deploying renewable power sources can significantly improve the power system restoration efficiency, and their inherent uncertainty should be carefully handled. Moreover, promising research trends are provided to improve the power system restoration with large renewable penetration. [ABSTRACT FROM AUTHOR]