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Abstract: Nanocomposites with platelets reinforcements are emerging materials with strong potential for future engineering applications. The present study is a first step to characterize and predict the elastic behavior of Montmorillonite (MMT) clay reinforced Polypropylene (PP) nanocomposites. The pellets of nanoclay composites were made by first uniformly mixing the MMT platelets in a twin-screw extruder by the melt intercalation route. These pellets were then converted into tensile specimens as per ASTM 638 by injection molding process. From tensile tests it is shown that there is a significant increase of the Young modulus with the mass fraction (2–7%) of clay platelets. A first approach of homogenization allows to conclude that the Ponte Castañeda and Willis (1995) bound predicts the measured moduli provided that a suitable aspect ratio of the reinforcement is considered. To cite this article: L. Cauvin et al., C. R. Mecanique 335 (2007). [Copyright &y& Elsevier]

Abstract: A new mechanism for biaxial tension tests was developed for loading an in-plane reinforced composite laminate or any injection-molded polymeric specimen simultaneously in two principal directions. This mechanism can be adapted to any uniaxial tension test machine and, thereby, it can reduce the cost of conducting tests on expensive dedicated machines. The fixture provides a uniform state of equibiaxial tension, necessary for characterizing the biaxial state of loading on any polymeric material system and it can also be reconfigured to test non-equibiaxial tension over a short range. The mechanism is presently utilized for understanding the failure behavior of injection molded short fiber polyamide and nanoparticle-reinforced PP thermoplastic composites. [Copyright &y& Elsevier]

Abstract: In this second part of a two-part paper, the failure mechanism of polypropylene (PP)/nanoclay composite under fracture loads is presented. The PP/nanoclay composite was prepared via melt compounding in a twin-screw extruder. Maleic anhydride grafted polypropylene (MA-g-PP) was used as a compatibilizer to improve the dispersability of the clay. The PP/clay nanocomposite was characterized by XRD and SEM. XRD results show possibilities of exfoliation, and SEM studies rule out large-scale particle agglomeration. Fractographic observations of PP/clay nanocomposite at lower loading rates reveal that excessive fibrillation and impregnated fibrils arrest crack propagation, and the fracture occurs by void initiation at larger clay particles. As the loading rate increases, crazes combined with voids to accelerate crack propagation. At higher loading rates, cleavage type brittle fracture is observed. [Copyright &y& Elsevier]

Abstract: The chip formation mechanism in orthogonal machining of unidirectional glass fiber reinforced polymer (UD-GFRP) composites is simulated using quasi-static analysis. Dynamic explicit finite element method with mass scaling is used for analysis to speed up the solution. A two-dimensional, two-phase micromechanical model with elastic fiber, elasto-plastic matrix and a cohesive zone is used to simulate the debonding interface between the fiber and the matrix. The elements of the fiber are failed once the maximum principal stress reaches the tensile strength and the matrix elastic modulus is degraded once the ultimate strength is reached. The effect of fiber orientation, tool parameters and operating conditions on fiber and matrix failure and chip size is also investigated. The degradation of the matrix adjacent to the fiber occurs first, followed by failure of the fiber at its rear side. The extent of sub-surface damage due to matrix cracking and interfacial debonding is also determined. [Copyright &y& Elsevier]

This study systematically investigates the effect of Shear Thickening Fluid (STF) treatment on the high strain rate properties of UHMWPE (Ultra High Molecular Weight Poly Ethylene) composites. Spherical nanosilica particles of size 100 nm were used for the synthesis of STF. The high strain rate impact studies were accomplished on in-house designed and fabricated Split Hopkinson Pressure Bar (SHPB) experimental set-up. Compression moulded UHMWPE variant Gold Shield ® was used as the ballistic composite. Both STF-treated as well as neat Gold Shield ® specimens were subjected to high strain rate impact testing. From the experimental results and Fractography studies it was revealed that STF treatment enhanced the ballistic resistance of Gold Shield ® composite material. In the SHPB experiments, the improved ballistic performance of STF-treated Gold Shield ® specimens was manifested in terms of higher peak stress, specimen strain rates and impact toughness. [ABSTRACT FROM AUTHOR]

In the present work, dynamic compression response of polypropylene (PP) based composites reinforced with Kevlar/Basalt fabrics was investigated. Two homogeneous fabrics with Kevlar (K3D) and Basalt (B3D) yarns and one hybrid (H3D) fabric with a combination of Kevlar/Basalt yarns were produced. The architecture of the fabrics was three-dimensional angle-interlock (3D-A). Three different composite laminates were manufactured using vacuum-assisted compression molding technique. The high strain rate compression loading was applied using a Split-Hopkinson Pressure Bar (SHPB) set-up at a strain rate regime of 3633–5235/s. The results indicated that the dynamic compression properties of thermoplastic 3D-A composites are strain rate sensitive. In all the composites, the peak stress, toughness and modulus were increased with strain rate. However, the strain at peak stress of Basalt reinforced composites (B3D, H3D) decreased approximately by 25%, while for K3D specimens it increased approximately by 15%. The K3D composites had a higher strain rate as compared to the B3D and H3D composites. In the case of K3D composite, except strain at peak stress, remaining dynamic properties were lower than the B3D composite, however, hybridization increased these properties. The failure mechanisms of 3D-A composites were characterized through macroscopic and scanning electron microscopy (SEM). [ABSTRACT FROM AUTHOR]

The ballistic impact response of thermoplastic-based composite armors made from Kevlar ® fabric and polypropylene (PP) matrix has been investigated against ballistic test standard NIJ-STD 0106.01 Type IIIA. Kevlar ® fabrics of different architectures, namely 2D plain woven, 3D orthogonal and 3D angle interlock fabrics, were produced and used as reinforcements to fabricate composite armor panels, using compression molding technology. Interfacial property between PP and Kevlar ® was improved by adding a coupling agent called maleic anhydride grafted PP. Reduced density was observed in Kevlar ® thermoplastic-based composites as compared to that of the thermoset-based laminates. Ballistic impact tests were imparted with 9 mm full metal jacket (FMJ) on armor panels having different fabric architecture. Ballistic test results revealed that 2D armor was 2.4–7% more susceptible to damage than 3D armors. Hydrocode simulations were carried out using ANSYS AUTODYN v. 14.0 to obtain an estimate for the ballistic limit velocity and simulate failure modes. Post-impact damage patterns obtained from the simulations were compared with the experimental results to assess the performance of the simulations. Good correlation between the hydrocode simulations and experiments was found, both in terms of failure modes and damage patterns. 3D composite armors were able to confront the 9 mm FMJ projectile; however, the 2D plain woven armors failed. The increase in the ballistic limit from 2D plain woven armor to 3D orthogonal and 3D angle interlock armors was 16.44% and 20%, respectively, indicating the effect of fabric architecture. [ABSTRACT FROM AUTHOR]

Abstract Nanocomposites with platelet reinforcements are emergent materials whose deformation mechanisms still need to be carefully investigated. In this study, we first present the studied class of nanocomposites (Polypropylene reinforced by Montmorillonite clay nanoplatelets). From uniaxial tensile tests, it is shown that some mechanical characteristics of the nanocomposite (Young's modulus, yield stress) significantly increase compared to the matrix even for very low volume fraction of reinforcements (maximum of 7% mass fraction for our tested specimen). The Ponte Castañeda and Willis [6] bound is adopted to account for the evolution of the elastic behavior of the material [71. Adapting the Hill-type incremental method [13] allows the simulation of the non linear behaviour of the material. However, it is shown that this scheme requires careful choice of the aspect ratio, in the plastic domain, to provide good predictions of plasticity. [ABSTRACT FROM AUTHOR]