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3D printing plays an important role in Industry 4.0 and has versatility to use different materials, including thermoplastic polymers. Polylactic acid (PLA), a bio‐based biodegradable polymer, is used as a potential replacement for petroleum‐based polymers in several applications, and is one of the most popular polymers used in 3D printing. Inorganic/organic nanoparticles can be incorporated in polymers to improve various properties such as thermal, mechanical, and tribological. This work investigates the effect of adding carbon black (CB) and alumina (ALM) nanofillers on the thermal, mechanical, and tribological properties of 3D printed PLA nanocomposites for tribological applications. Both nanofillers promoted progressive enhancement of thermal stability according to TGA. The improvement in the interaction between nanofillers and PLA matrix is revealed by an increase in viscosity of the nanocomposites. The nanocomposites containing 25%wt ALM and 75wt% CB presented better mechanical and wear properties, suggesting synergism between nanofillers and that CB may act as a compatibilizer between PLA and ALM. These results enable selecting the most suitable composition of nanofillers to be added to PLA to create filaments with better tribological properties. [ABSTRACT FROM AUTHOR]

Hybrid rubber nanocomposite blends based on (80/20) XNBR/EPDM containing 5 phr Cloisite 10A, 15A 20A, 25A, 93A, 30B, carbon black and silica nanofiller and two types of EPDM-g-MA and ENR 50 containing 5 phr was prepared by a two roll mill. A rheometer test was used to study the curing of the blends, the tensile test was used to study the mechanical strength of the nanocomposite and XRD, FESEM and TEM tests were used to evaluate and observe the morphology of the nanocomposite blends prepared. The results of the rheometer test show that the Cloisite 30B nanofiller, in addition to increasing the torque and optimum cure time, decreased compared to other nanofillers. The results of the XRD test showed that the ENR50 compatibilizer with the Cloisite 30B nanofiller compared to other nanofillers, compared to the EPDM-g-MA compatibilizer, significantly increased the openness of the layers by 2.21 nm. The results of FESEM and TEM confirmed the better distribution of Cloisite 30B nanoparticles in the XNBR/EPDM sample containing ENR 50 compatibilizer. Also, XRD evidence showed that the opening of the nanofiller layers of Cloisite 30B was higher the other nanofillers. This result is consistent with microscopic observations. In addition, all nanoparticles are located in the XNBR phase. The results of the tensile test showed that the modulus and tensile strength of nanocomposite containing Cloisite 30B nanofiller and ENR 50 compatibilizer with other nanocomposites increased. [ABSTRACT FROM AUTHOR]