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2 results on '"Lan, Yu"'

1. Rhodium‐Catalyzed Atroposelective Construction of Indoles via C−H Bond Activation.

Author

Sun, Lincong, Chen, Haohua, Liu, Bingxian, Chang, Junbiao, Kong, Lingheng, Wang, Fen, Lan, Yu, and Li, Xingwei

Subjects
*INDOLE compounds, *RHODIUM, *ANNULATION, *CHIRALITY element, *INDOLE, *FUNCTIONAL groups
Abstract

Reported herein is the rhodium(III)‐catalyzed C−H activation of anilines bearing an N‐isoquinolyl directing group for oxidative [3+2] annulation with four classes of internal alkynes, leading to atroposelective indole synthesis via dynamic kinetic annulation with C‐N reductive elimination constituting the stereo‐determining step. This reaction proceeds under mild conditions with high regio‐ and enantioselectivity and functional group compatibility. [ABSTRACT FROM AUTHOR]

Published
2021
Full Text
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2. Rhodium‐Catalyzed Atroposelective Construction of Indoles via C−H Bond Activation.

Author

Sun, Lincong, Chen, Haohua, Liu, Bingxian, Chang, Junbiao, Kong, Lingheng, Wang, Fen, Lan, Yu, and Li, Xingwei

Subjects
*INDOLE compounds, *RHODIUM, *ANNULATION, *CHIRALITY element, *INDOLE, *FUNCTIONAL groups
Abstract

Reported herein is the rhodium(III)‐catalyzed C−H activation of anilines bearing an N‐isoquinolyl directing group for oxidative [3+2] annulation with four classes of internal alkynes, leading to atroposelective indole synthesis via dynamic kinetic annulation with C‐N reductive elimination constituting the stereo‐determining step. This reaction proceeds under mild conditions with high regio‐ and enantioselectivity and functional group compatibility. [ABSTRACT FROM AUTHOR]

Published
2021
Full Text
View/download PDF

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