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2. Tri-chlorido, 2-methylallyl and 2-butenyl tert-butylimido niobium and tantalum complexes: Synthesis, multinuclear NMR spectroscopy and reactivityThis paper is dedicated to the memory of Dr Amelio Vázquez de Miguel who died April 20, 2010 and whom we remember with affection.
3. Drop-by-drop chemical reaction and sample introduction for capillary electrophoresis.
4. Interfacial tension controlled fusion of individual femtolitre droplets and triggering of confined chemical reactions on demandElectronic supplementary information (ESI) available: Device fabrication and experimental details, droplet shrinkage rates, droplet size distributions as functions of oil channel width, CCD images of formation of silver granules, two dimensional fluorescence distributions corresponding to Fig. 3, bright field movie sequences of acidic and basic droplet fusion events for Fig. 4. See DOI: 10.1039/c0lc00376j
5. Chloride ions enhance furfural formation from d-xylose in dilute aqueous acidic solutions.
6. A new type of iodosulfite ion formulated as I2SO22−Synthesis of 2: to an aqueous solution of 1(100 mL), which was prepared according to previously reported procedures,11SO2-saturated water (40 mL) was added and the solution was cooled to 5 °C. After standing for 12 h, yellow crystals precipitated.X-Ray crystallographic study for 2: X-ray diffraction data (12 432 reflections) were collected at 277 K on a Rigaku/MSC Mercury CCD system using graphite-monochromated Mo-Kα radiation (λ= 0.71073 ). A total of 3568 reflections were unique (Rint= 0.045). A crystal of 2was attached to a glass capillary using epoxy. All calculations were performed using the teXsan crystallographic software package from Molecular Structure Corporation.12The structures were solved by direct methods (SIR-97)13and refined by full-matrix least-squares techniques (SHELXL-97)14against F2. The non-hydrogen atoms were refined anisotropically. Hydrogen atoms were generated theoretically on the specific atoms and not refine
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