1. Effect of Valence Floating on the Magnetic Properties of Ca–Sn Co-Doping Y 3−x Ca x Fe 5−x Sn x O 12 (x = 0–0.25).
- Author
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Yin, Qisheng, Liu, Yingli, Chen, Jianfeng, and Lu, Shifan
- Subjects
- *
MAGNETIC properties , *YTTRIUM iron garnet , *MAGNETIC materials , *MAGNETIC moments , *SPIN polarization , *TIN - Abstract
First-principle calculations were used to simulate the changes in magnetic parameters and interatomic charge density in the crystal structure of yttrium iron garnet (YIG) caused by Ca–Sn co-doping. The simulation results illustrate that Ca and Sn have no spin polarization in the crystal, and the charge density among ions tends to increase with doping concentration. A solid-state reaction method was employed to prepare YIG with varying concentrations of Ca–Sn co-doping. The saturation magnetization ($4\pi M_{s}$) of the material shows an initial increase and then decrease as the number of doping increases. This phenomenon of increment in $4\pi M_{s}$ at first could be accounted for the increase of the net magnetic moment of material. The reduction in $4\pi M_{s}$ could be interpreted as the content of Fe3+ ($5~\mu \text{B}$) decreases, while the Fe2+ ($4~\mu \text{B}$) in the material becomes the primary portion when the concentration of doping exceeds 0.10. [ABSTRACT FROM AUTHOR]
- Published
- 2022
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