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The Parauapebas Formation and Igarapé Cigarra Formation constitute two Neoarchean extrusive units inserted in the metavolcanosedimentary sequence (~2.76 Ga) of the Grão Pará Group, Itacaiúnas Supergroup, being represented by basaltic seeps underlain and overlain by jaspillites, rhyolites, volcanoclastic rocks, and gabbro dikes/sills, thus being inserted in the Serra Sul district in the Mineral Province of Carajás, Pará. This study aimed to understand the igneous processes involved in the genesis of these basalts from both geological formations, supported by field, petrographic, and geochemical data. Inserted in the metavolcanosedimentary sequence of the Grão Pará Group (Carajás Domain), the basalts and basalt andesites, the most abundant types of the Parauapebas and Igarapé Cigarra Formations, occur as successions of massive and amygdaloidal lava flows. The study of core samples from nine stratigraphic holes that intersected basaltic rocks of the two geological formations in body S11D (Serra Sul) showed that these rocks reach thick layers with different characteristics, ranging from aphanitic to phaneritic. The basalts are dark green, aphanitic, phaneritic, thin to medium, and hypocrystalline. They show preserved igneous texture being commonly seriated as inequigranular, intersertal, ophitic, subophytic, intergranular, branching, and swallow tail. Its essential primary constituents are plagioclase, orthopyroxene, and clinopyroxene, and its accessory constituents are titanite and apatite. Chlorite, epidote, quartz, and calcite occur as secondary phases and are interpreted as the products of ocean-bottom hydrothermal alteration and/or incipient metamorphism. In general, the studied volcanic rocks stand out for SiO2 content between 47.00 and 56.04%, high alkali contents (4.70-7.50%), K2O contents between 0.40 and 3.97%, TiO2 (< 1.0%), and MgO between 4.90 and 8.16%. In the classification diagrams, the samples are situated in the fields of basalts, basalt andesites, trachyandesite, and trachybasalt basalts, in the transition of the toleitic and calc-alkaline series. The basalts of the Parauapebas and Igarapé Cigarra Formations were probably formed in an intraplate continental environment influenced by subduction zones. Therefore, the Grão-Pará Basin was probably formed in a convergent regime related to a subduction-type environment. The geochemical data indicate that the studied rocks of the Parauapebas Formation and the Igarapé Cigarra Formation correspond to basalts of calc-alkaline affinity. Two facies were identified in the Parauapebas Formation, namely, the Amendoim and Violão facies. In the Igarapé Cigarra Formation as well, the following facies were identified: Jacaré and Três Marias. Based on the geochemical interpretation, it is assumed that the rocks studied are arc-like continental basalts, which are formed in a subduction environment with influence from a possible asthenospheric source and modified by crustal contamination. [ABSTRACT FROM AUTHOR]

The middle Eocene Fulra Limestone Formation of the Kachchh Basin, western India was investigated to interpret depositional environments and sources of limestones based on facies analysis, mineralogy, and major, trace, and rare earth elements (REEs) geochemistry. Facies stacking pattern of the Fulra Limestone Formation exhibits an overall shallowing‐upward sedimentary succession developed in the middle to inner ramp to lagoonal set‐up. Staining of the thin sections and X‐ray diffraction patterns show dominance of calcite mineral. The CaO, ranging from 40.45% to 49.69%, is the dominant oxide among the major oxides followed by SiO2 (4.04–10.3%). The dominance of CaO over MgO suggests that the major mineral phase has been calcite and no dolomitization occurred during the deposition of the Fulra limestone. The low proportion of SiO2 and Al2O3 suggests low siliciclastic input during the precipitation of the Fulra limestone that is confirmed by the positive correlation of ∑REE with Al2O3, Fe2O3, Ni, Th, Sc, and Y and the negative correlation of SiO2, Al2O3, and Sr with CaO. The average value of REE contents in the Fulra Limestone Formation are lower (*16.02 ppm) than the average value of typical marine carbonates (*28 ppm). The Post‐Archean Australian Shale‐normalized REE + Y patterns of the Fulra limestone exhibit seawater like shale‐normalized REE + Y pattern, whereas slightly lower average value of Y/Ho ratio (34.60) than the typical seawater value (~44–74) suggests modification of the seawater, to some extent, by input of freshwater in a coastal environment. The REEs of the Fulra Limestone Formation have similarity with the carbonates of the Arabian Sea and/or shallow marine carbonates with exception of a few elements. It is envisaged from this study that the Fulra limestone was deposited in a shallow marine to coastal set‐up where mixing of the continental material in seawater was feasible. [ABSTRACT FROM AUTHOR]

Abstract The exceptionally organic-rich rocks of the 1.98 Ga Zaonega Formation deposited in the Onega Basin, NW Russia, have refined our understanding of Earth System evolution during the Paleoproterozoic rise in atmospheric oxygen. These rocks were formed in vent- or seep-influenced settings contemporaneous with voluminous mafic volcanism and contain strongly 13C-depleted organic matter. Here we report new isotopic (δ34S, Δ33S, Δ36S, δ13C org) and mineralogical, major element, total sulphur and organic carbon data for the upper part of the Zaonega Formation, which was deposited shortly after the termination of the Lomagundi-Jatuli positive carbon isotope excursion. The data were collected on a recently obtained 102 m drill-core section and show a δ13C org shift from −38‰ to −25‰. Sedimentary sulphides have δ34S values typically between +15‰ and +25‰ reflecting closed-system sulphur isotope behaviour driven by high rates of microbial sulphate reduction, high sulphate demand, hydrothermal activity and hydrocarbon seepage. Four intervals record δ34S values that exceed +30‰. We interpret these unusually 34S-enriched sulphides to be a result of limited sulphate diffusion into pore waters due to changes in sedimentation and/or periods of basinal restriction. Additionally, there are four negative δ34S excursions that are interpreted to reflect changes in the open/closed-system behaviour of sulphate reduction or availability of reactive iron. Our findings highlight the influence of basinal processes in regulating sulphur isotope records and the need for care before interpreting such signals as reflecting global conditions. Highlights • Zaonega Formation Δ33S-δ34S data track basin-specific rather than global processes. • Opposing Δ33S-δ34S relationship relates to rapid microbial sulphate reduction. • Positive δ34S excursions reflect partial basinal restriction. [ABSTRACT FROM AUTHOR]

Rare earth element (REE) and Y concentrations, and 87Sr/86Sr ratios were analyzed in 33 carbonate samples from the Paleogene Shahejie Formation in the Qikou depression, eastern China, with the goal of determining depositional environments and post-depositional conditions of carbonates in the region. The REE and Y concentrations were normalized to the post-Archean Australian shale (PAAS) standard. The La*PAAS/Yb*PAAS ratios of 0.35-1.52, where *PAAS indicates values for the PAAS standard, show light REE enrichment and heavy REE depletion in most samples. Values of La*PAAS (0.775-1.284) and Ce*PAAS (0.822-1.224), coupled with a relatively flat REE distribution, indicate that the Shahejie carbonates were deposited in lacustrine environments. Values of Y anomalies (1.009-1.527) and Y/Ho ratios (28.43-45.00) in the Shahejie Formation are greater than those of lacustrine carbonates and closer to those of marine carbonates, indicating that diagenetic fluids were probably influenced by seawater. In the carbonates from Well Kou-42, Eu anomalies (1.171-1.604), 87Sr/86Sr ratios (0.708 001-0.710 893), and high homogenization temperatures (104-151 ºC) suggest that the carbonates were affected by hydrothermal fluids. The REEs and Sr isotope ratios show that the carbonates from the Shahejie Formation in the Qikou depression were deposited in lacustrine environments, and were influenced by seawater and hydrothermal fluids. [ABSTRACT FROM AUTHOR]

The type section of the Hume Formation (114.6 m), located along the Hume River in western Northwest Territories, is examined in detail for its conodonts and benthic fossils. For the most part it consists of a late Eifelian (early Middle Devonian) kockelianus Zone age, with short intervals of australis and ensensis zones at its base and top, respectively. Three benthic assemblage zones are recognized, in ascending order, Eoschuchertella adoceta, Carinatrypa dysmorphostrota, and Eliorhynchus castanea. The ranges of selected benthic fossils suggest transgression and regression, which are in agreement with three T-R cycles of Johnson, Klapper and Sandberg (1985) and Johnson andKlapper (1992), namely Id, Ie, and If. Cycle Id occurs at the base of the Hume Formation, at contact with the underlyingGossage Formation, and iswithin the australis Zone. Cycle Ie is about midway in the Hume Formation, within the kockelianus Zone. Cycle If, at the top of theHume Formation, signals the entry of the ensensis Zone and the Kačák Episode,with the deposition of the overlying Hare Indian Formation. [ABSTRACT FROM AUTHOR]

The results of geochemical, mineralogical, and isotope (U-Pb and Sm-Nd) studies of metasedimentary manganese-bearing rocks from the Itantsa Formation of the Ikat terrane are presented. It is found that the carbonate-effusive-shale complex of the Itantsa Fm. formed under the continental margin environment, with volcanic activity accompanying sedimentation, in the interval of 650-540 Ma ago. [ABSTRACT FROM AUTHOR]

The data of geochemical study of Late Triassic cherts from tectonic-sedimentary complexes from different structural levels of the Samarka Terrane are reported. It is shown that the concentration and character of distribution of the major petrogenic oxides and minor and rare-earth elements in cherts of the upper and lower structural levels differ significantly, which results from differences in the facies environments of chert deposition. All the geochemical characteristics of cherts show that their deposition proceeded in the pelagic area of sedimentation, but in different parts. The Katen Complex composing the lower structural level is the most distant from the continental margin. The closest is the Amba-Matay Complex composing the upper structural level. Based on the geochemical and biostratigraphic data and the age of accretion of paleooceanic fragments, the length of the subducted oceanic plate (>6000 km) is calculated. [ABSTRACT FROM AUTHOR]

The Late Jurassic deposits of the Boulonnais area (N-France) represents the proximal lateral-equivalent of the Kimmeridge Clay Formation; they accumulated on a clastic-dominated ramp subject to synsedimentary faulting in relation with the northward propagation of the Atlantic rifting. Within the terrigenous accumulations, some carbonate objects are visible at various conspicuous levels: oyster patch reefs and fine-grained carbonate beds, either continuous, or more or less nodular. Preliminary studies demonstrated that the carbonate beds of the Bancs Jumeaux Formation as well as the carbonate matrix of the oyster patch reefs are of diagenetic origin. In this paper, we extend the study to many other limestone beds of the Boulonnais with mud- or wackestone texture, examining facies and microfacies through various techniques as well as geochemical data (O, C and S stable isotopes, major and trace elements). We conclude that all examined carbonate bodies are of early diagenetic origin and that they precipitated at, or close to, the sea bed, from seawater mixing with ascending fluids containing isotopically light carbon of organic origin. Fluid circulation was probably induced by the extensional block-faulting segmentation of the northern margin of the Boulonnais Basin in Late Jurassic times. Fluid seepages were either channelized along fault planes or more diffuse, as illustrated by the model we propose. [ABSTRACT FROM AUTHOR]

Sandstone petrography and mudstone mineralogy and geochemistry of the Late Oligocene–Early Miocene terrigenous deposits of the Macigno Fm. of the Trasimeno Lake area (Central Italy) provide new information on provenance, paleoenvironment, palaeoclimate, and geodynamics during the early stages of the northern Apennines foreland basin setting. Sandstones are rich in trace fossils and are quartzofeldspatic with various crystalline phaneritic (mostly granitoids) and medium-low grade metamorphic rock fragments. Volcanic and sedimentary lithic fragments are rare. The mudstone mineralogy contains a large amount of phyllosilicates, quartz, and feldspars and small amount of calcite, which increases in the mid-part of succession. Palaeoweathering indices (Chemical Index of Alteration with and without CaO value; CIA and CIA' respectively) suggest a source area that experienced low to moderate weathering and low recycling processes (on average, CIA = 66.4 and CIA' = 69.7). Furthermore, very low and homogeneous values of Rb/K ratios (<0.006) suggest weak to moderate weathering conditions. The sandstone and mudstone composition reflects a provenance derived from uplifted crystalline rocks. The different amount in feldspars, the variety of lithic fragments, the occurrence of mafic and carbonate input, coupled with evidence of multi-directional flows, suggest a provenance from different source areas. The geochemical proxies indicate a provenance from both felsic and mafic sources, predominantly for the Maestà section that shows Cr/V values ranging from 1.15 to 3.36 typical of source areas composed of both felsic and mafic rocks. The Western-Central Alps are inferred to be the main source area of the Macigno foreland system, but significant signals from the Mesomediterranean Microplate are also testified. These new data suggest that the Macigno Fm. was probably located in a peculiar area which received either distal fine turbidite flows from the northernmost Alpine area and residual sandy debris flows coming from the westernmost Alps. [ABSTRACT FROM AUTHOR]

Bitumens from carbonaceous shales of various ages of the Baikal-Patom highlands and the Degdekan deposit (Yana-Kolyma folded system) were considered. It was determined that bitumens of the Bodaibo synclinorium are mainly represented by asphaltenes, asphaltogenic acids, and hydrocarbons; bitumens of the Degdekan field are represented predominantly by hydrocarbons. [ABSTRACT FROM AUTHOR]