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Cubic Cu 2 O micro/nanocrystals were successfully synthesized by liquid-phase reduction using copper salt of CuSO 4 or CuCl 2 ·2H 2 O, and glucose or ascorbic acid as reducing agent, respectively. The activity of the catalysts was evaluated by light-off curves of CO self-sustained catalytic combustion via temperature-programmed oxidation of CO (CO-TPO), with the results showing the activity of catalysts following the order of Cu 2 O–Cl-GLU > Cu 2 O– S -GLU > Cu 2 O– S -AA > Cu 2 O–Cl-AA, (Cl denotes CuCl 2 ·2H 2 O, GLU denotes glucose, S denotes CuSO 4 and AA denotes ascorbic acid, respectively), corresponding to the ignition temperature of 109 °C, 122 °C, 137 °C and 186 °C, respectively. The crystal structure, elemental valence, morphology and redox property of the prepared catalysts were analyzed by using various characterization techniques. Combined with in situ infrared spectrum, the CO self-sustained catalytic combustion over Cu 2 O catalysts mainly follows the Mars-van-Krevelen (M-v-K) mechanism: the adsorbed and activated CO reacts with lattice oxygen to yield CO 2 and oxygen vacancy, and then the oxygen vacancy can be replenished by gaseous oxygen. Combined with catalytic performance of high-concentration CO, it is found that the catalysts prepared using glucose as reducing agent are more angular compared with ascorbic acid. The Cu 2 O–Cl-GLU synthesized with glucose and CuCl 2 ·2H 2 O exhibits the best catalytic activity among all the catalysts tested, attributing to its more obvious edge and rough crystal surface. The unique structure of Cu 2 O–Cl-GLU leads to the high exposure rate and coordination unsaturation of atoms on the cubic Cu 2 O micro/nanocrystals that can improve the ability of activating gaseous O 2 and low temperature reducibility, and consequently facilitating the catalytic activity. Cycle path diagram of CO oxidation reaction (a) and schematic diagram of CO oxidation reaction on Cu 2 O (b). [Display omitted] • Effects of reducing agent on catalytic properties is greater than that of copper salt. • High concentration CO can achieve self-sustained catalytic combustion on obtained Cu 2 O. • Glucose enhances unsaturation of Cu atoms contributing to high activity. • Chemically adsorbed oxygen on Cu 2 O surface promotes CO ignition. [ABSTRACT FROM AUTHOR]

• The powder sample is well designed and coated on the HC tube to form CuCe 0.75 Zr 0.25 O δ /HC catalyst. • The transient changes and two-dimensional temperature region are obtained for CO self-combustion via CO-TPO + FLIR. • The various intermediate species and competitive adsorption of reactants on different active sites are evidenced. • The different pathways and roles of M-K and L-H mechanisms are proposed using in situ IR. A CuCe 0.75 Zr 0.25 O δ catalyst was prepared by the sol-gel method and successfully coated on honeycomb ceramic (HC) carrier. The activity of CuCe 0.75 Zr 0.25 O δ /HC was determined by the CO-TPO + FLIR, with the results performing that the critical condition for CO self-sustained combustion is 3 vol% CO + 3 vol% O 2 /N 2 at 0.5 L/min. As the CO concentration increases from 1 vol% CO to 3 vol% CO, the induction process (T 15) shifts to rapid ignition with a transient change for the CO oxidation reaction. The furnace temperature for CO self-sustained combustion decreases with increasing the CO and O 2 concentrations. Upon increasing the CO 2 concentration, however, furnace temperature is needed to increase and realize CO complete conversion. The thermal stability test combined with SEM + EDX results indicate that the CuCe 0.75 Zr 0.25 O δ /HC retains an excellent thermal stability after a 200 h, and the high-temperature region remains at 225 ± 1 °C during the CO self-combustion reaction. The activity of catalyst is reduced slightly after the 200 h test because of the carbon deposition on the catalyst surface, but such a slight deactivation can be eliminated by the air oxidation method. In situ IR results show a competitive adsorption of CO/O 2 and CO 2 on the Cu-Ce active sites, indicating that the addition of gaseous CO 2 performs an inhibition of CO oxidation. CO preferentially adsorbs linearly at Cu+ sites to form carbonyls that react with lattice oxygen to produce CO 2 to release, which can be ascribed to M-K mechanism. The L-H mechanism is less important, which involves the relatively weak reaction of adsorbed CO and adsorbed oxygen on the Cu-Ce active sites to form carbonate species. [ABSTRACT FROM AUTHOR]