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Flexible piezoelectric sensors have received widespread attention in wearable electronics for their ability to convert mechanical energy into electrical energy, while the insufficient output power and complex preparation process have limited their application. In this work, several honeycomb structures based on graphene macro-film (GAMF) were created via laser engraving, which can utilize negative Poisson's ratio (NPR) properties to improve the output electric performance of flexible piezoelectric sensors. The effect of different electrode materials on the piezoelectric output was investigated in the experiments and compared with the theoretical equations, indicating that the output power of the sensor could be enhanced up to 142 % by improving the materials auxetic mechanical properties. The stability tests have proven that the sensors can operate effectively for a long time under different operating conditions. Moreover, the optimized sensor shows powerful potential for monitoring human movements such as finger tapping, joint bending, and foot stepping. This work opens up a new development path for the preparation of convenient and high-performance wearable electronic devices. The negative Poisson's ratio characteristic of the honeycomb graphene macro-film is used to increase the deformation of PVDF film to increase the electrical output performance of the flexible piezoelectric sensor. The optimized sensor can be used to detect human movements. [Display omitted] • Honeycomb graphene macro-films with different mechanical properties were prepared by laser engraving. • Flexible piezoelectric sensors based on honeycomb graphene macro-films are prepared. • The output performance of piezoelectric sensors can be improved by adjusting mechanical properties of electrode materials. • The flexible piezoelectric sensors can be used to detect human movements. [ABSTRACT FROM AUTHOR]

• A class of modified hexagonal honeycomb to realize pattern transformation. • Honeycomb's elastic constants are derived by theoretical energy analysis. • Honeycomb structures exhibit auxetic behavior after pattern transformation. • The cell/node of the honeycomb has a rotating behavior after pattern transformation. • The underlying mechanism of pattern transformation is revealed for honeycomb. Pattern transformation, as one of the special properties of mechanical metamaterials, is widely found in elastic porous structures and gradually expanding to honeycomb structures. Inspired by the higher-order flower-like buckling pattern of hexagonal honeycomb, and generalizing the geometry of structures that pattern transformation occurs under uniaxial compression, this paper proposes a Modified Hexagonal Honeycomb(MHH) structure by adjusting the thickness ratio α and the deflection extension angle θ of the cell wall to topologically reconstruct the honeycomb structure to initiate the first-order quasi-flower-like buckling pattern under uniaxial loading. Results show that the quasi-flower-like pattern transformation appears directly for the MHH structure under uniaxial compression, accompanied with a transition of the Poisson's ratio, from positive to negative. And the butterfly pattern, which appears for traditional hexagonal honeycomb only under biaxial loading, is also observed for the MHH under uniaxial compression. The relative size of the nodes among cell walls is believed to play a crucial role on the appearance of the pattern transformation of the honeycomb structure. This work has revealed the underlying physical mechanism for pattern transformation of honeycomb structures, and would also extend the application range of honeycomb structures to the design of elastic dampers, bending/torsion actuators, or robot drive joints. [ABSTRACT FROM AUTHOR]

[Display omitted] • Spinal interbody cages adapted for an auxetic, and honeycomb using standard CAD software operations and manufactured with SLM. • Auxetic-based cages exhibit higher strength properties than honeycomb-based cages. • The stiffness of the auxetic cages is comparable to stiffness of human cortical bone. • The honeycomb cages exhibit lower value of Young's modulus closer to that for vertebrae. This paper presents a method for modeling a biomedical device by adaptation a commercially available interbody cage for an auxetic metamaterial and honeycomb structure using standard operations in Computer-Aided design software. The mechanical properties of experimental prototypes of Ti-6Al-4 V cages made by selective laser melting using computer modeling (finite element analysis), static and low-cycle fatigue compression tests (up to 3500 cycles) are characterized. 3D printed cells with structures with an angle of inclination between cell edges of less than 90˚ (auxetic metamaterial) are shown to exhibit higher static compressive strength and fatigue resistance than cells based on structures with an angle of inclination greater than 90˚ (honeycomb structure). The changes in the inclination angle differently affect to the porosity and consequently to mechanical behavior of auxetic metamaterial and honeycomb structure. The Young modulus of the auxetic-based interbody cage is 6.68 ± 0.28 GPa and comparable to the elastic modulus of human cortical bone. The honeycomb-based cage exhibits lower values of Young modulus (1.19 ± 0.03 GPa) close to that of trabecular bone and vertebrae. Importantly, the auxetic-based cage is not destroyed after 3500 cycles under 14 kN load with residual deformations ≤ 1 % (0.21 ± 0.10 mm displacements). [ABSTRACT FROM AUTHOR]