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A novel material, Tris coated magnetic nano structured adsorbent (T-MNSA) was synthesized using incipient wetness impregnation method for removal of bisphenol A (BPA). T-MNSA maximum adsorption capacity was 160 mg/g and sorption density was 0.078 mole BPA/mole of Tris. In addition, degradation using ultrasound assisted bismuth ferrite (BF) sono-catalyst was studied for removal and cost efficiency differences. The degradation results show a complete removal of BPA at condition of 0.10 g/l of BF, 100% power, and 72 kHz frequency. The mechanism study reveals that T-MNSA forms biomolecules and covalently attaches to BPA, but BF generates large amount of H2O2 molecules and breaks down BPA to non-toxic CO2 and water. Cost analysis study reveals that T-MNSA is more economical than BF due to lower production and removal cost, almost ten times lower than degradation process using BF, and the material can be commercially produced in bulk quantities. [ABSTRACT FROM AUTHOR]

Abstract In this study two deep eutectic solvents (DESs) were prepared using ethylene glycol (EG) and two different ammonium-based salts. The potential of these DESs as novel agents for CNTs functionalization was examined by performing a comprehensive characterization study to identify the changes developing after the functionalization process. The impact of DESs was obvious by increasing the surface area of CNTs to reach 197.8 (m2/g), and by adding new functional groups to CNTs surface without causing any damage to the unique structure of CNTs. Moreover, CNTs functionalized with DESs were applied as new adsorbents for the removal of methyl orange (MO) from water. The adsorption conditions were optimized using RSM-CCD experimental design. The kinetics and the equilibrium adsorption data were analyzed using different kinetic and isotherm models. According to the regression results, adsorption kinetics data were well described by pseudo-second order model, whereas adsorption isotherm data were best represented by Langmuir isotherm model. The highest recorded maximum adsorption capacity (q max) value was found to be 310.2 mg/g. Graphical abstract Image 1 Highlights • DESs were used as functionalization agents for CNTs. • DES-CNTs combination was introduced as new adsorbent for Methyl orange (MO). • The dispersion of CNTs was enhanced after functionalization with DESs. • The highest maximum adsorption capacity of DES-CNTs adsorbent was 310.2 mg/g. [ABSTRACT FROM AUTHOR]

In the recent decade, deep eutectic solvents (DESs) have occupied a strategic place in green chemistry research. This paper discusses the application of DESs as functionalization agents for multi-walled carbon nanotubes (CNTs) to produce novel adsorbents for the removal of 2,4-dichlorophenol (2,4-DCP) from aqueous solution. Also, it focuses on the application of the feedforward backpropagation neural network (FBPNN) technique to predict the adsorption capacity of DES-functionalized CNTs. The optimum adsorption conditions that are required for the maximum removal of 2,4-DCP were determined by studying the impact of the operational parameters (i.e., the solution pH, adsorbent dosage, and contact time) on the adsorption capacity of the produced adsorbents. Two kinetic models were applied to describe the adsorption rate and mechanism. Based on the correlation coefficient (R2) value, the adsorption kinetic data were well defined by the pseudo second-order model. The precision and efficiency of the FBPNN model was approved by calculating four statistical indicators, with the smallest value of the mean square error being 5.01 × 10−5. Moreover, further accuracy checking was implemented through the sensitivity study of the experimental parameters. The competence of the model for prediction of 2,4-DCP removal was confirmed with an R2 of 0.99. [ABSTRACT FROM AUTHOR]