1. Design of high-performance wood-derived N-doped ECR electrocatalysts based on Marcus theory.
- Author
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Yu, Feihan, Wang, Wenxuan, Shi, Yimin, Li, Yudong, Liang, Daxin, Du, Minshu, and Liu, Feng
- Subjects
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CARBON dioxide reduction , *DOPING agents (Chemistry) , *ELECTROLYTIC reduction , *INDUSTRIAL capacity , *ELECTROCATALYSTS , *MELAMINE - Abstract
Electrochemical reduction of CO 2 over wood-derived metal-free N-doped carbon electrocatalysts provides a new route for converting CO 2 into value-added fuels However, it is a challenge to efficiently design and screen high-performance electrocatalysts. In this paper, we combined the Marcus equation with the theory of thermal-kinetic correlation to successfully predict the optimal N-C doping ratio. Poplar wood -derived 3D N-doped graphitized carbon with optimal N doping content (pyridine-N 1.87 at%, pyrrole-N, 1.52 at%), high specific surface area (471.2 m2 g−1), and abundant nanopores were successfully obtained with the assistance of melamine (N source), which exhibited a high ECR activity of 86.78 % at a low applied potential of −0.71 V (vs. RHE) and long-term stability of at least 10 cycles. This extends the application of the Marcus equation and improves new ideas for the future design of high-performance electrocatalysts. [Display omitted] • "Thermodynamic-kinetic-N/C doping ratio" curve established. • The accuracy of the "thermodynamics-kinetics -N/C doping ratio" curve is verified. • PB-NC4 shows high industrial potential. [ABSTRACT FROM AUTHOR]
- Published
- 2024
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