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Our paper investigates the problems of co-combustion of select grades of biomass, i.e. hay, straw, and wood waste, with natural gas. Research comprised both a laboratory experiment and numerical simulations with the use of a professional software application, Chemkin-Pro. The chemical mechanism of co-combustion of biomass with natural gas was described using 224 reactions and 56 chemical compounds. Based on the flow data determined on an experimental stand, the initial conditions were formulated and numerical simulations were performed. As a result of numerical simulations, the detailed chemical composition of combustion gas at the heating chamber outlet was obtained. The investigation has shown that the use of biomass for energy perposes significantly contributes to the reduction of pollutant emissions in flue gas. [ABSTRACT FROM AUTHOR]

Abstract The main problem and also challenge was to find a satisfactory effective tool for real-time control the torrefaction/pyrolysis process of biomass and to evaluate (also in real-time conditions) biochar quality. This paper presents results from investigation on a new method for both evaluating biochar quality and control biomass thermal processing at temperatures of 300, 350 and 400 ◦ C. Thermal processing of biomass in this temperature range is torrefaction and pyrolysis. Investigation was focused on processing Virginia Mallow (Sida Hermaphrodita) energetic crops. Several strong correlations were observed as follows: carbon and hydrogen content in biochar (charcoal), oxygen content, ash and volatile matter from biochar, calorific value and temperature of the process and finally, acetic acid in condensate and carbon content in the biochar. The results show that the content of acetic acid, being one of the major compounds present in the condensate (black liquor, biooil), is in satisfactory linear correlation with the process temperature and furthermore, with carbon content in biochar. The mathematical description for this polynomial function was proposed as follows: Carbon (%) = 0.6e-3 x Acetic Acid (ppm)+49.5. The correlation between acetic acid in black liquor and carbon in biochar was used to introduce a new method which can be considered as a diagnostic tool for determining biochar quality in real-time conditions during biomass thermal processing. Hence, carbon content in biochar as well as its calorific value can be determined by measuring percentage of acetic acid in the condensate. This correlation was considered as the main novelty presented here. This method provides relatively fast evaluation of quality of biochar produced in industrial scale torrefaction systems, what makes it possible to optimize process parameters (temperature, retention time) in real time conditions and improve biochar production process in this way. Highlights • C H tradeoff for biochar is in strong linear negative correlation. • Acetic acid in biooil increased from 5 to 25% with process temperature increase. • Acetic acid in biooil is verifiable correlated with carbon content in biochar. • Acetic acid vs. carbon correlation can be used to control biochar quality. [ABSTRACT FROM AUTHOR]

This review comprehensively examines biochar, an essential material in an era of climate change for reducing carbon dioxide (CO2) emissions into the atmosphere. It is inconspicuous, black, lightweight, and very porous, and is produced through the thermal conversion of biomass. Our literature review highlights biochar's expansive application possibilities. Firstly, its potential to improve soil quality and sequester CO2 has been examined, as well as its utilization in iron and steel manufacturing to minimize the quantity of coke and ultimately reduce CO2 emissions. In industrial manufacturing, the complete elimination of coke can promote environmental neutrality, which is achieved using biochar from biomass for its extrusion. Furthermore, biochar is becoming increasingly significant in modern energy storage technologies and as an important additive in Pickering emulsions, which are also employed in energy storage systems. Additionally, the use of carbon black is a broad topic, and this review illustrates where it can be successfully utilized, especially in environmentally sensitive areas. [ABSTRACT FROM AUTHOR]

As known, dried sewage sludge, is a by-product produced from waste water treatment, contains significant amounts of organic content, and makes up to 60% with overall calorific value from 9 to 12 MJ/kg. Hence, it can be considered as material for thermal processing focusing on heat and power production. Among thermal conversion technologies, gasification is seen as the effective one because it can be easily combined with heat and power cogeneration units. On the other hand, due to high mineral content (40–50%) in the sludge, it is difficult to be gasified and obtain syngas with calorific value satisfactory enough for fueling the internal combustion engine. The dried sludge can be subjected to be gasified at temperature above 850 °C. However, large amounts of mineral content do not provide favorable conditions to obtain this required temperature. Thus, it is proposed to enrich the sewage sludge with biomass characterized with significantly higher calorific value. In the article, co-gasification of sewage sludge and Virginia Mallow—energetic crops was investigated. Results from experimental and numerical investigation have been presented. The dried sewage sludge enriched with Virginia Mallow at a mass ratio of 0/100%, 50/50% and 100/0% in tests and in the range from 0 to 100% for theoretical analysis was applied in order to achieve effective gasification process. As observed, lignocellulosic biomass like Virginia Mallow contains low amounts of mineral content below 2%, which makes it appropriate for thermal processing. It contributes to more stable and efficient gasification process. Additionally, Virginia Mallow caused that the process temperature possible to achieve, was 950 °C. Thus, sewage sludge was mixed with this high-energy component in order to improve the gasification parameters and obtain syngas with higher calorific value. A zero-dimensional, two-zone model was developed with aid of the POLIMI kinetics mechanism developed by CRECK Modeling Group to simulate gasification of low calorific substances enriched with high calorific biomass. Obtained results showed that sewage sludge can be completely gasified at presence of Virginia Mallow. Syngas calorific value of approximately 5 MJ/Nm3 was produced from this gasification process. The maximal percentage of Virginia Mallow in the mixture with the sewage sludge was set at 50% due to economic aspects of the technology. It was found, that satisfactory conditions for effective gasification were achieved at this 50/50% percentage of sewage sludge and Virginia Mallow. Potential intensity of gasification was predicted from this 0-D 2-zones model, which calculates area of reduction zone to area of combustion zone. This reduction-to-combustion area ratio for the sewage sludge-Virginia Mallow mixture was estimated at value of 2. Finally, the model was successfully verified with results from tests, hence it was proposed as a tool for preliminary investigation on poor fuels gasification. [ABSTRACT FROM AUTHOR]

A novel approach, linking both experiments and modelling, was applied to obtain a better understanding of combustion characteristics of torrefied biomass. Therefore, Pine, Acacia and Miscanthus giganteus have been investigated under 260 °C, 1 h residence time and argon atmosphere. A higher heating value and carbon content corresponding to a higher fixed carbon, lower volatile matter, moisture content, and ratio O/C were obtained for all torrefied biomass. TGA analysis was used in order to proceed with the kinetics study and Chemkin calculations. The kinetics analysis demonstrated that the torrefaction process led to a decrease in Ea compared to raw biomass. The average Ea of pine using the KAS method changed from 169.42 to 122.88 kJ/mol. The changes in gaseous products of combustion were calculated by Chemkin, which corresponded with the TGA results. The general conclusion based on these investigations is that torrefaction improves the physical and chemical properties of biomass. [ABSTRACT FROM AUTHOR]

The article presents the possibilities of effective management of lignocellulosic waste by including it in the circular economy. The pyrolysis process was chosen as the thermal conversion method. This approach, due to a high flexibility of the obtained products, better quality of the solid residue (char), and the lower emission of pollutants into the atmosphere, e.g., SO2 and NOx, is a competitive solution compared to combustion process. Wood waste from alder and pine were analyzed. As part of laboratory tests, the elementary composition was determined, i.e., C, H, N, S, and O. The pyrolysis process was carried out at a temperature of 600 °C on an experimental stand for the conversion of solid fuels in a stationary bed. For the obtained data, using the Ansys Chemkin-Pro calculation tool, the detailed chemical composition of gaseous products of the pyrolysis process was modeled for a varying temperature range and residence time in the reactor. The studies have shown that for certain process conditions it is possible to obtain a high calorific value of pyrolytic gas, up to 25 MJ/m3. [ABSTRACT FROM AUTHOR]