Search

The optimization of the quantum efficiency of single-molecule light-driven rotary motors typically relies on chemical modifications. While, in isolated conditions, computational methods have been frequently used to design more efficient motors, the role played by the solvent environment has not been satisfactorily investigated. In this study, we used multiscale nonadiabatic molecular dynamics simulations of the working cycle of a 2-stroke photon-only molecular rotary motor. The results, which display dynamics consistent with the available transient spectroscopy measurements, predict a considerable decrease in the isomerisation quantum efficiency in methanol solution with respect to the gas phase. The origin of such a decrease is traced back to the ability of the motor to establish hydrogen bonds with solvent molecules. The analysis suggests that a modified motor with a reduced ability to form hydrogen bonds will display increased quantum efficiency, therefore extending the set of engineering rules available for designing light-driven rotary motors. Increasing the rotational efficiency of single-molecule light-driven rotary motors often relies on chemical modifications aimed at eliminating the factors that hinder rotation. Using multiscale nonadiabatic simulations, the authors investigate the transient conformations assumed by the motor molecule during its operation in a solvent and examine possibilities for enhancing the motor's efficiency by blocking certain solvent-solute interactions that restrain successful completion of the rotational movement. [ABSTRACT FROM AUTHOR]

It is estimated that 72% of the worldwide primary energy consumption is lost as waste heat. Thermoelectric Generators (TEGs) are a possible solution to convert a part of this energy into electricity and heat for space heating. However, for their deployment a proven long-term operation is required. Therefore, this research investigates the long-term stability of TEGs on system level in air and argon atmosphere under thermal cycling up to 543 K. The layout of the examined test objects resembles a TEG in stack design. The results show that the maximal output power of the test object in air reaches a plateau at 57% of the initial power after 50 cycles caused by an increased electrical resistance of the system. Whereas the test object in argon atmosphere shows no significant degradation of electrical power or resistance. The findings represent a step towards the understanding of the long-term stability of TEGs and can be used as a guideline for design decisions. [ABSTRACT FROM AUTHOR]

Cosmic dust transports information about the composition and evolution of distant realms over space and time. Dust sources may be in our local neighbourhood, such as the surfaces of moons and small bodies, or further away, in the galactic environment. The interior of moons like Io or Enceladus are well known dust sources in our solar system. Dust grains are therefore like probes, giving us the opportunity to investigate these objects at a distance. Thus, a new field of activity has been born: Dust Astronomy. The ultimate tool for Dust Astronomy is a dust observatory which was never been flown so far. Until today, all our knowledge is based on smaller individual dust detectors flown on various interplanetary spacecraft. Recently, a new generation of dust telescopes, which can be combined to a full dust observatory, became available. The scientific goal of such an observatory is to characterise our micrometeoroid environment with high precision and sensitivity and to record an inventory of various dust populations from asteroidal, cometary and interstellar dust sources. Two competitive studies on a Dust Astronomy mission were performed as part of a master's course, including mission analysis and spacecraft design. The goal was to demonstrate the feasibility of an observatory reaching the main asteroid belt with a minimum spacecraft mass using electric propulsion. Additional secondary payloads supporting the primary objective were selected as well. The results prove that small probes with less than 700 kg mass are capable of placing an array of dust telescopes deep in the asteroid belt, leading to a huge leap in Dust Astronomy and our knowledge about the local dust environment. • First presentation of feasibility studies for a dust observatory between Earth and asteroid belt. • A dust observatory is a tool for dust astronomy and studies interplanetary and interstellar dust fluxes in our solar system. • The observatories reach the asteroid belt within 7 years using electric propulsion. • Two full mission studies were performed by a small satellite project. [ABSTRACT FROM AUTHOR]