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1. Supramolecular Assembly and Binding in Aqueous Solution: Useful Tips Regarding the Hofmeister and Hydrophobic Effects.

Author

Gibb, Bruce C.

Subjects
*SUPRAMOLECULAR chemistry, *SOLUTION (Chemistry), *ORGANIC solvents, *MOLECULAR self-assembly, *WATER, *ORGANIC compounds
Abstract

The self-assembly of structurally discrete entities, and supramolecular chemistry in general, continues to expand into the aqueous realm. To do so, however, requires a firm understanding of the properties of aqueous solution, and how these 'change the rules' for binding and assembly relative to organic solvents. In this mini-review we highlight the state-of-the-art understanding of the supramolecular properties of water, and how these influence the design of hosts and self-assembling systems. [ABSTRACT FROM AUTHOR]

Published
2011
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