Search

Highlights: [•] Hydrates of alkaline earth metal complexes with 5-TPC and Phen ligands are binuclear. [•] Hydrates of alkaline earth metal complexes with 5-TPC and Phen ligands are isomorphous. [•] Transition metal complexes of divalent Mn and Pd with these ligands are mononuclear. [•] These hydrate structures form supramolecular architectures via a hydrogen-bridged network. [Copyright &y& Elsevier]

Highlights: [•] Two paddle wheel typed two Cu(II) complexes have been synthesized. [•] The complexes have been characterized by IR, EPR and X-ray diffraction studies. [•] It is interesting that complexes (1) and (2) differ in the axial coordinated solvent. [•] Influences of the axial solvents on supramolecular architectures are investigated. [Copyright &y& Elsevier]

Abstract: In the present study 1,2-bis(4-pyridyl)ethane (BPA) crystallizes with 2-chlorobenzoic acid (2CBA), 4-methylbenzoic acid (4MBA), phthalic acid (PA), succinic acid (SA) and adipic acid (AA) to yield co-crystals BPA.2CBA (1), BPA.4MBA (2), BPA.PA (3), BPA.SA (4) and BPA.AA (5) respectively. All the five co-crystals are constituted by the utilization of the (7) synthon, created by the combination of hard N-H⋯O and complementary soft C–H⋯O hydrogen bonds. 1 and 2 illustrate the formation of three component aggregate as in both cases BPA interacts with carboxylic acids to form supramolecular ladder-type assembies. Molecular recognition in co-crystals 3–5 results in the formation of extended infinite tapes and differ further as a consequence of the soft C–H⋯O bonds and stacking interactions. Structure 3 shows the formation of zig-zag tapes while 4 and 5 form linear infinite tapes. Structure 4 shows isostructural behaviour with an analogous structure previously reported (Bowes et al. (2003) ).The isostructurality is because of the structural resemblance between both the entities in the co-crystals – fumaric acid/succinic acid and 1,2-bis(4-pyridyl)ethane/1,2-bis(4-pyridyl)ethene. Compound 5 shows good degree of resemblance with another reported analogous structure-1,2-bis(4-pyridyl)ethene adipic acid. (Zhang et al. (2003) ). Structure 5 and the reported structure form similar supramolecular sheets through intertape interactions differing from each other only in the alignment of neighboring tapes. The linear tapes in both the cases are linked laterally through different C–H⋯O interactions and ventrally through different stacking interactions. This work illustrates the construction of different supramolecular architectures and the role of weak C–H⋯O hydrogen bonds and stacking interactions in the higher level of supramolecular organization. [Copyright &y& Elsevier]

Abstract: Interesting hydrogen-bonded supramolecular patterns have been achieved by hexafluorosilicate anion in the crystal structures of bis(thiabendazole) hexafluorosilicate dihydrate 1 and bis(pyrimethamine) hexafluorosilicate 2. In compound 1, the nitrogen atom of the benzimidazole ring rather than that of the thiazole ring is protonated. Water molecule is hydrogen-bonded with SiF6 2− anion through O–H⋯F hydrogen bonds to form a twelve membered cyclic hydrogen-bonded cluster. This cluster is self-organized to form a supramolecular chain. In the crystal structure of compound 2, the asymmetric unit contains two crystallographically independent protonated pyrimethamine (PMN) cations and a hexafluorosilicate SiF6 2− anion. The combination N–H⋯F and N–H⋯N hydrogen bonds results in the formation of complementary DADA (D and A represent donor and acceptor, respectively) array motif. It confirms that DADA array motif is a robust synthon in the crystal structures of diaminopyrimidine salts. [Copyright &y& Elsevier]