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1. Enantioselective Direct Functionalization of Indolesby Pd/Sulfoxide-Phosphine-Catalyzed N-AllylicAlkylation.

Author

Li-Yan Chen, Xiao-Ye Yu, Jia-Rong Chen, Bin Feng, Hong Zhang, Ying-Hua Qi, and Wen-Jing Xiao

Subjects
*ENANTIOSELECTIVE catalysis, *INDOLE compounds, *SULFOXIDES, *PHOSPHINE, *CATALYSTS, *ALLYLIC alkylation, *CATALYTIC activity
Abstract

A generaland efficient Pd/sulfoxide-phosphine complex-catalyzeddirect asymmetric N-allylic alkylation of indoleshas been developed to allow for the preparation of various N-allylated indoles in generally good yields with excellentenantioselectivities. This catalytic system could also be extendedto other N-containing heterocycles with good results. [ABSTRACT FROM AUTHOR]

Published
2015
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