1. Pyrite FeS2 as an in-situ oxygen remover for rechargeable batteries with layered cathode materials.
- Author
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Zhang, Sheng S. and Tran, Dat T.
- Subjects
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STORAGE batteries , *ELECTROLYTES , *ELECTRICAL conductors , *REACTIVE oxygen species , *PHASE transitions , *OXIDATION-reduction reaction - Abstract
Abstract Volume swelling is a typical mode of battery failures, which happens not only in the operation but also during the storage of rechargeable batteries as a result of electrolyte degradation, particularly the chemical oxidation of electrolyte solvents by the active oxygen released in phase transition of the layered cathode materials. Aiming to remove the active oxygen, we herein propose Pyrite FeS 2 powder as an in-situ oxygen remover based on the fact that FeS 2 can be ultimately oxidized to Fe 2 O 3 and Li 2 SO 4 by the active oxygen, and the redox reaction depletes considerable amount of oxygen. By mixing FeS 2 powder into a conventional LiNi 0.80 Mn 0.10 Co 0.10 O 2 (NMC811) cathode, it is found that under normal cycling conditions of the Li/NMC811 cells, FeS 2 is electrochemically stable while being capable of reacting with active oxygen and hence stabilizing the cell's capacity retention. The concept proposed in this work provides a practically viable and cost-effective approach for preventing volume swelling of the rechargeable batteries based on the layered cathode materials. Graphical abstract Image 1 Highlights • Phase transition and oxygen release is an intrinsic nature of layered cathode materials. • Pyrite FeS 2 is proposed as an in-situ oxygen remover for rechargeable batteries. • In battery FeS 2 is electrochemically stable and capable of removing active oxygen. • FeS 2 suppresses impedance growth and the 2nd structure crack of layered cathode materials. [ABSTRACT FROM AUTHOR]
- Published
- 2018
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