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Bartlett pears harvested at commercial maturity (10.64 kg/cm2 flesh firmness and 3.15 starch iodine rating) were fumigated with 1‐methylcyclopropene (3.3%VP SmartFreshTM) in a concentration range of 100–1,000 nl/L inside airtight chambers. The fruit were stored under cold storage conditions (2 ± 1°C with 95 ± 2%) followed by ambient holdings after monthly intervals. Treated fruit had significantly (p <.05) highest flesh firmness, total soluble solid, ascorbic acid, phenols, sensory scores with lowest PLW, spoilage, calcium content, and respiration rate. Further, fruit treated with 1,000 nl/L 1‐MCP retained edible quality during the successive ambient holding period of 15, 9, 6, and 3 days after 30, 60, 90, and 120 days of cold storage. The untreated control fruit after 30 and 60 days of cold storage could be stored only up to 9 and 3 days under ambient holding conditions and lost their sensory acceptability after 90 days of cold storage. Practical Applications: Response of pear fruit to 1‐MCP treatments is highly variable based on storage atmosphere, mode of application, and concentration of the active ingredient. In our findings, we reported that fumigating freshly harvested pears with 800, 900, and 1,000 nl/L 1‐MCP for 24 hr in airtight chambers retained highest fruit quality. Further, fumigation facilities can be established near production areas and fruit can be treated with 800 nl/L 1‐MCP with a shelf life of 15, 9, 6, and 3 d after 30, 60, 90, and 120 days of cold storage. Threshold acceptability values for the most important quality parameters, namely, TSS, firmness, and PLW were standardized which can be used in the future to predict the shelf‐life period of the fruit. [ABSTRACT FROM AUTHOR]