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To develop special insulating paper is of great significance to promote the service life of transformers. Using molecular simulation to guide the development of special insulating paper can greatly reduce the trial-and-error rate and waste of resources in traditional experiments. The effect of different types of polysilsesquioxane (POSS) on cellulose insulating paper was investigated by using molecular simulation. This paper investigated the thermal stability and mechanical properties and electrical characteristics of caged POSS, semi-caged POSS, and ladder-like POSS doped cellulose insulating paper. The results show that POSS with all types can enhance the performance of cellulose insulating paper, and ladder-like POSS possess the best modification effect. The glass transition temperature was increased by 58 K, and the bulk modulus, shear modulus, and elastic modulus of cellulose insulating paper doped with ladder-like POSS can improve up to 27.07%, 45.67%, and 41.28%, respectively. Meanwhile, the dielectric properties of ladder-like POSS modified insulating paper are also significantly improved. The findings of this paper propose a method for the preparation of ladder-like POSS modified insulating paper, which provides theoretical guidance for the experimental preparation of special insulating paper. [ABSTRACT FROM AUTHOR]

This work describes a novel technique for the measurement of inorganic arsenic in water by generating arsine gas and detecting the conductivity of moving protons, H+ (aqueous or aq), produced by the reaction: Ag+ (aq) + AsH3 (gas, g) → AgAsH2 (solid, s) + H+ (aq). The detection is based on an electrochemical gradient of protons in a confined porous substrate (filter paper) and measures the change in the conductance due to the higher mobility of H+ compared to other ions. The conductance was measured with a pair of silver electrodes attached to opposite sides of the substrate with a bipolar pulse conductance technique. The method is established in theory and in practice. The theoretical equation for conductance change shows that a constant increase in conductance is directly proportional to the As(total) concentration. The method is validated with a standard reference material and applied to the measurement of the groundwater sample. [ABSTRACT FROM AUTHOR]

The cellulose fibers that form washi are longer than those of regular paper made from wood pulp. Hence, the mechanical properties of washi can be higher than those of conventional paper. This study evaluated the magnetic, magnetostrictive, and tensile properties of negative magnetostrictive cobalt ferrite (CoFe2O4) particle dispersed handmade washi (washi−CoFe2O4). The CoFe2O4 additives magnetized the washi, which displayed negative magnetostriction with the fiber direction perpendicular to the magnetic field and in the parallel fiber direction. Concerning the mechanical properties, the washi−CoFe2O4 displayed an elongation of up to 77% after yielding. [ABSTRACT FROM AUTHOR]

The diffusion of moisture in the meta-aramid fiber (PMIA) oil-paper insulation system and the thermal decomposition of PMIA insulation paper in different moisture contents were studied via molecular dynamics simulations. The results showed that the PMIA insulation paper had a stronger ability to absorb water molecules than the insulating oil; therefore, water molecules in the insulating oil diffuse to the insulation paper, which further affects the thermal decomposition of the PMIA insulation paper. The activation energy of the water-bearing composite model was 129.96 kJ/mol, which was 5.5% lower than that of the pure PMIA (137.61 kJ/mol). It indicated that moisture could promote PMIA decomposition. The micromechanism of the enhanced thermal decomposition of PMIA with moisture contents could be described as follows: The O–H bond of the water can easily break to generate H atoms and hydroxyl radicals (•OH). The strong activity of H atoms allows it to easily combine with the ammonia base at the end of PMIA to generate NH3. Additionally, the free •OH radical can easily combine with the amido and carbonyl bonds at two ends of PMIA, undergo an oxidation reaction, and generate an oxhydryl. Therefore, it can reduce the chemical stability of the PMIA chain and further drive thermal decomposition. Statistical data on fragments generated by the thermal decomposition of the water-bearing PMIA composite system show that the main products include H2, C/H/O-containing molecules, hydrocarbon molecules, N-bearing molecules, and free radicals. [ABSTRACT FROM AUTHOR]

In this work, in-plane thermal conductivity measurement was carried out on graphene-based papers. Graphene-based papers were fabricated using various processing techniques such as chemical vapor deposition (CVD), hot pressing of graphene slurry, and evaporation induced self-assembly. The prepared materials were characterized using scanning electron microscopy, Raman spectroscopy, and X-ray diffraction. In-plane thermal conductivity measurement was performed via a steady state thin film thermal conductivity apparatus. The in-plane thermal conductivity measurements show that the CVD based sample has the highest thermal conductivity. COMSOL Multiphysics was used to simulate the in-plane thermal conductivity of graphene-based papers. [ABSTRACT FROM AUTHOR]

Holes and defects can greatly reduce the mechanical properties of multilayer graphene sheets under different loading conditions due to the stress concentration near the hole edge in each in-plane sheet and the lack of interlayer carbon–carbon bonds between the layers. Here, we report a novel design of multilayer open-hole graphene papers (MLGPs) formed through interlayer covalent bonding at the hole edges of multilayer open-hole graphene sheets (MLGSs) under high temperature using molecular dynamics (MD) simulations. Our MD results show that the hybrid sp2–sp3 interlayer bonds of MLGPs can significantly improve their both tensile strength and interlayer shear strength. The tensile strength and interlayer shear strength of MLGPs increase by around 20% and 3 times by comparison with those of MLGSs with the same number of layers, respectively, which mainly depends on the uniformity of their interlayer bond distribution. This study can provide an effective way to improve the mechanical performances of multilayer graphene sheets with flaws and also offer corresponding guidance for the design of MLGS-based nanocomposites. [ABSTRACT FROM AUTHOR]

This paper presents the design of a single-phase solid phononic crystal (PnC) structure featuring a regular hexagonal perforation pattern. The structure manifests three negative refraction bands, encompassing one for transverse waves and two for longitudinal waves, thereby enabling simultaneous control of shear and longitudinal waves. Due to the high symmetry of the triangular lattice, the equal frequency curves corresponding to the negative refraction band approach circular shapes, suggesting a nearly isotropic negative refraction effect. This negative refraction effect is achieved through specific mass resonance modes closely related to the porous structure designed in this paper. Initially, we analyze the band structure of the PnC, followed by designing the PnC plate structure to achieve negative refraction control for transverse waves at a frequency of 32.4 kHz, with a negative refraction index of −1. Additionally, negative refraction control for longitudinal waves is attained at frequencies of 44 and 64.54 kHz. Subsequently, we scrutinize the influence of various conditions on negative refraction, including different structural parameters, incident angles, and operating frequencies, while verifying the robustness of the designed phonon crystal structure. Leveraging the negative refraction characteristics of the structure, we construct an elastic wave lens to achieve perfect imaging of shear and longitudinal waves. Finally, employing finite element simulation and analyzing focusing imaging characteristics with different source positions, we validate that the results closely align with theoretical expectations. The solid PnC structure designed in this study holds significant potential for applications in the fields of elastic wave imaging. [ABSTRACT FROM AUTHOR]

The time-modulated active medium with linear independent frequency conversion method has been demonstrated to enable wave orientation and reconstruction. However, due to the symmetric scattering field, this technique requires intricate microcircuit designs. To overcome this limitation, this paper proposes a tunable piezoelectric metasurface based on acoustic black holes (ABHs) to redirect flexural wave reflections. The system can convert an incident flexural wave into a reflected wave of any direction and frequency. This is accomplished through the linear time modulation of the sensing signal, which breaks the constraints of Snell's law inherent in traditional designs and is insensitive to the incident amplitude. The coupling of the ABH damping system with a linear independent frequency conversion mechanism allows for the conversion of an incident flexural wave into a reflected wave in any direction and frequency while also eliminating the influence of second harmonic reflection on the wave field and simplifying the time modulation circuit. In addition, this paper demonstrates arbitrary angle reflection, focusing, beam splitting, and frequency conversion of the incident wave. By improving the flexibility of elastic wave manipulation, this paper introduces a new approach for active control of elastic waves and provides a design method that can be employed in a variety of applications ranging from vibration protection of engineering structures to vibration sensing and evaluation. [ABSTRACT FROM AUTHOR]

In this paper, a high precision detection method of copper ion (C u 2 + ) concentration based on weak measurement is proposed. The ternary complex formed by C u 2 + with L-tryptophan and phenanthroline reagents has circular dichroism (CD) signal at 605 nm in visible light. The CD signal can be obtained using the intensity contrast as a pointer in the imaginary weak-value amplification scheme. The measured sensitivity and resolution are 0.3417 mrad l/mg and 0.058 mg/l, respectively, which is improved by an order of magnitude compared to the traditional CD measurement method. It is also more accurate and less costly than commonly used C u 2 + detection methods. The C u 2 + concentration detection based on the weak measurement of CD signal detection proposed in this paper not only brings technological breakthroughs in the field of heavy metal ion detection, but also is of great significance in promoting the cross-development of chemistry, biomedicine, and life sciences. [ABSTRACT FROM AUTHOR]

Metasurfaces, due to their outstanding ability to control electromagnetic waves, have great application prospects in the field of wireless communication. This paper provides a comprehensive review of research work based on metasurface in three aspects: wireless power transfer, wireless information transmission, and novel wireless transceiver architectures. In the domain of wireless power transfer, several focusing metasurfaces and systems with unique performance are presented along with a new formula for calculating wireless power transfer. Concerning wireless information transmission section, the direct digital information transmission based on metasurface and the information transmission based on space-time-coding digital metasurface are introduced. Lastly, a simplified wireless transceiver with metasurfaces was introduced. The paper concludes with a discussion on the future directions of metasurfaces in the wireless communication domain. [ABSTRACT FROM AUTHOR]

In this work, we describe the synthesis of novel electrically and magnetically dual-driven Janus particles for a handwriting-enabled twisting ball display via the microfluidic technique. One hemisphere of the Janus particles contains a charge control agent, which allows the display color to be controlled by applying a voltage and superparamagnetic nanoparticles, allows handwriting by applying a magnetic field to the display. We fabricated a twisting ball display utilizing these Janus particles and tested the electric color control and handwriting using a magnet. As a result, the display was capable of permitting handwriting with a small magnet in addition to conventional color control using an applied voltage (80 V). Handwriting performance was improved by increasing the concentration of superparamagnetic nanoparticles and was determined to be possible even when 80V was applied across the electrodes for 4 wt.% superparamagnetic nanoparticles in one hemisphere. This improvement was impossible when the concentration was reduced to 2 wt.% superparamagnetic nanoparticles. The technology presented in our work can be applied to low-cost, lightweight, highly visible, and energy-saving electronic message boards and large whiteboards because the large-size display can be fabricated easily due to its simple structure. [ABSTRACT FROM AUTHOR]

Alternating current (ac) losses in conductor-on-rounded-core (CORC) cables of YBCO high-temperature superconducting (HTS) tapes are a significant challenge in HTS power applications. This study employs two finite element analysis (FEA) models to investigate the contributions from different ac loss components and provide approaches for reducing ac losses in cables. An FEA model based on the T-A formulation treats the cross section of thin superconducting layers as 1D lines and, therefore, only can predict the ac loss generated by the perpendicular magnetic field. In contrast, the model based on H-formulation can be performed on the actual 2D rectangular cross section HTS tapes to provide the total ac losses generated by magnetic fluxes penetrating from both the edges and surfaces of HTS tapes, although this model requires more computing time and memory. The 1D and 2D simulation models were validated by cross comparing the results from both models and by comparing sub-section and full cross section models. Subsequently, two models relate cable design and operational parameters to the surface and edge losses of a two-layer CORC cable by considering the (1) relative contributions of edge and surface losses to the overall ac losses; (2) effect of the current distribution between inner and outer HTS layers on ac losses; (3) impact of the tape alignment on ac losses in each HTS layer; (4) influence of the thickness of HTS layers on ac losses; (5) effect of size and number of inter-tape gaps on ac losses; and (6) contribution frequency on the ac losses. The research results given in this paper are therefore not only valuable to suggest strategies for reducing ac loss in multi-layer cables but also for developing more accurate and effective methods to calculate ac loss in CORC HTS cables. [ABSTRACT FROM AUTHOR]

Multi-scale predictive models for the shock sensitivity of energetic materials connect energy localization ("hotspots") in the microstructure to macro-scale detonation phenomena. Calculations of hotspot ignition and growth rely on models for chemical reaction rates expressed in Arrhenius forms; these chemical kinetic models, therefore, are foundational to the construction of physics-based, simulation-derived meso-informed closure (reactive burn) models. However, even for commonly used energetic materials (e.g., HMX in this paper) there are a wide variety of reaction rate models available. These available reaction rate models produce reaction time scales that vary by several orders of magnitude. From a multi-scale modeling standpoint, it is important to determine which model best represents the reactive response of the material. In this paper, we examine three global Arrhenius-form rate models that span the range of reaction time scales, namely, the Tarver 3-equation, the Henson 1-equation, and the Menikoff 1-equation models. They are employed in a meso-informed ignition and growth model which allows for connecting meso-scale hotspot dynamics to macro-scale shock-to-detonation transition. The ability of the three reaction models to reproduce experimentally observed sensitivity is assessed by comparing the predicted criticality envelope (Walker–Wasley curve) with experimental data for pressed HMX Class V microstructures. The results provide a guideline for model developers on the plausible range of time-to-ignition that are produced by physically correct Arrhenius rate models for HMX. [ABSTRACT FROM AUTHOR]

Geomagnetic navigation has become a hot spot in current research because of its characteristics of passiveness and good concealment. However, the magnetic interference from various ferromagnetic substances, electronic equipment, etc., of the carrier will be superimposed on the geomagnetic field, causing magnetometer measurement errors, thus affecting navigation accuracy. In practice, due to the limited maneuverability of the carrier, sufficient geomagnetic observation data cannot be obtained, resulting in the observation equation used for carrier magnetic interference compensation to be seriously pathological. To achieve the compensation of carrier magnetic interference, this paper proposes the total least squares method based on the ridge regression using the L curve to solve ridge parameters. This method can effectively suppress the measurement noise that exists on both sides of the observation equation, and is suitable for alleviating the pathological effects of carrier magnetic interference compensation. Experimental results show that the compensated magnetometer measurement error is reduced to 3% of the carrier magnetic interference by using the method proposed in this paper, which obtains more stable and accurate parameter estimates. [ABSTRACT FROM AUTHOR]

This paper proposes a piezoelectric energy harvester that concentrates force on the piezoelectric element by parallel springs. When vibrating, the force exerted by the mass is released at three equal points on the surface of the brass substrate through three parallel springs. This concentrated release of energy through the spring amplification effect facilitates large deformation of the piezoelectric ceramic sheet, resulting in a higher charge output. The results show that under the combined action of a 14 g annular hollow mass and a 0.3 mm wire diameter stainless steel spring, the energy harvester based on the lead zirconate titanate ceramic exhibited an outstanding output power of 1.0–32.1 mW at a low resonance frequency with acceleration amplitudes of 0.5–3 g (1 g = 9.8 m/s2). More importantly, to match the vibration frequency of the actual environment, this paper optimized the structure of the harvester and proposed that the harvester can be designed by selecting the weight of the mass block, the parameters and number of springs, and the shape of the brass substrate. The energy harvester designed in this study is expected to capture energy from low-frequency natural environments and exhibit outstanding output performance, which can provide guidelines for future efforts in this direction. [ABSTRACT FROM AUTHOR]

This paper describes the design and optimization of a 10 ml cartridge for patient sample processing using a 3.5 GHz (empty resonant frequency) TM010 cylindrical microwave cavity. The cartridge has been designed to augment a novel approach for the rapid diagnosis of M. tuberculosis (the causative agent of Ttuberculosis), which uses the direct application of microwaves to a bacteria-containing sample to release pathogen-specific DNA. The target bacterial DNA is then captured and recovered using magnetic nanoparticles coated with pathogen-specific DNA probes. Excitation parameters were optimized using three surrogates for M. tuberculosis, namely, M. smegmatis, M. abscessus, and M. bovis suspended in water and simulated sputum. The paper also explores the mechanism of microwave-mediated DNA release from bacteria using scanning electron microscopy. Examination of bacteria exposed to microwaves at power levels known to mediate the release of DNA reveals no obvious signs of permanent cell disruption, suggesting that a more subtle interaction is taking place. Finally, the presence of microwave-liberated M. bovis DNA was able to be detected at a level of sensitivity comparable to that achieved using microscopy. [ABSTRACT FROM AUTHOR]

As one of the promising room temperature nuclear radiation detection materials, the all-inorganic perovskite CsPbBr3 single crystal has been receiving much attention in recent years. Even though the performance of the CsPbBr3 detector is improving continuously, the disadvantages of detection instability have not been solved fundamentally, and this instability is mainly caused by ionic migration in the CsPbBr3 single crystal itself. In this paper, a reasonable ionic migration model is proposed based on an in-depth study of the current hysteresis phenomenon and ionic migration mechanism in the Ti/CsPbBr3/Ti detector. The model shows that the ions migrate to the anode or cathode under an external electric field, and the accumulated ions subsequently form an inverted internal electric field inside the crystal and carrier transport barriers at the metal–semiconductor interface simultaneously. The photoelectric characteristic and ionic migration activation energy (E a i o n) fitting results also prove the rationality of the ionic migration model. Furthermore, the ionic migration model can also be used to explain the left-shift of the energy response peak and the decrease in the normalized charge collection efficiency in the Ti/CsPbBr3/Ti detector. This paper systematically investigates the intrinsic origin of migrated ions and the influence of ionic migration on detection stability, which will provide a potential solution to improve detection stability by suppressing ionic migration in the near future. [ABSTRACT FROM AUTHOR]

In this paper, the super-cavitating phenomenon under the effect of two vehicles' encounter motion processes is numerically studied. Particular attention is given to the influence of the vertical gaps between the vehicle, the cavitation number, and the slenderness ratio on the cavity profile and radial force of the object. Several numerical models are built to study the cavity evolution process and the force acting on the vehicle to explore the influence mechanism of two vehicles' encounter motion on supercavitating flow. The study shows that the cavity around the vehicle is primarily affected by the vertical gaps and cavitation number, but is relatively weakly affected by the slenderness ratio. Several impact laws are acquired in the paper. The relationship between cavity fracture time and vertical gaps is approximately a power function and obeys the law of t = 5.433h0.3688. The concept of the time of the maximum radial force occurrence and the cavitation number follows the formula of t = 4.86e0.3688σ. The relationship between the maximum radial force occurrence position and the cavitation number is a function of Ln and consistent with the law n = −0.799ln(σ) + 8.427. [ABSTRACT FROM AUTHOR]

Dynamic shockless compression experiments provide the ability to explore material behavior at extreme pressures but relatively low temperatures. Typically, the data from these types of experiments are interpreted through an analytic method called Lagrangian analysis. In this work, alternative analysis methods are explored using modern statistical methods. Specifically, Bayesian model calibration is applied to a new set of platinum data shocklessly compressed to 570 GPa. Several platinum equation-of-state models are evaluated, including traditional parametric forms as well as a novel non-parametric model concept. The results are compared to those in Paper I obtained by inverse Lagrangian analysis. The comparisons suggest that Bayesian calibration is not only a viable framework for precise quantification of the compression path, but also reveals insights pertaining to trade-offs surrounding model form selection, sensitivities of the relevant experimental uncertainties, and assumptions and limitations within Lagrangian analysis. The non-parametric model method, in particular, is found to give precise unbiased results and is expected to be useful over a wide range of applications. The calibration results in estimates of the platinum principal isentrope over the full range of experimental pressures to a standard error of 1.6%, which extends the results from Paper I while maintaining the high precision required for the platinum pressure standard. [ABSTRACT FROM AUTHOR]

This paper presents a self-consistent multi-dimensional mathematical model and a numerical approach for simulating the low-temperature plasma induced by the femtosecond laser filament. Addressing limitations in current models, we analyze key aspects of the laser plasma behavior, including plasma generation, detailed chemical kinetics, energy exchange channels, total energy balance, and hydrodynamics. The developed model and LOTASFOAM code are applied to study the temporal and spatial decay of the plasma produced by a femtosecond laser pulse in pure nitrogen at atmospheric pressure. The paper also includes a discussion on the spatial and temporal dynamics of electronically excited states of nitrogen in the decaying laser plasma. [ABSTRACT FROM AUTHOR]