Search

The Marano-Grado Lagoon (MGL) is extensively contaminated by mercury (Hg) from local sources and long-term (500 years) tidally delivered inputs from the Idrija Hg mine (Slovenia) through Isonzo River suspended loads. A multibox WASP-7 (Water Analysis Simulation Program) model was used to simulate the long-term dynamics of the mercury cycle in the MGL. Scenario simulations were used to compute changes in the system over 100 years. Present and future Hg concentrations in water, sediment, and Hg budgets were compared, including evasion and MeHg inputs to the Mediterranean Sea, based on climate changes and mercury capping in tributary rivers. Using the Ref baseline scenario, the model computes a general decrease in Hg T of 13% in the water column and of 80% in sediment and a strong MeHg increase in sediment (+73%). The net sea export of Hg T decreases by 57% to up to 48 kg/y while MeHg increases by 10% to up to 0.63 kg/y. The lagoon sediment recovery time of Hg T up to a target level of 0.3 mg/kg is computed over 570 years for surface sediments (1750 for subsurface sediments). When removing Hg from boundaries, the same target value for surface sediments is reached within 110 years. [ABSTRACT FROM AUTHOR]