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A cost-effective cement composite material has been developed for grounding systems, utilizing carbon black, carbon nanotubes, and steel fibers as conductive dopants. The electrical conductivity, mechanical properties, and fluidity of cement composites are investigated, and the synergetic mechanism of multiple conductive dopants in cement composites is revealed based on microscopic means. The results show that the combination of carbon black, carbon nanotubes, and steel fibers facilitates the establishment of efficient conductive networks in cement composites. The addition of 5 % carbon black, 0.3 % carbon nanotubes (by weight of cement), and 0.6 % steel fibers (by volume of composite) reduced the resistivity of the cement composite from 5568 Ω·cm to 310 Ω·cm after 28 days of curing. Then, it decreased to 267 Ω·cm after natural drying in laboratory environment until the 90th day. In addition, the resistivity of cement composites varies less than 5 % in environments ranging from −20°C to 50°C. Furthermore, the compressive and flexural strengths were 30.06 MPa and 6.17 MPa, and the flow diameter was 167 mm, which provided good mechanical strength and workability for conventional engineering applications. This paves an effective way for the further application of cement composites in grounding systems. • Electrically conductive cement composite was developed using carbon black, carbon nanotubes, and steel fibers. • Carbon black, carbon nanotubes, and steel fibers has synergistic combination effect to composite. • The distribution of carbon black, carbon nanotubes, and steel fibers within the cement composites is closely observed. • This combination of conductive dopants facilitates large-scale production of electrically conductive cement composites. [ABSTRACT FROM AUTHOR]

• Post-fire curing of cement composites was notably modified by carbon nanomaterials. • CBN and MWCNT improved rehydration and strength recovery of mortars exposed to 200–400 °C. • Recured nanomodified mortars exposed to 200–400 °C and 600 °C had relative residual factors higher than 85% and 40%, respectively. • Decomposition of CBN and MWCNT after 500 °C decreased strength recovery of rehydrated mortars. Concrete elements exposed to fire can partially recover strength and stiffness if recured in water or in a moist environment. This paper reports a pioneering investigation of the influence of post-fire curing on residual mechanical properties and microstructure of cement mortars containing different concentrations of carbon-black nanoparticles (CBN) or multi-walled carbon nanotubes (MWCNT). A total of 84 specimens were subjected to various maximum exposure temperatures (200, 400, or 600 °C) and post-fire curing (water-recuring for 1 day followed by air-recuring for 27 days). X-ray diffraction (XRD), scanning electron microscopy (SEM), and energy-dispersive spectrometry (EDS) were used to investigate the microstructure of different types of specimens. Experimental tests were carried out to determine the compressive strength, static modulus of elasticity, and dynamic modulus of elasticity of rehydrated specimens. Nanofillers enhanced the strength recovery of composites exposed to temperatures up to 400 °C, since they improved rehydration reactions. In this case, the rehydration process provided values of relative residual strength and elastic modulus factors higher than 85%. Composites containing 0.4% MWCNT and 3% CBN presented the best strength and stiffness recovery. Therefore, small contents of carbon nanomaterials provided additional nucleation sites for dehydration products to sediment and being rehydrated. Moreover, water adsorbed by the nanomaterials during the water-recuring process was used later to provide greater rehydration. Composites containing 1.2% MWCNT and 9% CBN presented lower mechanical properties recovery, as high contents of nanomaterials made it harder for water to reach decomposed C-S-H gel, hindering the development of rehydration reactions. After 600 °C, lower relative residual factors were obtained, but always higher than 40%. It happened because nanofillers were not able to provide those rehydration improvements, since their thermal decomposition started at about 500 °C. [ABSTRACT FROM AUTHOR]