1. Viscoelastic properties of copolycarbonates comprising isosorbide and 1,4-cyclohexanedimethanol.
- Author
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Han, Ruiqi, Kida, Takumitsu, and Yamaguchi, Masayuki
- Subjects
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GLASS transition temperature , *MODULUS of rigidity , *SHEARING force , *MOLECULAR weights , *POLYCARBONATES - Abstract
Viscoelastic properties of copolycarbonate materials comprising isosorbide (ISB) and cyclohexanedimethanol (CHDM) were studied as a function of the ISB content. In the glassy state, β dispersion was clearly detected in the dynamic mechanical spectra. The tensile storage modulus E′ at room temperature increased with the ISB content, and the glass transition temperature Tg, i.e., peak temperature of α dispersion, increased with the ISB content. It was found from oscillatory shear modulus that the rubbery plateau modulus GN0 decreased with the ISB content. The entanglement molecular weights Me were found to be 2330–3640, which were slightly higher than that of bisphenol-A polycarbonate and much lower than those of poly(methyl methacrylate) and polystyrene. The onset shear stress of shark-skin failure at capillary extrusion was evaluated and found to increase with the ISB content. [ABSTRACT FROM AUTHOR]
- Published
- 2023
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