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Silicon oxycarbide (SiOC) ceramics have been used to fabricate microwave-absorbing metastructures, demonstrating impressive absorption capabilities. However, SiOC ceramic metastructures with excellent performance require simple fabrication processes and appropriate mechanical and electromagnetic properties. In this study, a solvent-free photosensitive polysiloxane preceramic was developed by blending methoxy/hydroxy polysiloxanes with acrylates, with a ceramic yield of over 60% after curing using a novel two-step ultraviolet (UV)/thermal method. The composition and microstructure of SiOC ceramics can be designed by controlling the preceramic composition. Dense, crack-free gyroid-shellular shaped triple periodic minimal surface (GS-TPMS) electromagnetic metastructures were fabricated using digital light processing (DLP) 3D printing technology. By designing the porosity of the GS-TPMS structure to 51%, an effective absorption bandwidth that covers the X-band can be achieved at a thickness of 3.1 mm. The honeycomb structure, with a geometric density of 0.69 g/cm3, exhibited a high compressive strength of 107.05 MPa. This paper presents an efficient approach for the prompt and customized fabrication of lightweight ceramic metastructures with outstanding microwave absorption properties. • A solvent-free polysiloxane/acrylate hybrid preceramics is developed for 3D printing. • The UV/thermal two-stage treatment achieved cross-linking curing of the preceramics. • Multiscale design of SiOC ceramics for enhanced microwave absorption properties. • SiOC ceramic metastructures with effective absorption in the X-band are prepared. [ABSTRACT FROM AUTHOR]

Due to the limitations of the Kramers-Kronig relationship, how to achieve ultra-wide effective absorption bandwidth remains a challenge for typical magnetic-dielectric absorbers. In the present work, we have explored the possibility of obtaining ultra-wide absorption bandwidth in FeSiAl composites with help of efficient electromagnetic (EM) simulation software-Computer Simulation Technology (CST). Flaky FeSiAl powders covered by CeO 2 have been prepared, in which EM parameters can be tuned by filling ratio of FeSiAl/CeO 2 in FeSiAl/CeO 2 -paraffin composites. The filling ratio has an effect on impedance matching and EM parameters by the arrangement of particles in the paraffin. The composite with 30 wt% flaky FeSiAl/CeO 2 achieves an effective absorption bandwidth (EAB) of 6.48 GHz and the optimal microwave absorption efficiency of 1499.3 dB GHz/(wt%⋅m) at 1.9 mm. Integrated with a macroscale honeycomb structural design, the FeSiAl/CeO 2 composites based metastructure exhibits broadband microwave absorption with an EAB of 14.224 GHz covering from 3.776 GHz to 18 GHz and reflection loss of-65.61 dB at 8.5 GHz. The excellent performances of the designed absorber are ascribed to multiple loss by integrating EM parameters of flaky FeSiAl/CeO 2 and the geometry parameters of honeycomb metasrtucture. The present work makes flaky FeSiAl/CeO 2 composites possible to achieve broadband microwave absorption. [ABSTRACT FROM AUTHOR]