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This paper uses data from the 1995 and 2000 World Values Survey to examine and compare the relationship between social capital, education and political participation in Western and Eastern Europe. The concept of social capital is measured using indicators of trust and membership in voluntary organizations, while the concept of political participation is put into operation through indicators of political action. The research uncovers clear indicators showing that social capital is a factor in political participation in Eastern Europe and that the existence of general social trust is a characteristic of the most successful transitions. The paper finds evidence to support the theory that a trust-building mechanism based on reciprocity and a "critical mass" is indeed at work in the democratization process and that social capital is an integral part of transition for the Eastern European states. [ABSTRACT FROM AUTHOR]