1. Sorption of Radiocaesium onto Powdered and Compacted Rectorite Studied by Batch and Capillary Methods.
- Author
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Lei Chen and Xianjin Yu
- Subjects
- *
ABSORPTION , *PHYSICAL & theoretical chemistry , *HYDROGEN-ion concentration , *SEPARATION (Technology) , *ANALYTICAL chemistry , *PROPERTIES of matter - Abstract
The sorption of radiocaesium onto Na-rectorite as a function of pH value under ambient conditions was studied by batch and capillary methods. The results indicated that the sorption of Cs+ ions was dependent on the ionic strength and, to a lesser extent, on the pH value. The distribution coefficients for Cs+ ion sorption onto powdered rectorite (as determined via the batch technique) were much higher than those of Cs+ ions onto compacted rectorite (as determined by capillary test), thereby suggesting that the sorption of Cs+ ions onto rectorite was strongly dependent on the density of rectorite, i.e. the interlaminary space of the compacted rectorite contributes significantly on Cs+ ion sorption. The distribution coefficients calculated from theoretical calculations, experimental measurements and the diffusion coefficients of Cs+ ions were compared and discussed in detail. The sorption and diffusion mechanisms in compacted rectorite were also discussed. [ABSTRACT FROM AUTHOR]
- Published
- 2007
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