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This article presents the information on the valorization of waste generated during the production of tissue paper. The possibility of bioconversion of the polysaccharide part of paper sludge into simple sugars has been evaluated. The options for processing the paper sludge before enzymic hydrolysis to achieve the maximum yield of monosaccharides have been considered. Pretreatment with acids has been found to be a key step before the biocatalytic cleavage of waste polysaccharides. An additional yield of enzymic hydrolysis products after pretreatment with acids has been obtained by pre-extraction of the paper sludge with spirit or acetone. It has been established that the most intense enzymic hydrolysis of readily available fractions of the paper sludge takes place in the first 10–12 hours. Further, the process slows down, probably due to the action of the remaining components of the fillers, as well as an increase in the proportion of the difficult-to-hydrolyze polysaccharide part. In all cases, the proportion of absolutely dry non-hydrolyzed residue has been about 43±2 % of the dry matter of the paper sludge. The main products of enzymic hydrolysis have been glucose and xylose. The resulting sugars have been used for mixotrophic cultivation of the Tetradesmus obliquus and Chlorella vulgaris algae. Yeast strains have been selected for the conversion of monosaccharides from the paper sludge. In a series of experiments on non-sterile yeast cultivation, the Candida utilis PAL D and Debaryomyces hansenii SWING R cultures have turned out to be the most productive (within 2.10±0.14 g of air-dry yeast weight/dm3 per 24 hours). The degree of conversion of hydrolysate sugars has been 70±2 %. Most of the remaining sugars (about 80 %) have been represented by xylose. Complete utilization of the sugars has taken place on the 2nd day when having added an extra nitrogen source to the medium. On the other hand, the spent nutrient medium after yeast separation has been suitable for mixotrophic cultivation of microalgae. It has been revealed that the economic costs of pre-treatment of the paper sludge with nitric acid can be leveled by using the resulting salts as a nitrogen source for cultivating yeast. In doing so, the yield of yeast biomass increases by almost 2 times.

Abstract To compare the urine Congo‐red dot paper test (CRD) with dipstick urinalysis to screen preeclampsia (PE). A total of 409 paired spot urine samples were obtained prospectively from women with suspected pre‐eclampsia attending for routine hospital visits. Congo‐red dot paper test and dipstick urinalysis were examined and compared to screen pre‐eclampsia. The agreement between the two urinary test is modest (kappa coefficient = 0.28, 95% CI 0.14–0.42). The specificity of CRD was higher than urinalysis (97.4% vs. 90.4%, p

Contemporary ESL education focuses on screen-based reading, specifically in the context of university level learners. Also, a sudden shift from paper bound reading activities to screen-based tasks was inevitable in response to COVID-19 outbreak. In this regard, the case of inferential and advanced level reading among the young ESL learners of developing countries appears researchable because of the general low digital literacy of these learners. This study, therefore, aimed to investigate the effect of reading mode shift from paper to screen on the inferential comprehension performance among Pakistani ESL learners at university level. A total of 426 undergraduate learners were sampled from Bachelor of Science program in a well-known university in the city of Lahore, Pakistan. Inferential reading was conceptualized through Bloom’s higher order thinking skills, that is, Analyzing, Evaluating and Creating skills therefore the reading comprehension test was based on these skills. Adopting sequential test administration, first the paper-based reading test, and later the screen-based reading was given. The obtained data were analyzed using Rendell’s XCALIBRE and SPSS V. 26.0. The logit scale descriptives, learner ability (θ), and mean scores demonstrated that the learners performed significantly higher in the paper test as compared to screen test. Moreover, it was found that the effect of reading mode shift was larger in Creating skill. The findings may have significant implications for reading mode selection, enhancement of digital competence and effect of reading mode shift in developing countries with inadequate IT facilitation and digital literacy among ESL learners.

The present study was conducted to draw the co-authorship network of hot papers of science citation index in the Web of Science (WOS) database from 2020 to 2021. This investigation is a descriptive study using a scientometrics approach. This research was conducted using social network analysis indices to visualize the co-authorship networks of hot papers in the science citation index. The structure of the co-authorship network of researchers of hot papers in the field of science consists of 47,045 authors who have contributed to the publication of 3475 hot papers from 2020 to 2021, which indicates the high co-authorship of these authors. Moreover, it was found that among the co-authorship patterns of these researchers, the most significant number of articles during the studied years was related to the five-author collaborations. Moreover, the average Collaboration Coefficient (CC) of the authors of hot papers was higher than 0.80, indicating the authors' strong tendency to produce joint articles. The high collaboration of the authors of hot papers in the science citation index can be one of the reasons for increasing the level of visibility and the potential for using them.

Reliable data on U.S. paper and cardboard waste by location and type are critical for developing waste-reduction solutions, but detailed geographic analysis is lacking in the literature. In this study, we employ statistical and geospatial methods to assess paper and cardboard waste in the United States by type at the national, state, county, and local levels. Of the estimated 110 million tons of paper and cardboard waste managed domestically in 2019, approximately 56% was landfilled, 6% was combusted, and 38% was recycled. The estimated market value of paper and cardboard lost to landfilling in 2019 was $4 billion, and the estimated losses of embodied energy and combustion energy were equivalent to 9% and 4% of U.S. primary industrial energy consumption, respectively. Associated landfilling fees amounted to almost $4 billion. This study aims to inform efforts to implement beneficial waste-management strategies by policy makers, researchers, businesses, and communities across the United States and to provide a model for similar studies in other parts of the world.

Introduction: Monitoring the atypical antipsychotic drug clozapine is crucial to ensure patient safety. This article showcases a high-throughput analytical method for measuring clozapine and its primary metabolite norclozapine (N-desmethylclozapine) in serum using paper spray mass spectrometry (PS-MS). Objectives: This study aimed to assess the viability of a PS-MS method for the rapid measurement of clozapine and norclozapine in human serum samples as an alternative to liquid chromatography mass spectrometry (LC-MS). Methods: Serum samples were processed by protein precipitation followed by deposition of the supernatant containing labelled internal standards onto paper spray substrates mounted in cartridges. Analytes were then analyzed using a triple quadrupole mass spectrometer equipped with a commercial paper spray ionization source. The results obtained from the patient samples were compared to those from a validated LC-MS assay. Results: PS-MS calibrations for clozapine and norclozapine were linear (R2 > 0.99) over five days. Between-run precision was below 8 %, and within-run precision did not exceed 10 %. When compared to a validated LC-MS method, the mean bias for 39 patient samples was −9% for clozapine and −1% for norclozapine, with no outliers. Mass spectrometry ion ratio comparisons indicated no interference for patient samples above the lower limit of quantification. There was less than 7 % change in the measured concentrations of both analytes over five days for samples dried on paper substrates. Notably, virtually no maintenance of the MS source was required during this study. Conclusion: This study illustrates the potential of PS-MS for serum drug monitoring in the clinical laboratory.

Besides scientific impact, papers can also achieve a technological impact that remains less known in the scientific community. Cited papers in the patents are considered as the index to measure the technological impact. This study aimed to analyze the technological impact of Iranian publications using co-authorship and co-word map, their evolution, the journals, and the subject areas of these publications. This applied research focuses on the quantitative study and visualization with a scientometric approach. The research population was all studies (4554 records) that were published during 2011-2020 in one of the Iranian institutions and had been cited by one of the international patents. The data collection tool was the SciVal database. CiteSpace and Excel spreadsheets were used to analyze the data. Of the 4,554 papers cited by the scholarly outputs that have been cited in patents e patents, most of them were published in collaboration with the USA (9%). Islamic Azad University and Tehran University of Medical Sciences (13% each) were the most active Iranian universities. The number of Iranian papers cited in patents had a downward trend from 686 in 2011 to 57 in 2020. RSC Advances journal was the first top journal to publish these papers. Of 27 subject areas, engineering (24.1%) was the first popular subject that patents cite in their publications. The cluster analysis of keywords identified 8 clusters, including “x-ray diffraction,” “animal,” “adult,” “escherichia coli,” “tissue engineering,” “coronavirus infection,” “neural network,” and “methane.” The technological impact of Iranian research has declined in recent years. It is suggested that research policymakers should consider scholarly outputs that have been cited in patents, which, in a way, shows the flow of knowledge to the industry and encourages researchers to produce such papers.

Abstract Soot stain from diverse sources is the most common stain that stains historical paper documents found in libraries, museums, and storage facilities. It is believed to be one of the types of deterioration that arises from the contact between stains and paper sheets. Therefore, in the present work, the effectiveness of the synthesized hybrid nanogel consisting of carbopol and nanoparticles (NPs) of ZnO, TiO2, or Fe3O4, in low and high-viscosity forms, for eliminating soot stains from historical paper manuscripts was conducted. The prepared hybrid nanogels were characterized utilizing the TEM, AFM, XRD, DLS, and Zeta Potential techniques. Following preparation, the soot-stained paper samples were heated to 105 °C for 6 days, a process known as accelerated thermal aging. Surface morphology, mechanical properties and the color change of the paper samples were investigated. The prepared hybrid nanogel had a spherical shape with well-defined edges and uniform size, with an average particle diameter ranging from 30 to 35 nm. There was no significant NPs agglomeration seen, suggesting uniform dispersion in the carbopol matrix. Additionally, the prepared gels' crystal structure and phase purity were revealed by the XRD analysis results. Paper fibers were visible in some parts of the treated sample with TiO2/carbopol hybrid nanogel at high-viscosity before aging. Cleaning soot-stained paper samples using high-viscosity Fe3O4/carbopol hybrid nanogel is more successful than using low-viscosity nanogel. the sample treated with high-viscosity ZnONPs/carbopol hybrid nanogel produced the highest total color differences (ΔE) (26.17). The paper sample treated with high-viscosity ZnO/carbopol hybrid nanogel exhibited the maximum tensile strength (61.8 N/mm2) and elongation at break (1.174%). The evaluation of the paper samples both before and after the cleaning process revealed that, the treatment with high-viscosity ZnO/carbopol hybrid nanogel gave the best results in removing soot stains from stained paper samples.

To improve the surface properties of low-density wood, poplar wood was functionalized by laminating Al2O3 impregnated paper onto poplar wood (Populus tomentosa Carr.) via unilateral surface compression. Bonding strength between Al2O3 impregnated paper and wood reached up to 3.08 MPa, meeting commercial grade I requirements for impregnated paper laminated wood flooring. A cross-linked structure between Al2O3 impregnated paper and wood was formed without visible cracks or other defects. Density of the functionalized wood surface increased remarkably and the surface hardness was significantly improved, surpassing that of hardwoods for wood flooring. The functionalized wood surface also exhibited high wear resistance, which reached to the specification for commercial grade I impregnated paper laminated wood flooring. Additionally, the water resistance of the functionalized wood surface was significantly improved through lamination with Al2O3 impregnated paper. The functionalized wood demonstrated high applicability for wood flooring.

Microbially contaminated food can cause serious health hazards and economic losses, therefore sensitive, rapid, and highly specific visual detection is called for. Traditional detection of microorganisms is complex and time-consuming, which cannot meet current testing demands. The emergence of paper-based biosensors provided an effective method for efficient and visual detection of microorganisms, due to its high speed, all-in-one device, low cost, and convenience. This review focused on 5 biomarkers, namely nucleic acids, proteins, lipopolysaccharides, metabolites, and the whole microorganism of microorganisms. Besides, the recognition methods were summed up in 5 forms, including immunological recognition, aptamer recognition, nucleic acid amplification-mediated recognition, DNAzyme recognition and clustered regularly interspaced short palindromic repeats mediated recognition. In addition, we summarized the applications of paper-based biosensors in the detection of microorganisms thoroughly. Through the exploration of different biomarkers, identification methods, and applications, we hope to provide a reference for the development of paper-based biosensors and their application in safeguarding the food chain.

Nanofibrillated cellulose (NFC) and its combined usage with cationic starch and a cationic copolymer of acrylamide were studied in relation to the properties of paper. Independent pulp treatments using additives separately included 0%, 5%, 10%, and 15% refined long fiber pulp, 3 and 6% NFC, 0.75 and 1.5% cationic starch and 0.07% and 0.15% cationic polyacrylamide and combined treatments. Handsheets were made of the above treatments, and finally their optical and microscopic properties were evaluated. Increasing the NFC content to 6% increased the brightness and yellowness of the white liner by 13% and 21%, respectively. The liner opacity was also reduced by 1%. Additionally, increasing NFC by 6% compared to imported long fibers, the brightness and yellowness of the white liner increased 5.44% and 6.3%, respectively. The liner opacity was also reduced by 1%. A 1.5% cationic starch addition to NFC increased the brightness of the white liner by 4.4%, its whiteness increased 1.5%, and its yellowness increased 2.1%. The opacity of the liner was also reduced by 7.1%. The use of NFC and cationic starch can improve the optical properties of the white liner, while imported long fibers may be problematic.

The filter paper (FP) method, a cost-effective, versatile, and convenient approach, has found extensive application in analyzing fine-grained soils, enabling the successful measurement of a broad spectrum of total and matric suctions. However, using the FP method in sand with a limited range of suction profiles has been notably underrepresented in the existing literature. Therefore, this study investigated the applicability of the contact FP method in establishing soil water retention curves (SWRCs) using five distinct FP calibration curves for 10 poorly graded sands. Among these calibration curves, the one presented by Chandler yielded the highest suction values, which were followed by those of ASTM. Furthermore, the FP results were subjected to fitting with a mathmatical model, which led to the observation that the overall trends in the obtained SWRCs displayed smooth sigmoidal shapes, resulting in a complete and coherent SWRCs. The SWRC results of five sand samples were assessed through validation against the hanging column technique (HCT) results, indicating a high degree of concordance and affirming the suitability of the FP method for sands characterized by a limited suction profile. Notably, the entire range of suction values fell within the 0.01–20 kPa range based on the calibration curves presented by Chandler and ASTM for all the examined sand samples, except sands 9 and 10. Furthermore, the suction values were unobtainable using the two aforementioned calibration curves within the ranges of 0.01–1.47 kPa and 0.01–0.172 kPa. [ABSTRACT FROM AUTHOR]

Polyethylene-, polyvinylidene chloride-, and per- and polyfluoroalkyl substance-coated paper generate microplastics or fluorochemicals in the environment. Here, we report an approach for the development of oil-resistant papers using an environmentally friendly, fluorine-free, water-dispersible poly(dimethylsiloxane) (PDMS) coating on kraft paper. Carboxylic-functionalized PDMS (PDMS-COOH) was synthesized and subsequently neutralized with ammonium bicarbonate to obtain a waterborne emulsion, which was then coated onto kraft paper. The water resistance of the coated paper was determined via Cobb60 measurements. The Cobb60 value was reduced to 2.70 ± 0.14 g/m2 as compared to 87.6 ± 5.1 g/m2 for uncoated paper, suggesting a remarkable improvement in water resistance. Similarly, oil resistance was found to be 12/12 on the kit test scale versus 0/12 for uncoated paper. In addition, the coated paper retained 70–90% of its inherent mechanical properties, and more importantly, the coated paper was recycled via pulp recovery using a standard protocol with a 91.1% yield. [ABSTRACT FROM AUTHOR]

Sensitizers are used to prepare photosensitive materials for ink-printing and thermal-recording media. Typical sensitizers contain an aromatic ring and exhibit aryl hydrocarbon receptor-mediated activity. They can accumulate in aquatic biota, leading to the disruption of ecosystems. Effluent from paper recycling plants has been identified as a source of contamination, and the presence of sensitizers in toilet paper may represent a new source of contamination in aquatic environments. To examine possible sources of contamination by sensitizers, this study investigated the levels of sensitizers in recycled toilet paper. We also studied the prevalence of sensitizers in rivers receiving effluents from sewage treatment plants in Japan, from 2020 to 2022. We detected eight sensitizers and related compounds in both toilet paper and river water samples; their total concentrations ranged from 0.78 to 34 µg/g (mean: 12 µg/g) in toilet paper and 58–1167 µg/L (median: 77 µg/L) in water. In the water samples, sensitizers were partitioned between liquid and suspended solid phases, and in suspended solids, sensitizers accounted for an average of 42% of the total. Correlation analysis showed a high correlation between sensitizer composition in the water from a river receiving sewage treatment plant effluents and toilet paper. Since these compounds were also detected in the river water analyzed in this study, toilet paper should be considered a novel source of sensitizers contamination in sewage treatment systems. [ABSTRACT FROM AUTHOR]

Abstract Gels prepared from the polysaccharide gellan are used for aqueous poulticing treatments in paper conservation when the application of water must be restricted. Optimal use of the rigid, yet shapeable gel requires direct contact with the paper surface, which carries the risk of gel residues on the treated surface. We used acid methanolysis as a destructive analytical method to detect rhamnose as a component of gellan, which was undetectable with ATR-FTIR spectroscopy. We show that there is a significant probability of leaving gellan residues on the paper. Conservators should be aware of this potential side effect when considering the use of gellan poultices in direct contact with paper objects.

• Pulp and paper mill sludge (PPMS) landfill sites have GHG assessment challenges. • GHG fluxes measured by chambers with (F +) and without (F-) a frame were compared. • Flux relationships up to 80 % were shown between F- and F + chambers (the standard) • Correction factors for F- chambers were built to estimate fluxes from F + chambers. • The approach can refine GHG inventories on PPMS landfill sites. Assessments of greenhouse gas (GHG) emissions in managed areas are facing various challenges. A non-flow-through, non-steady-state (NFT-NSS) chamber coupled to a frame permanently inserted into the landfilled substrates is a standard method for quantifying GHG emissions in managed areas, such as pulp and paper mill sludge (PPMS) landfill sites. Frequent measurements are needed to minimize uncertainties on GHG emission factors at the landfill site scale. However, maintaining a frame inserted into the substrates for a long time period is often impossible due to landfilling management operations. Therefore, GHG measurements using NFT-NSS chambers placed directly on substrates' surface could be an interesting option. Our objectives were to determine the relationships between CO 2 , CH 4 , and N 2 O fluxes measured with (F +) and without (F-) a frame inserted in the substrates' surface and to develop correction factors for fluxes measured without a frame. Measurements were made at different PPMS landfill sites in the province of Québec, Canada. Stronger GHG flux relationships were observed at the provincial (across sites) than the specific site scale: the variance in GHG fluxes from F- chambers explained up to 80 % of variance in fluxes from F + chambers. The measured CO 2 , CH 4 , and N 2 O fluxes in F- chambers were on average 53, 78, and 63 % lower, respectively, than those estimated by the models at provincial scale. The correction factors developed with this approach could greatly extend the number of sites where in situ GHG measurements can be done and would help refining GHG inventories at the provincial and national levels. [ABSTRACT FROM AUTHOR]

Size presses on paper machines are used to apply a solution of a polymer – usually starch – to the surface of the sheet and thereby to increase the stiffness, surface strength, and printing quality of the product. This article reviews publications dealing with the size press equipment, the materials, and factors affecting both the operating efficiency and attributes of the resulting paper. The emergence of film-press equipment (e.g. blade-metering size presses) in the 1980s has greatly decreased the frequency of web breaks and increased productivity. Starch technology at the size press, though relatively mature, continues to evolve. By adjustment of starch attributes, solids levels, and incorporating other additives, modern papermakers can tune size press outcomes to meet a range of paper product requirements, including strength, hydrophobicity, and the reduction of air permeability. By application of various synthetic polymers, mineral particles, and even nanocellulose in combination with starch or other base polymers, there is potential to extend the technology to meet a range of future needs for paper products.

In the field of paper conservation and archival research, identifying the raw materials of paper is important to elucidate its history and culture. As the most basic element of the raw materials for paper, fibers have not been sufficiently investigated. In this study, we propose a nondestructive method for estimating paper fibers from macro photographs ( $4000\times3000$ pixels) captured using a digital camera. The proposed method consists of background patch (500 pixels per side) detection (BPD), wherein background regions with no text are identified; patch fiber classification (PFC), wherein background patches obtained after BPD are analyzed for fiber classification; and paper fiber estimation (PFE), wherein macro images obtained after PFC are analyzed for fiber estimation. BPD and PFC are employed to perform patch-based classification on segmented macro images, which are reconstructed during PFE to obtain the final fiber estimation results. We performed experiments using 1337 macro images (64176 patches) to evaluate the fiber estimation accuracy for kozo, mitsumata, and gampi via three-fold cross-validation. The average fiber classification accuracy for patch images was observed to be 79.1%; accordingly, the average fiber estimation accuracy for macro images was 85.8%. Experimental results indicated that PFE can be realized in a nondestructive manner on macro images of paper captured using a digital camera.

Impinging air jets can be used to dewater, heat, and dry the web of tissue paper. High velocities of the air jets degrade the paper, and appropriate adjustments to the jet velocity and the distance of the nozzle from the surface of the wet web are crucial to obtain the highest quality product. This work investigated the correlation between the velocity of the air jet and the strength of paper subjected to the impingement method. Papers with an initial moisture content of 20% and various pulp mixes were tested, and the physical properties of papers were explored. After impinging an air jet, different tensile strength limits were obtained in the machine and cross directions. The paper had lower apparent density and higher roughness compared to classical pressing. The dependence of tensile strength and roughness on the fibers composition also was determined. Increasing the amount of eucalyptus fibers in impingement dewatered paper resulted in a decrease in its tensile strength and roughness. The value of elongation before breaking was the highest for softwood papers after the impingement method. The maximum velocity of an air jet that can be used to dewater or dry paper without the risk of damage to the papers was determined.

Abstract Numerous natural dyes were used to dye mediaeval Islamic paper from the tenth to the nineteenth century, using a variety of techniques. The objective of this research is to develop an analytical method using high performance liquid chromatography with diode array detection (HPLC–DAD) to identify natural dyes in forty historical Islamic paper manuscripts from two collections. In addition, novel information was obtained from original treatises containing recipes for dyeing paper and the chronological use of dyes in dyeing mediaeval Islamic paper between the tenth and seventeenth centuries. The results show that thirty-four of the forty manuscripts examined contained dyes. Six natural dyes were detected, including henna, madder, lac, safflower, turmeric, and weld. This is the first study aimed at developing a method for determining various natural dyes in Islamic paper from a wide historical and geographical range in the mediaeval time and to fill significant gaps in the technical and historical knowledge of papermaking.

To develop special insulating paper is of great significance to promote the service life of transformers. Using molecular simulation to guide the development of special insulating paper can greatly reduce the trial-and-error rate and waste of resources in traditional experiments. The effect of different types of polysilsesquioxane (POSS) on cellulose insulating paper was investigated by using molecular simulation. This paper investigated the thermal stability and mechanical properties and electrical characteristics of caged POSS, semi-caged POSS, and ladder-like POSS doped cellulose insulating paper. The results show that POSS with all types can enhance the performance of cellulose insulating paper, and ladder-like POSS possess the best modification effect. The glass transition temperature was increased by 58 K, and the bulk modulus, shear modulus, and elastic modulus of cellulose insulating paper doped with ladder-like POSS can improve up to 27.07%, 45.67%, and 41.28%, respectively. Meanwhile, the dielectric properties of ladder-like POSS modified insulating paper are also significantly improved. The findings of this paper propose a method for the preparation of ladder-like POSS modified insulating paper, which provides theoretical guidance for the experimental preparation of special insulating paper. [ABSTRACT FROM AUTHOR]

Purpose: This paper aims to study the application of high-tolerance and flexible indigenous bacteria and fungi, along with the co-metabolism in recycled paper and cardboard mill (RPCM) wastewater treatment (WWT). Design/methodology/approach: The molecular characterization of isolated indigenous bacteria and fungi was performed by 16S rRNA and 18S rRNA gene sequencing, respectively. Glucose was used as a cometabolic substrate to enhance the bioremediation process. Findings: The highest removal efficiency was achieved for both chemical oxygen demand (COD) and color [78% COD and 45% color removal by Pseudomonas aeruginosa RW-2 (MZ603673), as well as approximately 70% COD and 48% color removal by Geotrichum candidum RW-4 (ON024394)]. The corresponding percentages were higher in comparison with the efficiency obtained from the oxidation ditch unit in the full-scale RPCM WWT plant. Originality/value: Indigenous P. aeruginosa RW-2 and G. candidum RW-4 demonstrated effective capability in RPCM WWT despite the highly toxic and low biodegradable nature, especially with the assistance of glucose. [ABSTRACT FROM AUTHOR]

The main part of companies in Bulgaria are built, however in the 70s, and upgraded last decade. The country supplies around 80 % of its supplies of paper, paperboard and pulp with own production. Integrated treatment of wastes is a priority for realizing closed life cycle of materials. The aim of the present work is to investigate the composition and other important characteristics of biomass wood ash wasted from paper industry. The correlations and associations among the chemical characteristics are also studied to find some basic trends and important relationships between two similar wastes from different enterprises. It was proved that all samples taken contained Ba, Cr, Mn, Ni, Co, Al, Fe, Cu and Zn far below the legal limits for such type of products. A product has a certain anti-acidic effect. The other positive result was that the content of iron is between 34 to 60 mg per 1 kg dry waste. The microscopic photos confirmed that the particles are close to the nano-size materials. The content of the elements C, N, H is in good quantities and ratios, which is a prerequisite for their use as a soil improver. By the results of this study, it was confirmed that all samples produced as a result of the thermal treatment and final low water content achieved are free from pathogen microorganisms and different weed seeds, affecting the yield and soil sustainability. That allows determining the optimal ratio between the used components with a view to obtain products with desired thermal stability and physico-chemical properties as soil improvers. [ABSTRACT FROM AUTHOR]

Carbon fibre-reinforced ultra-high temperature ceramics (UHTCs) are considered a class of promising materials for several applications, the most appealing ones being in the aerospace sector. Reinforcement is necessary to overcome the brittleness and low thermal shock resistance of ceramics and is often provided through the addition of carbon fibres or other carbon-based phases, such as nanotubes, graphene, and graphite. The present work is focused on the toughening of UHTCs through incorporation of 30−50 vol% thin, ordered graphite layers from conventional filter paper followed by hot pressing sintering. Cellulose filter paper was selected because it undergoes thermolysis with no melting stage forming a strong carbonaceous residue that can be used as toughener. Microstructure and mechanical properties of toughened composites were compared to those of other materials reinforced with short carbon fibres and the effect of different distribution of graphite was studied. Addition of graphite allowed toughness to be increased from 3−4 MPa·m1/2 (for un-reinforced materials) to 5.1−5.5 MPa·m1/2, similar to results obtained with short fibre reinforcement. The high-temperature properties, such as strength and toughness as well as oxidation resistance at 1500 ℃, were also examined.

Paper pulp is a lignocellulosic fibrous material used in the industrial production of paper and board products. In addition to cellulose and hemicellulose, paper pulp contains 1 to 20% lignin, depending on the raw materials and pulping process used. Lignin is a heterogenous aromatic polymer that is hydrophobic and more resistant to microbial degradation compared to the easily biodegradable cellulose and hemicellulose. In this study, the biodegradation of paper pulps containing varying amounts of lignin was examined in soil and marine environments using ISO testing methods. Lignin significantly reduced the mineralization of paper pulps to CO2 in both environmental conditions, and a strong inverse correlation between lignin content and the mineralization to CO2 was observed. A similar impact was observed with natural materials containing lignin, such as birch sawdust. Since the calculation of biodegradability in most ISO and EN standards is based solely on the concept of mineralization to CO2, materials containing lignin can receive poor values in these tests. The implications of this for standardized requirements of biodegradability and possible options to overcome testing deficiencies are discussed.

Automatic test paper design is critical in education to reduce workloads for educators and facilitate an efficient teaching process. However, current designs fail to satisfy the realistic teaching requirements of educators, including the consideration of both test quality and efficiency. This is the main reason why teachers still manually construct tests in most teaching environments. In this paper, the quality of tests is quantitatively defined while considering multiple objectives, including a flexible coverage of knowledge points, cognitive levels, and question difficulty. Then, a model based on the technique of linear programming is delicately designed to explore the optimal results for this newly defined problem. However, this technique is not efficient enough, which cannot obtain results in polynomial time. With the consideration of both test quality and generation efficiency, this paper proposes a genetic algorithm (GA) based method, named dynamic programming guided genetic algorithm with adaptive selection (DPGA-AS). In this method, a dynamic programming method is proposed in the population initialization part to improve the efficiency of the genetic algorithm. An adaptive selection method for the GA is designed to avoid prematurely falling into the local optimal for better test quality. The question bank used in our experiments is assembled based on college-level calculus questions from well-known textbooks. The experimental results show that the proposed techniques can construct test papers with both high effectiveness and efficiency. The computation time of the test assembly problem is reduced from 3 hours to 2 seconds for a 5000-size question bank as compared to a linear programming model with similar test quality. The test quality of the proposed method is better than the other baselines.

In the era of Industry 4.0, digital transformation has spurred the swift advancement of technologies, including intelligent predictive maintenance scheduling, prognostics and health management. The accurate prediction of remaining useful life plays a crucial role in these technologies as it extends power equipment’s safe operational duration and decreases the maintenance costs associated with unforeseen shutdowns. Also, the increased accessibility of data for monitoring system conditions has paved the way for the more immense adoption of machine learning models in prognostics and health management for power transformers. At the moment, with the ever-increasing demand for electricity, there is a corresponding increase in the degradation processes of power transformers. Transformers insulation system and more importantly, the paper insulation happens to be the principal part where the degradation is prominent. Therefore, an accurate prediction of the insulating paper condition through its degree of polymerization is required to guarantee the reliability of power transformers. In this regard, the predictions, reliability, and health monitoring of this power equipment can be actualized by modeling the degradation of transformer insulation paper through several machine learning frameworks. In this view, this review paper has been drafted not only to serve as a guide for researchers interested in the fields of transformer insulation system fault prognosis but also to offer insights into potential research directions as existing literature in modeling and evaluating transformer paper insulation is presented.

To improve the accuracy and efficiency of the aging life prediction and assessment of transformer oil-paper insulation, and to make up for the deficiencies of traditional characterizers, such as 2-furfural, carbon monoxide, and carbon dioxide, a method for the simultaneous determination of methanol, ethanol, $n-\mathbf{propanol}$, and $n$-butanol in oil with a single injection is established by headspace-gas chromatography-mass spectrometry. The measured results show that the determination limits of the four alcohol characterizers can be controlled to $\mathbf{10}\ \mu \mathbf{g}/\mathbf{kg}$ level. Based on this method, the change patterns of the above four alcohols with thermal aging time and degree of polymerization are obtained through thermal aging experimental research. Ethanol, $n$-propanol, and $n$-butanol in oil indicate nearly linear correlations with thermal aging time and degree of polymerization, similar to that of methanol. By analyzing 52 sets of measured data of 500 kV EHV transformers in operation, $n$-butanol is found to have excellent performance, and a new method to evaluate the aging state of oil-paper insulation employing $n$-butanol and methanol is proposed along with the aging attention value model. The measured data of 500 kV EHV transformers in operation indicate that the combination of $n$-butanol and methanol as the preferred characterizers can effectively compensate for the shortcoming of traditional characterizers in the early stages of aging, and the feasibility of the method is verified. Two possible pathways for the generation of $n$-butanol by cellulose cleavage during the aging of oil-paper are proposed from the chemical structure of cellulose.

The current study is related to fabrication of point-of-care molecularly imprinted paper-based analytical devices, specifically related to ovarian cancer early stage detection. The task involves creating a paper coated with silver nanoparticles (AgNPs) that can be used as a transducer via surface enhanced Raman spectroscopy (SERS) to detect the threshold level of the biomarker lysophosphatidic acid (LPA) as a template molecule to diagnose ovarian cancer. MIPs are synthetic receptors designed for a targeted molecule which are prepared from polymers in the presence of target such as small molecules, proteins or cells etc. Removal of the template results in cavities which are structurally and electrostatically complementary to the template molecule. The molecularly imprinted polymer (MIP) layer was anchored on vinyl trimethoxy silane modified-paper, which served as a detector by hydrolytically modifying the paper surface with vinyl trimethoxy silane. To detect LPA in serum samples for ovarian cancer, MIP-paper based on SERS was developed. Patients with benign ovarian tumors had an LPA level of 7.73 μM whereas those with ovarian cancer have a level of 16.99 μM. A healthy person's LPA level is 2.92 μM. Consequently, the rise in LPA levels may aid in the early detection of ovarian cancer. The study refers to the use of a point of care device to diagnose ovarian cancer early, which should be simple, effective, and cost-effective. The analytical tool in the study is a sensor with high selectivity and sensitivity, quick assay times, and inexpensive costs. For LPA in serum, the binding constant of modified paper-based MIP ranges from 11.00 μM to 0.08 μM. The amalgamation of nanoparticles on 2D-paper with MIP have lead to develop sensor which can effectively select LPA in untreated real samples like serum.

Evaluating the long-term influence of academic papers in the early stage after publication is crucial for research management and decision-making. Although the total number of citations has been considered as a valid indicator to measure the academic influence of papers, there are still some bottleneck problems in predicting future citation counts. Firstly, it remains a challenging task to select the reasonable features due to the diversity of model features. Secondly, some prediction models are overly complex and their defects may cause prediction bias or even errors. Finally, the most important thing is that very few models possess long-term predictive ability. This paper proposes a prediction model that can provide an early evaluation of the long-term citations, or the long-term influence, of academic papers. The model uses features available immediately after publication or after a certain period of time. Taking academic papers in Information Science and Library Science as our experimental subject, we train the model using three machine learning algorithms and find that the artificial neural network performs satisfactorily. Our findings may offer guidance for research management and decision-making.

Extant studies have focused on exploring the research output of universities in Nigeria, but the measure of the quality of research output using citations per paper (CPP) from the Web of Science (WoS) and Scopus is scarcely discussed. This paper investigated the quality of papers published by the top 76 universities in Nigeria. Five hypotheses on CPP were tested using Kruskal-Wallis and Mann-Whitney tests. These hypotheses tested whether CPP is the same or different i) across six geo-political regions (GPRs), ii) between the two major regions, iii) across three university funding types, iv) in Scopus and WoS, and v) if these two databases are correlated. Results using these two databases indicated that no significant median differences were detected among universities across the six GPRs, between northern and southern Nigeria, and between the three funding types (federal, state, and private). Moreover, no significant median differences in CPP between Scopus and WoS were detected, and CPP in both databases was highly positively correlated (0.879; p = 0.05). A comparison of the mean CPP of Nigeria (5.90) from Scopus with 57 other African countries ranked it 47th despite being ranked third in terms of volume of published articles. Policy prescriptions are made on the implications of using CPP for practice.

Poly(3-hydroxybutyrate) (PHB), a biodegradable polymer, has been studied as a substitute for petroleum-based polymers used for barrier coating to improve the barrier and mechanical properties of paper. In this study, ethyl cellulose (EC), a cellulose derivative, was used to prepare a polymer blend for enhancing the barrier properties of PHB. The prepared PHB/EC blend was then applied as a paper coating material. Additionally, the barrier and mechanical properties of the PHB/EC blend-coated paper based on the PHB/EC mixing ratio and coating weight were analyzed. The results showed that the EC could act as a binder for the PHB/EC blend-coated paper. Consequently, the PHB/EC blend-coated paper exhibited significant improvements in mechanical and barrier properties, including a substantial increase of over 100% in internal bond strength, more than 20% in tensile strength, exceeding 60% enhancement in water resistance, and a remarkable increase of over 90% in air permeability.

Herein, the challenge of accurately classifying the manufacturing origin of printing paper, including continent, country, and specific product, was addressed. One-dimensional convolutional neural network (1D CNN) models trained on infrared (IR) spectrum data acquired from printing paper samples were used for the task. The preprocessing of the IR spectra through a second-derivative transformation and the restriction of the spectral range to 1800 to 1200 cm-1 improved the classification performance of the model. The outcomes were highly promising. Models trained on second-derivative IR spectra in the 1800 to 1200-cm-1 range exhibited perfect classification for the manufacturing continent and country, with an impressive F1 score of 0.980 for product classification. Notably, the developed 1D CNN model outperformed traditional machine learning classifiers, such as support vector machines and feed-forward neural networks. In addition, the application of data point attribution enhanced the transparency of the decision-making process of the model, offering insights into the spectral patterns that affect classification. This study makes a considerable contribution to printing paper classification, with potential implications for accurate origin identification in various fields.

Ultra high frequency (UHF) partial discharge (PD) detection is a common method for transformer oil-paper insulation defect location. However, the accuracy of PD positioning in practical application is easily affected by noise and sensor layout. In order to ensure the effectiveness of PD positioning detection of transformer oil-paper insulation defect, an UHF PD positioning detection platform for oil-paper insulation defects is established. Based on the conventional K-means method, a modified clustering demarcation PD anti-interference positioning method is proposed, which effectively reduces the positioning error. Aiming at the problem of sample clustering demarcation aliasing, when the optimal correction coefficient L is 1.1, the UHF PD positioning error can be reduced to less than 0.1 m, which verifies the effectiveness of the proposed method. Finally, the variation law of positioning error of different sensor layout is analyzed, and the optimal layout scheme of UHF sensor for transformer oil-paper insulation defect detection is proposed, which can provide reference for the layout and positioning of transformer on-line monitoring sensor.

The Bündnis Junger Ärztinnen und Ärzte (BJÄ, Alliance of Young Physicians in Germany) has presented a position paper (PP) on Postgraduate Medical Education (PGME) against the background of an unfolding hospital reform in Germany, and they describe existing deficits of PGME in Germany. Based on this, demands were made of legislators, employers and medical associations which could result in a sweeping reformation of PGME. Hospital reforms can only be accomplished with well trained and motivated physicians. In this respect the BJÄ regards the reform of hospitals and the health-care system as a chance for a reform of PGME, which is long overdue. Legislative competence for PGME lies with the States of the Federal Republic of Germany and this warrants an adjustment of state medical association laws to accommodate the demands of the BJÄ. Generally PGME must be taken into consideration in all health-care legislation, in analogy to the meanwhile globally adopted principle of “Health in all Politics (HiAP)”. The BJÄ has made every endeavour to produce this PP. The responsible stakeholders and actors in the health-care system would be well-advised to take the position paper seriously with a dwindling physician work force in hospitals and serious quality deficits in PGME. Hence, the BJÄ must be comprehensively supported. They need congenial partners to define the scientific foundation of all their demands, to test their application under real life conditions in hospital and outpatient care, to pursue research on the impact on patient care and on the intended transformation of the health-care system. This might best be accomplished by partnering with a scientific as has been the case in many countries for decades.

In the field of book heritage, it is important to develop cleaning/disinfecting treatments that can slow down the degradation of paper to prevent evident and irreversible damage. The objectives of the cleaning treatments are to remove external contaminants and oxidation and decomposition products of the paper, but these processes must not modify the unique characteristics of the book heritage resulting in irreversible changes in the structure of the paper. Recently, several innovative cleaning treatments were developed with the aim of being minimally invasive; however, to assess the effect of these treatments on paper, it is necessary to use a diagnostic non-destructive, rapid, and affordable process. In previous work, we used surface scanning Raman spectroscopy to develop a diagnostic protocol able to follow the aging processes of the paper, discriminating between hydrolysis and oxidation. In this paper, we applied this protocol to study the action of different types of treatments (hydrogel and EUV irradiation), evaluating both their effectiveness and impact on paper parameters. The results reported here demonstrate that the developed in operando diagnostic procedure can follow the changes in the paper structure comparing them to the variability due to the intrinsic inhomogeneity of paper, without sample contact in a rapid and effective way. [ABSTRACT FROM AUTHOR]

Recycled paper has become increasingly used as a raw material in the paper industry. However, hornification limits its application. Herein, the effect of recycling on the mechanical properties and microstructure of khasi pine pulp was systematically studied. The mechanical properties deteriorated and water retention value decreased after recycling. X-ray diffraction and Fourier-transform infrared spectroscopy revealed that cellulose crystallinity increased and partial cocrystallization occurred on cellulose microfibrils. Through the analysis of the morphology of secondary fibers by FQA, the loss of fine fibers caused by each reuse was found. Using the filtration method to prepare the recycled paper reduced the loss of fine fibers and improved the mechanical properties, with the tensile strength of a sample prepared using a sand core filter unit for five cycles (8.37 MPa) being like that of a sample prepared using a paper machine after one cycle. The investigation of the internal structure of the paper showed that the retained fine fibers were bonded between the long fibers, promoting the bonding between the fibers. Fine fibers improve the curling and twisting of fibers to some extent, especially in the first three recycling cycles. The hornification phenomenon of recycled paper was studied from the viewpoint of the fiber components, which is important to promote the development and application prospect of recycled paper. [ABSTRACT FROM AUTHOR]

Abstract Background Undergraduate STEM instructors want to help students learn and retain knowledge for their future courses and careers. One promising evidence-based technique that is thought to increase long-term memory is spaced retrieval practice, or repeated testing over time. The beneficial effect of spacing has repeatedly been demonstrated in the laboratory as well as in undergraduate mathematics courses, but its generalizability across diverse STEM courses is unknown. We investigated the effect of spaced retrieval practice in nine introductory STEM courses. Retrieval practice opportunities were embedded in bi-weekly quizzes, either massed on a single quiz or spaced over multiple quizzes. Student performance on practice opportunities and a criterial test at the end of each course were examined as a function of massed or spaced practice. We also conducted a single-paper meta-analysis on criterial test scores to assess the generalizability of the effectiveness of spaced retrieval practice across introductory STEM courses. Results Significant positive effects of spacing on the criterial test were found in only two courses (Calculus I for Engineers and Chemistry for Health Professionals), although small positive effect sizes were observed in two other courses (General Chemistry and Diversity of Life). Meta-analyses revealed a significant spacing effect when all courses were included, but not when calculus was excluded. The generalizability of the spacing effect across STEM courses therefore remains unclear. Conclusions Although we could not clearly determine the generalizability of the benefits of spacing in STEM courses, our findings indicate that spaced retrieval practice could be a low-cost method of improving student performance in at least some STEM courses. More work is needed to determine when, how, and for whom spaced retrieval practice is most beneficial. The effect of spacing in classroom settings may depend on some design features such as the nature of retrieval practice activities (multiple-choice versus short answer) and/or feedback settings, as well as student actions (e.g., whether they look at feedback or study outside of practice opportunities). The evidence is promising, and further pragmatic research is encouraged.

Hemp hurd fiber, a low-value waste stream from the hemp industry, has potential downstream applications as an alternative to non-renewable plastics for single-use food service ware and packaging applications. Packaging paper substrates made from chemically pulped hemp hurd, mixed in varying ratios with bleached thermomechanical radiata pine pulp were developed and tested. Handsheets were characterized using several mechanical property tests including tensile strength, tearing resistance, burst strength, short-span compression, ring crush, together with Gurley air resistance, contact angle, and Cobb60 tests. Generally, addition of hemp hurd fibers significantly improved handsheet mechanical properties. Hot-pressing of the handsheets so as to approximate molded fiber thermoforming further enhanced their performance, with pure hemp hurd handsheets having the highest mechanical properties and barrier performance. A prototype was successfully thermoformed from hemp fiber, demonstrating overall feasibility of this fibre source for molded fibre objects.

Degradation of insulation paper is a key contributor to the failure of power transformers. Insulation degradation accelerates at elevated temperatures, which highlights the potential for better thermal management to prolong life. While several studies have analyzed the benefits of high thermal conductivity oil for reducing temperatures inside a transformer, this study is an initial assessment of the benefits of high thermal conductivity paper on transformer life. Blending particulates with cellulosic fibers offers a pathway for high thermal conductivity paper (with good dielectric properties), which can reduce internal temperatures. Presently, life extensions that can be achieved by the use of such thermally conducting papers were estimated, with the thermal conductivity of the paper being the key parameter under study. The analytical-numerical thermal model used in this study was validated against experimental measurements in a distribution transformer, adding confidence to the utility of the model. This model was then used to provide estimates of hot-spot temperature reduction resulting from the use of papers with higher thermal conductivity than baseline. Transformer life was predicted conventionally by tracking the degree of polymerization of paper over time, based on an Arrhenius model. Results indicate that increasing the thermal conductivity of paper from 0.2 W/mK (baseline) to 1 W/mK reduces the hot spot temperature by 10 °C. While degradation significantly depends on the moisture and oxygen content, the model shows that such a temperature reduction can increase life for all conditions, by as much as a factor of three.

Abstract This study identifies important factors for designing an effective biomimetic paper‐based fog harvesting substrate by examining the harvesting properties of different surfaces, including glass, polyethylene, and superhydrophobic paper. In laboratory‐scale fogging tests, the wetting behavior of the substrates is characterized, and the importance of the tilt angle of the respective surface relative to the fog flow is elaborated. Because successful fog harvesting requires both efficient accumulation of water droplets on the surface (by condensation and collision) and sufficient but not excessive roll‐off of the liquid, the amount of water finally collected is clearly related to the pinning effect, which should prevent the smallest droplets from being carried away by the wind but must not lead to full and permanent wetting of the surface. Coalescence is identified as a major phenomenon to improve droplet roll‐off. In this context, superhydrophobic paper indicates to be a more effective water collector than glass or polyethylene, especially when oriented vertically, since it allows the droplets to roll off very efficiently. Finally, the addition of glass particles to the superhydrophobic coating is proposed as a means of enhancing pinning and improving the fog harvesting efficiency.

This report presents an investigation into the use of carbon paper electrodes prepared from chitosan-adhered graphene magnetite nanoparticles for the analysis of Cr(VI). The preparation and storage of carbon paper electrodes is a simple process, and these electrodes are easier to replace than electrodes modified by more conventional methods. The electrochemical detection of Cr(VI) using square wave adsorption cathodic dissolution voltammetry (SWAdCSV) with high selectivity and sensitivity, as well as the optimum conditions for the preparation of the electrodes and the electrode parameters affecting the SWAdCSV signal, were the main points of focus of the investigation. Cr(VI) was detected linearly in the range of 4-40 μg L-1 with a detection limit of 2.84 μg L-1. The electrode output precision, calculated as %RSD, was 7.16% (n = 6), and this was the measurement used for the detection of Cr(VI) in standard and test samples with recoveries between 89% and 114%. The results were consistent with those obtained using the standard UV-Vis spectrophotometric method with a paired t-test at 95% confidence level. [ABSTRACT FROM AUTHOR]

Non-enzymatic electrochemical blood glucose sensors often suffer from issues such as requiring an alkaline environment, limited monitoring range, and poor anti-interference properties. Carbon substrates have been demonstrated to improve the performance of non-enzymatic sensors, but complex and energy-consuming manufacturing processes restrict their use. Herein, a simple and green approach for the preparation of 3D porous Au/Au-Pt networks (PAAPNs) is proposed using tissue paper for recycling as the nanomaterial substrate to deposit Au-Pt bimetallic nanoparticles. The unique structure of the PAAPNs sensor allows for low-potential operation (-1.0 V) with a wide monitoring range (-0.25 to 36 mM) in a neutral environment. Moreover, the sensor exhibited excellent selectivity (<10% response of interference) even without the use of an anti-interference outer membrane. Further investigation using density functional theory (DFT) simulation revealed the synergistic effect between Au and Pt in promoting glucose oxidation. Overall, this work provides a simple and low-carbon footprint method for creating carbon substrates from tissue paper for recycling, offering new opportunities for fabricating novel value-added nanomaterials for medical sensing applications. [ABSTRACT FROM AUTHOR]

Development of low-cost, efficient, and stable oxygen evolution electrocatalysts is crucial for the conversion and storage of renewable energy. Therefore, an effective integrated heterostructure catalyst is needed to achieve a lower overpotential during oxygen evolution process. In this paper, cobalt-zinc bimetallic MOF precursors are used as templates to prepare bimetallic cobalt-based selenides with good oxygen evolution catalytic activity and stability on carbon fiber paper. Due to the high specific surface area and porous structure of the coupling structure of nanorods and polyhedra, and the strong electronic coupling between CoSe 2 and ZnSe on nanorods. CoSe 2 -ZnSe/CP exhibits excellent electrocatalytic activity in 1 M KOH solution. It only requires an overpotential of 275 mV to reach the current density of 10 mA cm-2, and the Tafel slope is 68.9 mV dec-1. In addition, after 12 h of continuous operation of CoSe 2 -ZnSe/CP, the activity decay of the catalyst is negligible. This work provides a method for the design of heterogeneous bimetallic selenide integrated oxygen evolution electrocatalysts. [Display omitted] • The CoSe 2 -ZnSe/CP catalyst is obtained by selenization of MOF precursor at high temperature. • The catalyst has unique nanorod-coupled polyhedral morphology and high specific surface area. • The strong electron coupling between CoSe 2 and ZnSe improves the oxygen evolution activity. • CoSe 2 -ZnSe/CP exhibits low overpotential, high exchange current density and fast kinetics. [ABSTRACT FROM AUTHOR]

Georgia Brady Barnhill's book, "Gems of Art on Paper: Illustrated American Fiction and Poetry, 1765–1885," provides a comprehensive and detailed account of the growth of illustrated American fiction and poetry. Barnhill explores the development of the illustration industry, from early experiments to technological advancements, and the evolution of illustrators and craftspeople. The book focuses on a neglected period of book illustration and offers a holistic view of mainstream literary illustration, discussing specific editions, illustration technologies, and important creators. Barnhill's work is a valuable resource for scholars and researchers interested in the history of book illustration in America. [Extracted from the article]

Carbon paper is commonly used for catalytic electrode preparation because of its high conductivity, corrosion resistance, and stability. However, traditional electrode preparation methods are inappropriate for highly hydrophobic carbon paper. In this paper, a high‐activity carbon paper catalytic electrode was prepared using multistrategies cold plasma modification to create atomic structural defects, dope N and Cu elements, and introduce oxygen‐containing functional groups. Analyses show that the bombardment of high‐energy particles caused atomic structural defects. Nitrogen and copper entered the carbon paper through plasma‐induced chemical recombination and physical adsorption, reaching 5.26% and 3.83%, respectively. Ethanol‐based plasma introduced oxygen‐containing functional groups to improve hydrophilicity. Finally, the plasma‐prepared electrode exhibited a reduction efficiency of 87.69% in an electrocatalytic nitrate reduction reaction. [ABSTRACT FROM AUTHOR]

The increase in energy valorization of paper sludge and biomass waste through incineration results in a rise in waste paper fly ash (WPFA), often perceived as hazardous and requiring specific treatment. In this study, natural carbonation technology at a pilot scale was employed to mitigate the hazardous nature of WPFA by enhancing the stabilization of metal and metalloid trace elements (MMTE), particularly barium (Ba) and lead (Pb) leaching. Natural carbonation of WPFA was found to be optimal at a water/solid ratio of 0.3 L/kg under natural temperature and humidity conditions. Batch leaching tests based on thermodynamic equilibrium were used to assess MMTE solubility concerning pH in both non-carbonated and carbonated WPFA at natural pH. After 7 days of natural carbonation, the leaching concentration of Ba and Pb was below the legal limit in France. The concentration of Ba and Pb in carbonated samples decreased by 98.5% and 98%, respectively. Analyses using thermogravimetry, X-ray diffraction, scanning electron microscopy, and energy-dispersive spectroscopy demonstrated the increased formation and quantity of calcite (CaCO3) with longer carbonation times, along with the formation of new minerals as BaCO3 and PbCO3, confirming the immobilization of these elements post-carbonation. The leaching behavior and release potential of carbonated WPFA were further evaluated using the four-stage sequential extraction procedure proposed by the European Commission’s Bureau of Reference (BCR). The speciation of Ba and Pb shifted significantly from the soluble substance (F1) at 17.6% and 14.8%, respectively, to the carbonate fraction (F2) at 0.49% and 0.02% after 90 days of carbonation. The percolation water collected during the carbonation process adheres to discharge standards into the sea.

Conventional techniques for sharing paper documents in teleconferencing tend to introduce two inconsistencies: 1) media inconsistency: a paper document is converted into a digital image on the remote site; 2) space inconsistency: a workspace deliberately inverts the partner’s handwriting to make a document easy to read. In this paper, we present a novel system that eliminates these inconsistencies. The media and space inconsistencies are resolved by reproducing a real paper document on a remote site and allowing a user to handover the paper document to a remote partner across a videoconferencing display. From a series of experiments, we found that reproducing a real paper document contributes to a higher sense of information sharing. We also found that handing over a document enhances a sense of space sharing, regardless of whether the document is digital or paper-based. These findings provide insights into designing systems for sharing paper documents across distances.

Since the last two decades, the use of natural fiber reinforced polymer composites has garnered significant application considerations over the synthetic fiber reinforced composites due to their numerous advantages and unique properties. Likewise, epoxy resin has attracted the interest of many researchers for composite synthesis, basically because of its chemical stability, thermal and mechanical characteristics. Hence, the primary aim of this study was to investigate the influence of dombeya fiber and paper particulate on the physical and mechanical properties of dombeya fiber and paper particulate-reinforced polymer composites for structural applications. Dombeya fiber and paper particles are renewable and biodegradable materials, thereby making them environmentally friendly materials to replace synthetic materials. Hand lay-up technique was utilized to fabricate the hybrid-reinforced biocomposites after which they were subjected to mechanical, wear, density, and moisture absorption properties. The surface morphology of the fractured surface was also analyzed to investigate its microstructural features. It was discovered from the results that hybrid biocomposites demonstrated improved properties over the unreinforced composite, with composites from 9-wt% dombeya fiber-paper particles reinforced biocomposite exhibiting the most suitable properties with commensurate density with the unreinforced epoxy matrix. These obtained characteristics support the material as a suitable material for biomedical apparatus application such as orthopedic implants, surgical instruments, and bone fixation devices.

Abstract Personalized healthcare management is an emerging field that requires the development of environment‐friendly, integrated, and electrochemical multimodal devices. In this study, the concept of integrated paper‐based biosensors (IFP−Multi) for personalized healthcare management is introduced. By leveraging ink printing technology and a ChatGPT–bioelectronic interface, these biosensors offer ultrahigh areal‐specific capacitance (74633 mF cm−2), excellent mechanical properties, and multifunctional sensing and humidity power generation capabilities. More importantly, the IFP−Multi devices have the potential to simulate deaf‐mute vocalization and can be integrated into wearable sensors to detect muscle contractions and bending motions. Moreover, they also enable monitoring of physiological signals from various body parts, such as the throat, nape, elbow, wrist, and knee, and successfully record sharp and repeatable signals generated by muscle contractions. In addition, the IFP−Multi devices demonstrate self‐powered handwriting sensing and moisture power generation for sweat‐sensing applications. As a proof‐of‐concept, a GPT 3.5 model‐based fine‐tuning and prediction pipeline that utilizes recorded physiological signals through IFP−Multi is showcased, enabling artificial intelligence with multimodal sensing capabilities for personalized healthcare management. This work presents a promising and ecofriendly approach to developing paper‐based electrochemical multimodal devices, paving the way for a new era of healthcare advancements.