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Häufig liegen natürliche und technische partikuläre Nanomaterialien (NM) in Formulierungen (i.d.R. Suspensionen, Emulsionen oder Suspoemulsionen) und Produkten vor, welche aus mehreren dispersen Phasen und komplexen Dispersionsmedien bestehen. Dabei gilt es, spezifische Grenzflächeneigenschaften der Partikel, ihre Wechselwirkungen untereinander und mit dem Dispersionsmedium zu berücksichtigen. Beispielsweise bestimmen die Grenzflächeneigenschaften, ob sich die Partikel eher in wässriger Phase oder in Lipidphase bzw. an deren Phasengrenzen anordnen. Die Grenzflächeneigenschaften werden maßgeblich durch die Adsorption gelöster Spezies beeinflusst, hängen also von der Zusammensetzung des Dispersionsmediums ab. In dieser Arbeit werden mit theoretischer und empirischer Forschung wie methodischer Vorgehensweise neue Beiträge zur Nanopartikelcharakterisierung erarbeitet. Die notwendige Ausarbeitung von Richtlinien an SOPs für die Charakterisierung von Nanopartikelsystemen wird hierbei berücksichtigt. Diese Richtlinien ermöglichen eine Anwendung im Kontext verschiedenartiger Analyseaufgaben, und die Ergebnisse können dem Leser dieser Arbeit unmittelbar Nutzen bringen.

This book describes different aspects of characterization and detection of nanomaterials in liquid disperse systems, such as suspensions, emulsions and suspoemulsions. Natural and technical particulate nanomaterials (NMs) are often present in formulations and products consisting of several disperse phases and complex dispersion media. Specific interfacial properties of the particles, their interactions with each other and with the dispersion medium, have to be considered. For example, the interfacial properties determine whether the particles tend to be arranged in aqueous or lipid phases or at their phase boundaries. The interfacial properties are significantly influenced by the adsorption of dissolved species, i.e., they depend on the composition of the dispersion medium. This poses great challenges for the characterization of these nanoparticle systems and requires adequate preparation methods. The nanoparticle measurement techniques aim at a deep physico-chemical understanding of the dispersity state of nanoparticle systems. Since the dispersity state of nanoparticle systems in an application usually does not correspond to their original manufacturing process, the formulation of new or improved product properties is of decisive importance. The characterization of nanoparticles in complex formulations or matrices requires an adequate sample preparation based on an existing or yet to be developed Standard Operating Procedure (SOP). The structure of the SOPs includes the dispersion regulations, which are of essential importance for comparing reproducible results of nanoparticle measurement with respect to comparability and transferability worldwide. The aim is to separate and isolate relevant NMs with knowledge of the interrelationships.

Nanoscience and nanotechnologies are leading to a major point to our understanding of nature. Nanotechnology can be generally defined as creation and use of nano-sized systems, devices, and structures which have special functions or properties because of their small size. This volume on Nanotechnology Applications in Health and Environmental Sciences focuses on biotechnological and environmental applications of nanomaterials. It covers popular and various nanomedical topics such as oncology, genetics, and reconstructive medicine. Additionally, many chapters give leading-edge information on nano-sensor applications and usage in specific disciplines. Also, two chapters on novel subjects have been included on Lantibiotics and microbiota. This book should be useful for nanotechnologists, microbiologists, and researchers interested in nanomedicine and nano-biotechnology, as well as environmental nanotechnology.

Since the second edition of Liquid-Vapor Phase-Change Phenomena was written, research has substantially enhanced the understanding of the effects of nanostructured surfaces, effects of microchannel and nanochannel geometries, and effects of extreme wetting on liquid-vapor phase-change processes. To cover advances in these areas, the new third edition includes significant new coverage of microchannels and nanostructures, and numerous other updates. More worked examples and numerous new problems have been added, and a complete solution manual and electronic figures for classroom projection will be available for qualified adopting professors.

The Handbook of Materials Modeling, 2nd edition is a six-volume major reference serving a steadily growing community at the intersection of two mainstreams of global research: computational science and materials science and technology. This extensively expanded new edition reflects the significant developments in all aspects of computational materials research over the past decade, featuring progress in simulations at multiple scales and increasingly more realistic materials models. Thematically separated into two mutually dependent sets – “Methods: Theory and Modeling (MTM)” and “Applications: Current and Emerging Materials (ACE)” – the handbook runs the entire gamut from theory and methods to simulations and applications. Readers benefit from its in-depth coverage of a broad methodological spectrum extending from advanced atomistic simulations of rare events to data-driven artificial intelligence strategies for materials informatics in the set MTM, as well as forefront emphasis onmaterials of far-ranging societal importance such as photovoltaics and energy-relevant oxides, and cutting-edge applications to materials for spintronic devices, graphene, cement, and glasses in the set ACE. The thorough, interconnected coverage of methods and applications, together with a line-up of internationally acclaimed editors and authors, will ensure the Handbook of Material Modeling's standing as an enduring source of learning and inspiration for a global community of computational materials scientists.

Graphene–electrolyte systems are commonly found in cutting-edge research on electrochemistry, biotechnology, nanoelectronics, energy storage, materials engineering, and chemical engineering. The electrons in graphene intimately interact with ions from an electrolyte at the graphene–electrolyte interface, where the electrical or chemical properties of both graphene and electrolyte could be affected. The electronic behavior therefore determines the performance of applications in both Faradaic and non-Faradaic processes, which require intensive studies. This book systematically integrates the electronic theory and experimental techniques for both graphene and electrolytes. The theoretical sections detail the classical and quantum description of electron transport in graphene and the modern models for charges in electrolytes. The experimental sections compile common techniques for graphene growth/characterization and electrochemistry. Based on this knowledge, the final chapter reviews a few applications of graphene–electrolyte systems in biosensing, neural recording, and enhanced electronic devices, in order to inspire future developments. This multidisciplinary book is ideal for a wide audience, including physicists, chemists, biologists, electrical engineers, materials engineers, and chemical engineers.

This textbook and comprehensive reference source and serves as a timely, practical introduction to the principles of nanotribology and nanomechanics. This 4th edition has been completely revised and updated, concentrating on the key measurement techniques, their applications, and theoretical modeling of interfaces. It provides condensed knowledge of the field from the mechanics and materials science perspectives to graduate students, research workers, and practicing engineers.

This Springer Laboratory volume is a practical guide for scientists and students dealing with the measurement of mechanical properties of polymers at the nanoscale through AFM force-distance curves.In the first part of the book the reader will find a theoretical introduction about atomic force microscopy, focused on force-distance curves, and mechanical properties of polymers. The discussion of several practical issues concerning the acquisition and the interpretation of force-distance curves will help scientists starting to employ this technique.The second part of the book deals with the practical measurement of mechanical properties of polymers by means of AFM force-distance curves. Several'hands-on'examples are illustrated in a very detailed manner, with particular attention to the sample preparation, data analysis, and typical artefacts. This section gives a complete overview about the qualitative characterization and quantitative determination of the mechanical properties of homogeneous polymer samples, polymer brushes, polymer thin films, confined polymer samples, model blends and microstructured polymer blends through AFM force-distance curves. The book also introduces to new approaches and measurement techniques, like creep compliance and force modulation measurements, pointing out approximations, limitations and issues requiring further confirmation.

Nanomaterials attract tremendous attention in recent researches. Although extensive research has been done in this field it still lacks a comprehensive reference work that presents data on properties of different Nanomaterials. This Handbook of Nanomaterials Properties will be the first single reference work that brings together the various properties with wide breadth and scope.

This dissertation contributes to the understanding of fundamental issues in the highly interdisciplinary field of colloidal science. Beyond colloid science, the system also serves as a model for studying interactions in biological matter. This work quantitatively investigated the scaling laws of the characteristic lengths of the structuring of colloidal dispersions and tested the generality of these laws, thereby explaining and resolving some long-standing contradictions in literature. It revealed the effect of confinement on the structuring, independently of specific properties of the confining interfaces. In addition, it resolved the influence of roughness and charge of the confining interfaces on the structuring and as well providing a method to measure the effect of surface deformability on colloidal structuring.

This book is concerned with functional nanomaterials, materials containing specific, predictable nanostructures whose chemical composition, or interfacial structure enables them to perform a specific job: to destroy, sequester, or detect some material that constitutes an environmental threat. Nanomaterials have a number of features that make them ideally suited for this job: they have a high surface area, high reactivity, easy dispersability, and rapid diffusion, to name a few. The purpose of this book is to showcase how these features can be tailored to address some of the environmental remediation and sensing/detection problems faced by mankind today. A number of leading researchers have contributed to this volume, painting a picture of diverse synthetic strategies, structures, materials, and methods. The intent of this book is to showcase the current state of environmental nanomaterials in such a way as to be useful both as a research resource and as a graduate level textbook. We have organized this book into sections on nanoparticle-based remediation strategies, nanostructured inorganic materials (e.g. layered materials like the apatites), nanostructured organic/inorganic hybrid materials, and the use of nanomaterials to enhance the performance of sensors.

In the 1990s, nanoparticles and quantum dots began to be used in optical, electronic, and biological applications. Now they are being studied for use in solid-state quantum computation, tumor imaging, and photovoltaics. Handbook of Nanophysics: Nanoparticles and Quantum Dots focuses on the fundamental physics of these nanoscale materials and struct

The atomic force microscope (AFM) has been successfully used to perform nanorobotic manipulation operations on nanoscale entities such as particles, nanotubes, nanowires, nanocrystals, and DNA since 1990s. There have been many progress on modeling, imaging, teleoperated or automated control, human-machine interfacing, instrumentation, and applications of AFM based nanorobotic manipulation systems in literature. This book aims to include all of such state-of-the-art progress in an organized, structured, and detailed manner as a reference book and also potentially a textbook in nanorobotics and any other nanoscale dynamics, systems and controls related research and education. Clearly written and well-organized, this text introduces designs and prototypes of the nanorobotic systems in detail with innovative principles of three-dimensional manipulation force microscopy and parallel imaging/manipulation force microscopy.

Mechanics Over Micro and Nano Scales covers the recent developments in the fields of mechanics in all forms over micro, meso and nano scales. Special emphasis is given to related novel applications and includes fundamental aspects of fluid and solid mechanics, soft matters, scaling laws, and synthetic biology. At the micro and nano scales, realization of many technologically viable ideas relies on the skillful integration of mechanics at macroscopic and molecular levels, both for solids as well as fluids. Research in the related areas is no longer confined to the understanding of the governing the physics of the system, but is also responsible for triggering a technological revolution at small scales. This book also: discusses the fundamentals of mechanics over micro and nano scales in a level accessible to multi-disciplinary researchers, with a balance of mathematical details and physical principles, covers life sciences and chemistry for use in emerging applications related to mechanics over small scales and demonstrates the explicit interconnection between various scale issues and the mechanics of miniaturized systems.Mechanics Over Micro and Nano Scales is an ideal book for researchers and engineers working in mechanics of both solids and fluids.

This book presents the biophysics of hair. It deals with the structure of hair, its mechanical properties, the nanomechanical characterization, tensile deformation, tribological characterization, the thickness distribution and binding interactions on hair surface. Another important topic of the book is the health of hair, human hair and skin, hair care, cleaning and conditioning treatments and damaging processes. It is the first book on the biophysical properties of hair.

Nanomaterial science has received increasing attention over the last twenty years. As more and more applications are discovered in medical sciences, physics, chemistry, polymer science, material science and engineering, there is a growing need for a basic understanding of nanoparticle interactions and their role in the thermodynamic and kinetic stability of nanodispersions.'Nanodispersions: Interactions, Stability and Dynamics'collects research in nanodispersion interactions and stability by the distinguished Eli Ruckenstein and his research group at SUNY-Buffalo. This book provides valuable insight into current investigations of nanotechnology.

Providing the framework for breakthroughs in nanotechnology, this landmark publication is the first comprehensive reference to cover both fundamental and applied physics at the nanoscale. After discussing the theoretical principles and measurements of nanoscale systems, the organization of the set follows the historical development of nanoscience. Each peer-reviewed chapter presents a didactic treatment of the physics underlying the nanoscale materials, applications, and detailed experimental results. State-of-the-art scientific content is enriched with fundamental equations and illustrations, many in color.

This book contains 35 review articles on nanoscience and nanotechnology that were first published in Nature Nanotechnology, Nature Materials and a number of other Nature journals. The articles are all written by leading authorities in their field and cover a wide range of areas in nanoscience and technology, from basic research (such as single-molecule devices and new materials) through to applications (in, for example, nanomedicine and data storage).

The tools of nanodiagnostics, nanotherapy, and nanorobotics are expected to revolutionize the future of medicine, leading to presymptomatic diagnosis of disease, highly effective targeted treatment therapy, and minimum side effects. Handbook of Nanophysics: Nanomedicine and Nanorobotics presents an up-to-date overview of the application of nan

For centuries, electrochemistry has played a key role in technologically important areas such as electroplating or corrosion. In recent decades, electrochemical methods are receiving increasing attention in important strongly growing fields of science and technology such as nanosciences (nanoelectrochemistry) and life-sciences (organic and biological electrochemistry). Characterization, modification and understanding of various electrochemical interfaces or electrochemical processes at the nanoscale, has led to a huge increase of the scientific interest in electrochemical mechanisms as well as of application of electrochemical methods in novel technologies. This book presents exciting emerging scientific and technological aspects of the introduction of the nanodimension in electrochemical approaches are presented in 12 chapters/subchapters.

The Most Detailed Resource Available on Points of Zero ChargeWith their work growing in complexity, chemists involved with surface phenomena-related projects have outgrown the common resources available to them on points of zero charge (PZC) of oxides. Reporting on a limited number of materials in a limited number of scenarios, these resources ofte

Conducting Polymers with Micro or Nanometer Structure describes a topic discovered by three winners of the Nobel Prize in Chemistry in 2000: Alan J. Heeger, University of California at Santa Barbara, Alan G. MacDiarmid at the University of Pennsylvania, and Hideki Shirakawa at the University of Tsukuba. Since then, the unique properties of conducting polymers have led to promising applications in functional materials and technologies. The book first briefly summarizes the main concepts of conducting polymers before introducing micro/nanostructured conducting polymers dealing with their synthesis, structural characterizations, formation mechanisms, physical and chemical properties, and potential applications in nanomaterials and nanotechnology. The book is intended for researchers in the related fields of chemistry, physics, materials, nanomaterials and nanodevices. Meixiang Wan is a professor at the Institute of Chemistry, Chinese Academy of Sciences, Beijing.

This volume is concerned with functional nanomaterials: materials containing specific, predictable nanostructure whose chemical composition or interfacial structure enable them to perform a specific job — destroy, sequester or detect some material that constitutes an environmental threat. Nanomaterials have a number of features that make them ideally suited for this job: high surface area, high reactivity, easy dispersability, and rapid diffusion. The purpose of this book is to showcase how these features can be tailored to address some of the environmental remediation and sensing/detection problems faced today. The leading researchers contributing to this volume paint a picture of diverse synthetic strategies, structures, materials and methods. The book is organized into sections on nanoparticle-based remediation strategies, nanostructured inorganic materials (such as layered materials like the apatites), nanostructured organic/inorganic hybrid materials, and the use of nanomaterials to enhance the performance of sensors. The chemistries captured by the contributors form a rich and colorful tapestry.

Microfluidic Technologies for Miniaturized Analysis Systems provides a comprehensive overview of the fluidic aspects of Lab-on-a-Chip technology. This book describes the most important and state-of-the-art microfluidic technologies and the underlying principles utilized in the implementation of fluidic protocols of miniaturized analysis systems. This book discusses many of the effects, outcomes, and techniques which are unique to microfluidic systems. The specific components of this technology toolbox are elucidated through research and examples presented by some of the most renowned experts in the field. Microfluidic Technologies for Miniaturized Analysis Systems is an important reference for professionals and academic researchers seeking information about the latest techniques, including: Control and pumping of small amounts of liquid Particle and cell manipulation Micromixing Separation technology Bioanalytic methods About the MEMS Reference Shelf:The MEMS Reference Shelf is a series devoted to Micro-Electro-Mechanical Systems (MEMS), which combine mechanical, optical, or fluidic elements on a common microfabricated substrate to create sensors, actuators, and microsystems. This series strives to provide a framework where basic principles, known methodologies, and new applications are integrated in a coherent and consistent manner.STEPHEN D. SENTURIA, MASSACHUSETTS INSTITUTE OF TECHNOLOGY,PROFESSOR OF ELECTRICAL ENGINEERING, EMERITUS

Modern materials science and biophysics has increasingly focused on studying and controlling intermolecular interactions on the single-molecule level. The peer-reviewed literature contains an increasing number of studies that either measure the interaction forces directly or use mechanical forces to deform the molecules or trigger structural transitions. Molecular force spectroscopy is the result of unprecedented advances in the capabilities of modern force measurement instruments in the past decade and describes a number of techniques that use mechanical force measurements to study interactions between single molecules and molecular assemblies in chemical and biological systems. Examples of these techniques include atomic force microscopy, optical tweezers, surface forces apparatus, and magnetic tweezers. These techniques typically target a specific range of experimental systems and geometries, but all use mechanical force transducers to apply and detect nanonewton range forces between single molecules in condensed phases. Molecular force spectroscopy measurements have been very important for studies of adhesion and friction forces, where they provided the first truly nanoscale capabilities. Force spectroscopy has been instrumental in understanding mechanical properties and nanoscale dynamics of polymer systems from elasticity to nanoscale phase segregation. In biophysics, applications range from probing protein folding to direct mapping of intermolecular interaction potentials. This volume presents a review of modern force spectroscopy, including fundamentals of intermolecular forces, technical aspects of the force measurements, and practical applications. The Handbook begins with a review of fundamental physics of loading single and multiple chemical bonds on the nanometer scale with a discussion of thermodynamic and kinetic models of binding forces and dissipation effects in nanoscale molecular contacts, covers practical aspects of modern single-molecule level techniques, and concludes with applications of force spectroscopy to chemical and biological processes. Computer modeling of force spectroscopy experiments is addressed as well. In sum, Handbook of Molecular Force Spectroscopy is a comprehensive, authoritative guide to planning, understanding, and analyzing modern molecular force spectroscopy experiments with an emphasis on biophysical research.

Because of their structural and dynamical properties, microheterogeneous systems have been employed as solvent and reaction media both to synthesize and stabilize nanoparticles. Following this route, inside their nanometer-sized heterogeneities the nanoparticles of many different substances have been incorporated. The book shows the distinct advantages of this synthetic strategy over that of many other methods. Moreover, it furnishes to the reader a collection of theoretical and experimental facts allowing him to reduce the number of trial and errors necessary to arrive at an optimal synthetic protocol.

In the last few years there has been significant progress in the development of microfluidics and nanofluidics at the application as well as at the fundamental and simulation levels. This book provides a comprehensive summary of these changes describing fluid flow in micro and nano configurations. Where as in their previous book entitled Microflows: Fundamentals and Simulation the authors covered scales from one hundred nanometers to microns (and beyond), in this new book they discuss length scales from angstroms to microns (and beyond). While still maintaining the emphasis on fundamental concepts with a mix of semianalytical, experimental, and numerical results, this book outlines their relevance to modeling and analyzing functional devices. The text has been divided into three main subject categories: gas flows; liquid flows; and simulation techniques. The majority of the completely new developments in this book are in liquid flows and simulation techniques chapters withmodified information throughout the rest of the book. This book can be used in a two-semester graduate course. Also, selected chapters can be used for a short course or an undergraduate-level course. The book is suitable for graduate students and researchers in fluid mechanics, physics, and in electrical, mechanical and chemical engineering. Review of earlier volume: Applied Mechanics, 2002:'Among recent books that addressed the physics of micro devices, the present one... is perhaps the best of the bunch.... Microflows: Fundamentals and Simulation has a lot to offer and is certainly recommended as a good place to start for MEMS students interested in flow physics.'

With this handbook the distinguished team of editors has combined the expertise of leading nanomaterials scientists to provide the latest overview of this field. The authors cover the whole spectrum of nanomaterials, ranging from theory, synthesis, properties, characterization to application, including such new developments as: quantum dots, nanoparticles, nanoporous materials, as well as nanowires, nanotubes and nanostructural polymers nanocatalysis, nanolithography, nanomanipulation methods for the synthesis of nanoparticles. The book can thus be recommended for everybody working in nanoscience: Beginners can acquaint themselves with the exciting subject, while specialists will find answers to all their questions plus helpful suggestions for further research.

This second edition of Handbook of Micro/Nanotribology addresses the rapid evolution within this field, serving as a reference for the novice and the expert alike. Two parts divide this handbook: Part I covers basic studies, and Part II addresses design, construction, and applications to magnetic storage devices and MEMS.Discussions include:surface physics and methods for physically and chemically characterizing solid surfacesroughness characterization and static contact models using fractal analysissliding at the interface and friction on an atomic scalescratching and wear as a result of slidingnanofabrication/nanomachining as well as nano/picoindentationlubricants for minimizing friction and wearsurface forces and microrheology of thin liquid filmsmeasurement of nanomechanical properties of surfaces and thin filmsatomic-scale simulations of interfacial phenomenamicro/nanotribology and micro/nanomechanics of magnetic storage devicesThis comprehensive book contains 16 chapters contributed by more than 20 international researchers. In each chapter, the presentation starts with macroconcepts and then lead to microconcepts. With more than 500 illustrations and 50 tables, Handbook of Micro/Nanotribology covers the range of relevant topics, including characterization of solid surfaces, measurement techniques and applications, and theoretical modeling of interfaces.What's New in the Second Edition? New chapters on:AFM instrumentationSurface forces and adhesionDesign and construction of magnetic storage devicesMicrodynamical devices and systemsMechanical properties of materials in microstructureMicro/nanotribology and micro/nanomechanics of MEMS devices