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This book provides a concise overview of the use of ionic liquids as electrolytes in lithium-ion batteries (LIBs) from a theoretical and computational perspective. It focuses on computational studies to understand the behavior of lithium ions in different ionic liquids and to optimize the performance of ionic liquid-based electrolytes. The main features of the book are as follows:• Provides a thorough understanding of the theoretical and computational aspects of using ionic liquids as electrolytes in LIBs, including the evaluation and reproducibility of the theoretical paths.• Covers various computational methods such as density functional theory, molecular dynamics, and quantum mechanics that have been used to study the behavior of lithium ions in different solvents and to optimize the performance of ionic liquid-based electrolytes.• Discusses recent advances such as new computational methods for predicting the properties of ionic liquid-based electrolytes, new strategies for improving the stability and conductivity of these electrolytes, and new approaches for understanding the kinetics and thermodynamics of redox reactions with ionic liquids.• Suggests how theoretical insights can be translated into practical applications for improving performance and safety.This monograph will be of interest to engineers working on LIB optimization.

This book provides a detailed description of hydrogen production through water electrolysis. It starts with the theoretical description of the chemical, thermodynamic, and kinetic issues related to the electrolysis of water. The main available technologies and the ones under development are detailed from a technical and a scientific point of view. At the end of the book Dr. Cavaliere describes the main hydrogen applications and their contribution to the grand energy transition that is expected by the middle of the century. The book also examines the economic issues related to the transition toward the hydrogen society.

Electrochemical membrane technology has drawn extensive attention worldwide during the past decade in water and wastewater treatment. Coupling electrochemical process with membrane technology not only enables a higher removal or decomposition of pollutants in waters, but also ensures a more effective control of membrane fouling as well as a more highly selective separation process. The recent development of electrochemical membrane technology has also extended its applications in desalination, energy harvest, and resource recovery from seawater and wastewaters. Electrochemical Membrane Technology for Water and Wastewater Treatment consolidates state-of-the-art research developments in electrochemical membrane technology in water reclamation and sustainability in terms of fundamental theories, membrane and electrode materials, reactor designs, fouling control mechanisms and applications. Electrochemical Membrane Technology for Water and Wastewater Treatment also introduces fundamental theories and applications of electrochemical membrane technology. The knowledge gaps and future research perspectives in electrochemical membrane technology are also addressed. This book is an excellent resource for the understanding of fundamental theories, latest developments and future prospects in electrochemical membrane technology, which can benefit a broad audience of researchers and engineers working in water purification, membrane technology and electrochemical process. - Consolidates scattered knowledge of electrochemical membrane technology into a more accessible resource - Provides a comprehensive review of fundamental theories, membrane materials and module design as well as the latest developments of electrochemical membrane technology - Provides the state-of-art review on the applications of electrochemical membrane technology - Includes detailed discussion on the challenges and prospects of electrochemical membrane technology in different applications

The Second Edition of Introduction to Electrochemical Science and Engineering outlines the basic principles and techniques used in the development of electrochemical engineering related technologies, such as fuel cells, electrolyzers, and flow-batteries. Covering topics from electrolyte solutions to electrochemical energy conversion systems and corrosion, this revised and expanded edition provides new educational material to help readers familiarize themselves with some of today's most useful electrochemical concepts. The Second Edition includes a new Appendix C with a detailed description of how the most common electrochemical laboratories can be organized, what data should be collected, and how the data should be treated and presented in a report. Video demonstrations for these laboratories are available on YouTube. In addition, the author has added conceptual and numerical exercises to all of the chapters to help with the understanding of the book material and to extend the important aspects of the electrochemical science and engineering. Finally, electrochemical impedance spectroscopy is now used in most electrochemical laboratories, and so a new section briefly describes this technique in Chapter 7.This new edition Ensures readers have a fundamental knowledge of the core concepts of electrochemical science and engineering, such as electrochemical cells, electrolytic conductivity, electrode potential, and current–potential relations related to a variety of electrochemical systems Develops the initial skills needed to understand an electrochemical experiment and successfully evaluate experimental data without visiting a laboratory Promotes an appreciation of the capabilities and applications of key electrochemical techniques Features eight lab descriptions and instructions that can be used to develop the labs by instructors for a university electrochemical engineering class Integrates eight online videos with lab demonstrations to advise instructors and students on how the labs can be carried out Features a solutions manual for adopting instructors The Second Edition is an ideal and unique text for undergraduate engineering and science students and readers in need of introductory-level content. Graduate students and engineers looking for a quick introduction to the subject will benefit from the simple structure of this book. Instructors interested in teaching the subject to undergraduate students can immediately use this book without reservation.

With interdisciplinary perspectives from internationally renowned experts, Noble-Metal-Free Electrocatalysts for Hydrogen Energy is one of the most authoritative references to focus solely on state-of-the-art knowledge of noble-metal-free electrocatalysts, as well as their nanostructures and unique properties. The chapters within contain cutting-edge breakthroughs, horizons, and insights into functional materials for energy applications.This book contains over 3000 references and 200 figures, and is a highly valuable resource for scientists, students, and engineers working in the fields of electrochemistry, catalysis, fuel cells, batteries, and supercapacitors.

This book focuses on novel electrochemical materials particularly designed for specific energy applications. It presents the relationship between materials properties, state-of-the-art processing, and device performance and sheds light on the research, development, and deployment (RD&D) trend of emerging materials and technologies in this field. Features: Emphasizes electrochemical materials applied in PEM fuel cells and water splitting Summarizes anode, cathode, electrolyte, and additive materials developed for lithium-ion batteries and reviews other batteries, including lithium-air, lithium-sulfur, sodium- and potassium-ion batteries, and multivalent-ion batteries Discusses advanced carbon materials for supercapacitors Highlights catalyst design and development for CO2RR and fundamentals of proton facilitated reduction reactions With a cross-disciplinary approach, this work will be of interest to scientists and engineers across chemical engineering, mechanical engineering, materials science, chemistry, physics, and other disciplines working to advance electrochemical energy conversion and storage capabilities and applications.

>Collagen-Derived Materials Comprehensive Resource for Current Ideas and Strategies for the Synthesis and Characterization of Advanced Collagen-Derived Materials This book presents and summarizes new synthetic strategies and multi-functional applications of collagen-derived materials in electrochemical energy storage and conversion. Through easily-comprehensible illustrations and images, the book presents basic knowledge for collagen-derived materials (including gelatin and collagen-derived carbons) and their typical synthesis and applications, thus enabling students and new researchers to obtain a thorough understanding of different materials and corresponding application areas. This book also serves as an important reference book for scientists and engineers in different research fields. It presents the up-to-date ideas and strategies for the synthesis and characterization of advanced collagen-derived materials, as well as multi-functional applications (especially in energy-related areas). Sample topics covered within the book include: Structural compositions, properties, and extraction of collagen and gelatin Precursors, structural compositions, and synthesis of collagen-derived carbons Applications of collagen-derived materials in electrochemical energy storage and conversion Applications of collagen-derived materials as electrode and supporting materials in the electrochemical energy storage and conversion systems, including capacitors, batteries, and electrocatalysts Challenges and opportunities for the design and synthesis of different collagen-derived materials For electrochemists, materials scientists, chemical engineers and students in related programs of study who are interested in the topic of collagen-derived materials, Collagen-Derived Materials: Synthesis and Applications in Electrochemical Energy Storage and Conversion serves as an important resource for gaining a holistic understanding of the field and learning about the state of the art based on promising energy-related applications.

Sustainable Energy, Towards a Zero-Carbon Economy Using Chemistry, Electrochemistry and Catalysis provides the reader with a clear outline of some of the strategies, particularly those based on various chemical approaches, that have been put forward with the aim of reducing greenhouse gas emissions in order to achieve'zero carbon'by 2050. The author describes the chemistry of some of the processes involved, paying particular attention to those that involve heterogeneous catalytic steps and electrolysis methods. In cases in which the technology is already established, details are given of the reactor systems used. He discusses novel developments in the areas of transport, the production of essential products using renewable energy and the uses of sustainable biomass. - Outlines international approaches to cutting or reducing greenhouse gas emissions - Describes current production and uses of energy - Outlines new approaches to energy supply and usage - Discusses the hydrogen economy and the uses of renewable energy - Outlines the importance of fuel-cell and electrolysis systems - Discusses biomass as a resource of energy and fuels

This book provides targeted support for students taking courses at the undergraduate level involving electrochemical methods and voltammetry, precision analytical techniques used in chemical engineering, chemical research and development, and pharmaceutical science. The learning method applied in this book, and the contents chosen, have been specifically tried-and-tested to support students preparing for exams, and for those having difficulty absorbing concepts and attaining an analytical understanding of their application. Through this book, “written for students by a student,” the author provides accessible learning resources that address students'needs when preparing for examinations.

Electrochemistry of Porous Materials describes essential theoretical aspects of the electrochemistry of nanostructured materials and primary applications, incorporating the advances in the field in the last ten years including recent theoretical formulations and the incorporation of novel materials. Concentrating on nanostructured micro- and mesoporous materials, the highly anticipated Second Edition offers a more focused and practical analysis of key porous materials considered relatively homogeneous from an electrochemical point of view. The author details the use of electrochemical methods in materials science for characterization and their applications in the fields of analysis, energy production and storage, environmental remediation, and the biomedical arena. Additional features include: Incorporates new theoretical advances in the voltammetry of porous materials and multiphase porous electrochemistry. Includes new developments in sensing, energy production and storage, degradation of pollutants, desalination and drug release. Describes redox processes for different porous materials, assessing their electrochemical applications. Written at an accessible and understandable level for researchers and graduate students working in the field of material chemistry. Selective and streamlined, Electrochemistry of Porous Materials, Second Edition culls a wide range of relevant and practically useful material from the extensive literature on the subject, making it an invaluable reference for readers of all levels of understanding.

Carbon dioxide reduction is a key research challenge in the global mission to reduce CO2 emissions. The process presents a unique challenge in that it can produce several different products, presenting the user with the challenge of selectively and efficiently producing on single useful material. This book presents an introduction to the field, covering the chemical reactions involved, the range of innovative materials and reactor designs most recently developed, and the future targets that need to be met.

High-k Materials in Multi-Gate FET Devices focuses on high-k materials for advanced FET devices. It discusses emerging challenges in the engineering and applications and considers issues with associated technologies. It covers the various way of utilizing high-k dielectrics in multi-gate FETs for enhancing their performance at the device as well as circuit level. Provides basic knowledge about FET devices Presents the motivation behind multi-gate FETs, including current and future trends in transistor technologies Discusses fabrication and characterization of high-k materials Contains a comprehensive analysis of the impact of high-k dielectrics utilized in the gate-oxide and the gate-sidewall spacers on the GIDL of emerging multi-gate FET architectures Offers detailed application of high-k materials for advanced FET devices Considers future research directions This book is of value to researchers in materials science, electronics engineering, semiconductor device modeling, IT, and related disciplines studying nanodevices such as FinFET and Tunnel FET and device-circuit codesign issues.

This new volume discusses new and well-known electrochemical energy harvesting, conversion, and storage techniques. It provides significant insight into the current progress being made in this field and suggests plausible solutions to the future energy crisis along with approaches to mitigate environmental degradation caused by energy generation, production, and storage. Topics in Electrochemical Energy Conversion and Storage Systems for Future Sustainability: Technological Advancements address photoelectrochemical catalysis by ZnO, hydrogen oxidation reaction for fuel cell application, and miniaturized energy storage devices in the form of micro-supercapacitors. The volume looks at the underlying mechanisms and acquired first-hand information on how to overcome some of the critical bottlenecks to achieve long-term and reliable energy solutions. The detailed synthesis processes that have been tried and tested over time through rigorous attempts of many researchers can help in selecting the most effective and economical ways to achieve maximum output and efficiency, without going through time-consuming and complex steps. The theoretical analyses and computational results corroborate the experimental findings for better and reliable energy solutions.

This book introduces the main aspects of modern applied electrochemistry. Starting with the basics of electrochemical kinetics, the authors address the chemistry and types of corrosion, principles of electro- and biocatalysis, electrodeposition and its applications in industrial processes. The book later discusses the electrochemistry and photoelectrochemistry of semiconductors and their applications in solar energy conversion and photocatalysis.

Electrochemical processes are long known but are becoming increasingly important again, due to modern applications, such as electro-mobility or energy storage. Thus, electrochemistry is not only a topic for chemists and physicists, but also for technical engineers. This book addresses all aspects of electrochemistry, which are important in these days: electrodes, corrosion, interphases, processes, energy storage, analytical methods, and sensors.

Written by two of the world's leading authorities in the field of electrochemistry, this book comprehensively addresses workhorse electrochemical reactions that serve as the basis of modern research for alternative energy solutions. Provides an accessible and readable summary on the use of electrochemical techniques and the applications of electrochemical concepts to functional molecular-level systems Includes a new chapter on proton coupled electron transfer, a completely revamped chapter on molecular catalysis of electrochemical reactions, and added sections throughout the book Bridges a gap and strengthens the relationship between electrochemists, molecular and biomolecular chemists—showing a variety of functions that may be obtained by multi-component systems designed using the paradigms of both chemistries

For Researchers, Students, Industrial Professionals, and ManufacturersElectrochemical Reduction of Carbon Dioxide: Fundamentals and Technologies is your guide to improved catalytic performance in the electrochemical reduction of carbon dioxide (CO2). Written by electrochemical energy scientists actively involved in environmental research and develo

Electrochemical Energy: Advanced Materials and Technologies covers the development of advanced materials and technologies for electrochemical energy conversion and storage. The book was created by participants of the International Conference on Electrochemical Materials and Technologies for Clean Sustainable Energy (ICES-2013) held in Guangzhou, China, and incorporates select papers presented at the conference.More than 300 attendees from across the globe participated in ICES-2013 and gave presentations in six major themes: Fuel cells and hydrogen energy Lithium batteries and advanced secondary batteries Green energy for a clean environment Photo-Electrocatalysis Supercapacitors Electrochemical clean energy applications and markets Comprised of eight sections, this book includes 25 chapters featuring highlights from the conference and covering every facet of synthesis, characterization, and performance evaluation of the advanced materials for electrochemical energy. It thoroughly describes electrochemical energy conversion and storage technologies such as batteries, fuel cells, supercapacitors, hydrogen generation, and their associated materials. The book contains a number of topics that include electrochemical processes, materials, components, assembly and manufacturing, and degradation mechanisms. It also addresses challenges related to cost and performance, provides varying perspectives, and emphasizes existing and emerging solutions.The result of a conference encouraging enhanced research collaboration among members of the electrochemical energy community, Electrochemical Energy: Advanced Materials and Technologies is dedicated to the development of advanced materials and technologies for electrochemical energy conversion and storage and details the technologies, current achievements, and future directions in the field.

Due to the increasing demand for power generation and the limited nature of fossil fuels, new initiatives for energy development based on electrochemical energy conversion systems are springing up around the world. Introduction to Electrochemical Science and Engineering describes the basic operational principles for a number of growing electrochemi

With contributions from leading researchers in their fields, this book provides an overview of the most important electrochemical power sources in development today. Focusing on materials, design, and performance, the text presents the most recent and innovative technologies employed in battery and fuel cell technologies. Topics include acid-alkaline batteries, microbial fuel cells, lithium batteries, lead acid batteries, ultracapacitors, vanadium flow batteries, and carbon dioxide electroreduction. The book discusses the advantages of these cells over conventional methodologies, and their future applications.

The use of regenerative energy in many primary forms leads to the necessity to store grid dimensions for maintaining continuous supply and enabling the replacement of fossil fuel systems. Chemical energy storage is one of the possibilities besides mechano-thermal and biological systems. This work starts with the more general aspects of chemical energy storage in the context of the geosphere and evolves to dealing with aspects of electrochemistry, catalysis, synthesis of catalysts, functional analysis of catalytic processes and with the interface between electrochemistry and heterogeneous catalysis. Top-notch experts provide a sound, practical, hands-on insight into the present status of energy conversion aimed primarily at the young emerging research front.

This new and important book gathers the latest research from around the globe in the study in the dynamic field of electrochemistry and highlights such topics as: electrochemical applications of modified electrodes in wastewater treatment, corrosion and protection of magnesium and its alloys as a biomaterial, electrochemical hydrogen storage, analysis of electrochemical reactor performance and others.

This book presents state-of-the-art information concerning properties and processes involved in glass melts. Based upon contributions by renowned authors and scientists working with glass melt systems, Properties of Glass-Forming Melts is an excellent compilation of the current knowledge on property data, mechanisms, measurement techniques, and str

This invaluable book focuses on the mechanisms of formation of a solid-electrolyte interphase (SEI) on the electrode surfaces of lithium-ion batteries. The SEI film is due to electrochemical reduction of species present in the electrolyte. It is widely recognized that the presence of the film plays an essential role in the battery performance, and its very nature can determine an extended (or shorter) life for the battery. In spite of the numerous related research efforts, details on the stability of the SEI composition and its influence on the battery capacity are still controversial. This book carefully analyzes and discusses the most recent findings and advances on this topic.

Based on the author's lecture notes for a course on Physical Chemistry of Oxides at High Temperatures held at the Graduate School of the Tokyo Institute of Technology, this book examines the micromechanism of migration of ions and electronic defects contained in solid and liquid oxides at high temperature.The book is primarily designed for use as a graduate-level text and includes 150 problems for students. The emphasis is on introduction of simple theories for transport properties of oxides, which can be universally used at low and high temperatures, for various combinations of oxides.

The first book of its kind, Environmental Electrochemistry considers the role that electrochemical science and engineering can play in environmental remediation, pollution targeting, and pollutant recycling. Electrochemical-based sensors and abatement technologies for the detection, quantification, and treatment of environmental pollutants are described. Each chapter includes an extensive listing of supplemental readings, with illustrations throughout the bookto clarify principles and approaches detailed in the text. - The first book to review electro- and photoelectrochemical technologies for environmental remediation, pollution sensors and pollutant recycling - Applicable to a broad audience of environmental scientists and practicing electrochemists - Includes both laboratory concepts and practical applications

Physiology and Electrochemistry of Nerve Fibers explores the properties of nerve fibers, including morphology, biochemistry, and physical chemistry. The book also makes an effort to trace the origins of the concepts that are important in studying the physiology of the nerve fibers. The text covers the early studies of electrochemistry; the different theories regarding nerve excitation; the conduction of nerve impulses along different nerve fibers; and the behavior of impulses in myelinated nerve fibers and its electrical excitation. The book also discusses the emergence, morphology, and biochemistry of the squid giant axon, as well as further studies about it; macromolecular transitions; the physiochemical approach and model; and the electrochemical considerations of the classical membrane theory. The monograph is intended for doctors specializing in neurology, psychologists, and psychiatrists who wish to know more about nerve fibers, their structure, chemical properties, functions, and the theories behind it, as well as its transmission of electrical impulses.

Electrochemistry of Biological Molecules presents a fairly complete summary of the electrochemistry of the more important groups of nitrogen heterocyclic molecules including purines and pyrimidines and their nucleosides and nucleotides, polynucleotides and nucleic acids, pteridines, flavins, pyrroles, porphyrins, and pyridines. Topics covered range from the theory and instrumentation of electrochemistry to various biological molecules, including pteridines, isoalloxazines, flavins, and flavin nucleotides. Comprised of nine chapters, this book begins with an overview of electrochemical techniques and their use to study biological materials, followed by a discussion on the theory and instrumentation of electrochemistry, with emphasis on their significance and utility as well aa their principles and circuits. Subsequent chapters explore nitrogen heterocyclic molecules such as purines and pyrimidines and their nucleosides and nucleotides, polynucleotides and nucleic acids, pteridines, flavins, pyrroles, porphyrins, and pyridines. The electrochemistry of biologically important pyridines is considered. This monograph should be of value to electrochemists, biochemists, and biologists.