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Intermetallic compounds are in the focus of solid-state research for a wide range of future applications, e.g. in heterogeneous catalysis, for thermoelectric generators, and basic research of quantum critical effects. A comprehensive overview is given on various crystal growth techniques that are particularly adopted to intermetallic phases. Experienced authors from leading institutes give detailed descriptions of the specific problems in crystal growth of intermetallic compounds and approaches to solve them.

The book consists of two parts: Part 1 is a standard text of dislocation theory. Mathematics is avoided as much as possible. Part 2 describes application of dislocation theory, which includes mechanical properties (including the inverse temperature dependence of strength) and dislocations in functional materials such as Si, GaN and SiC and dislocations in a thin crystal such as an epitaxial layer. This is what has been long anticipated among researchers in industry.The book contains about 330 illustrations (mostly originals by the author) and the pictures obtained by the author by means of in-situ experiment in a transmission electron microscope over the past 50 years.This book includes many exercises, which the author found useful when he was teaching in Department of Materials Science and Engineering of Nagoya University to stimulate their interests in dislocation theory.

With the highly competitive development of pharmaceutical and chemical industries, mastering crystal growth is becoming increasingly important. Modern industrial manufacturers place high importance on the ability to grow novel crystals with a specific habit and improve the performance of existed crystals using tailored operating conditions. Therefore, the ability to synthesize a particular morphology and to predict the crystal morphology of new compounds is becoming even more desirable. The recent development of crystal growth is vital for researchers in crystallography and crystallization to respond and realize this objective. With this need in mind, this book mainly targeted at introducing crystal growth from three aspects ranging from basic concepts and detailed mechanisms to advanced applications in hot areas of materials science. This book introduces various experimental and theoretical methods to grow different crystals, which includes the techniques to grow single crystals, CaCO3 polymorphs, metal-organic crystals, liquid crystals, fenamate crystals, cocrystals, and the theoretical models to predict the crystal morphologies within a different environment. From these carefully selected contents, readers will not only learn of the basic theory and experimental techniques implemented, but also keep abreast with both state-of-the-art crystal growth and its overlap with other subjects.

This monograph is devoted to the growth of crystals using optical furnaces. Optical furnaces can be understood and designed making recurrence to concepts that stem from analytical geometry.

This book introduces the principles and techniques of crystal growth by the flux method, which is arguably the most useful way to obtain millimeter- to centimeter-sized single crystals for physical research. As it is possible to find an appropriate solvent (“flux”) for nearly all inorganic materials, the flux method can be applied to the growth of many crystals ranging from transition metal oxides to intermetallic compounds. Both important principles and experimental procedures are described in a clear and accessible manner. Practical advice on various aspects of the experiment, which is not readily available in the literature, will assist the beginning graduate students in setting up the lab and conducting successful crystal growth. The mechanisms of crystal growth at an elementary level are also provided to better understand the techniques and to help in assessing the quality of the crystals. The book also contains many photographs of beautiful crystals with important physical properties of current interest, such as high-temperature superconductors, strongly correlated electronic systems, topological insulators, relaxor ferroelectrics, low-dimensional quantum magnets, non-linear optical materials, and multiferroics.

In this volume, contributions covering the theoretical and practical aspects of multicomponent crystals provide a timely and contemporary overview of the state-of-the art of this vital aspect of crystal engineering/materials science. With a solid foundation in fundamentals, multi-component crystals can be formed, for example, to enhance pharmaceutical properties of drugs, for the specific control of optical responses to external stimuli and to assemble molecules to allow chemical reactions that are generally intractable following conventional methods. ContentsPharmaceutical co-crystals: crystal engineering and applicationsPharmaceutical multi-component crystals: improving the efficacy of anti-tuberculous agentsQualitative and quantitative crystal engineering of multi-functional co-crystalsControl of photochromism in N-salicylideneaniline by crystal engineeringQuinoline derivatives for multi-component crystals: principles and applicationsN-oxides in multi-component crystals and in bottom-up synthesis and applicationsMulti-component crystals and non-ambient conditionsCo-crystals for solid-state reactivity and thermal expansionSolution co-crystallisation and its applicationsThe salt-co-crystal continuum in halogen-bonded systemsLarge horizontal displacements of benzene-benzene stacking interactions in co-crystalsSimultaneous halogen and hydrogen bonding to carbonyl and thiocarbonylfunctionalityCrystal chemistry of the isomeric N,N'-bis(pyridin-n-ylmethyl)-ethanediamides, n = 2, 3 or 4Solute・solvent interactions mediated by main group element (lone-pair)・・・π(aryl) interactions

'The book is well organized and is pedagogical. By discussing crystallization in pure systems, the author introduces and describes the important concepts, physical parameters and theoretical models pertaining to nucleation and growth of crystals … If you are a young investigator or a graduate student whose research involves understanding the fundamentals of crystallization including nucleation and growth, this book will be a treat for you. Readers who have a strong background in physical chemistry or thermal physics may find the book easy to read. Nevertheless, this book should be a good reference to have on the bookshelf if you are an experienced researcher whose interest crosses the path with the general topics of crystal growth.'Acta Crystallographica Section BThe processes of new phase formation and growth are of fundamental importance in numerous rapidly developing scientific fields such as modern materials science, micro- and optoelectronics, and environmental science. Crystal Growth for Beginners combines the depth of information in monographs, with the thorough analysis of review papers, and presents the resulting content at a level understandable by beginners in science. The book covers, in practice, all fundamental questions and aspects of nucleation, crystal growth, and epitaxy.This book is a non-eclectic presentation of this interdisciplinary topic in materials science. The third edition brings existing chapters up to date, and includes new chapters on the growth of nanowires by the vapor-liquid-solid mechanism, as well as illustrated short biographical texts about the scientists who introduced the basic ideas and concepts into the fields of nucleation, crystal growth and epitaxy. All formulae and equations are illustrated by examples that are of technological importance. The book presents not only the fundamentals but also the state of the art in the subject.Crystal Growth for Beginners is a valuable reference for both graduate students and researchers in materials science. The reader is required to possess some basic knowledge of mathematics, physics and thermodynamics.

Hydrothermal crystal growth offers a complementary alternative to many of the classical techniques of crystal growth used to synthesize new materials and grow bulk crystals for specific applications. This specialized technique is often capable of growing crystals at temperatures well below their melting points and thus potentially offers routes to new phases or the growth of bulk crystals with less thermal strain. Borate crystals are widely used as nonlinear optical, laser and luminescent materials due to their diversified structures, and good chemical and physical properties. The growth of high-quality borate crystals is required for their applications. A fundamental problem for borate crystal growth is the high-temperature melt structures in the crystal growth systems. This book discusses several crystals and the crystal growth processes.

This collection conta ins the results of a number of investiga­ tions which have been carried out in the Hydrothermal Synthesis Laboratory of the Institute of Crystallography, Academy of Sciences of the USSR; it constitutes a continuation of an earlier collection which appeared in 1968: Hydrothermal Synthesis of Crystals. Problems associated with the synthesis of oxides, simple and complex sulfides, carbonates, silicates, and germanates are consid­ ered, and a great deal of factual material relating to the growth of single crystals of some of these compounds on a seed is presented. Some of the articles pay special attention to the kinetic asp­ ect of the growth of crystals; the conditions of growth are relat­ ed to the morphological characteristics of the growing faces, and the relationship between the habit of the crystals and the oomposi­ tion and constitution of the solutions is considered. A fair number of articles are concerned with the crystalliza­ tion of new compounds, most of which have now been synthesized under hydrothermal conditions for the very first time; these in­ clude ternary chalcohalides of composition AVBvIVVII. zirconates, lithium silicates, and germanates. The collection also contains a description of the apparatus used for precision measurements at high temperatures and pres­ sures. We hope that this publication will present a better idea of the special characteristics of the hydrothermal method of synthes­ izing and.growing crystals, and will prove useful to all those in­ terested in this field of knowledge.

Crystal growth and nucleation are treated in the specialized literature in different ways depending on the discipline in question (physics, physical chemistry, chemical engineering) and on the theoretical approaches (atomistic vs continuum approach as regards crystal growth, phase vs chemical concept as regards nucleation). This book relates the different approaches to one another, giving preference to atomistic treatments by the methods of statistical thermodynamics and chemical kinetics. This unified approach also facilitates an understanding of some related phenomena of surface physics, such as adsorption, wetting etc. The book allows research novices and graduate students to get an insight into the physics of the phenomena and to interpret some of the experimental results.

Crystal engineers aim to control the way molecules aggregate in the crystalline phase and are therefore concerned with crystal structure prediction, polymorphism, and discovering the relative importance of different types of intermolecular forces and their influence on molecular structure. In order to design crystal structures, knowledge of the types, strengths, and nature of possible intermolecular interactions is essential. Non-covalent interactions involving p-systems is a theme that is under extensive investigation as these interactions can be inductors for the assembly of a vast array of supramolecular architectures. The Importance of Pi-Interactions in Crystal Engineeringcovers topics ranging from the identification of interactions involving p-systems, their impact on molecular and crystal structure in both organic and metallorganic systems, and how these interactions might be exploited in the design of new materials. Specialist reviews are written by internationally recognized researchers drawn from both academia and industry. The Importance of Pi-Interactions in Crystal Engineeringprovides an essential overview of this important aspect of crystal engineering for both entrants to the field as well as established practitioners, and for those working in crystallography, medicinal and pharmaceutical sciences, solid-state chemistry, physical chemistry, materials and nanotechnology

In this book, the authors present topical research from across the globe in the study of the theory, mechanisms and morphology of crystal growth. Topics discussed include the theory of kinetic experiment at crystal growth from solutions in melts; self-assembly of epitaxial III-V-compound semiconductor quantum dots; supersaturation formation and measurement; the growth mechanisms of electrodeposited nanowires and the growth and morphology evolution of ZnO nanowires synthesized by chemical vapors.

This book presents the state of the art in nanoscale surface physics. It outlines contemporary trends in the field covering a wide range of topical areas: atomic structure of surfaces and interfaces, molecular films and polymer adsorption, biologically inspired nanophysics, surface design and pattern formation, and computer modeling of interfacial phenomena. Bridging'classical'and'nano'concepts, the present volume brings attention to the physical background of exotic condensed-matter properties. The book is devoted to Iwan Stranski and Rostislaw Kaischew, remarkable scientists, who played a crucial role in setting up the theoretical fundamentals of nucleation and crystal growth phenomena in the last century.

This book, a continuation of the series “Advances in Materials Research,” is intended to provide the general basis of the science and technology of crystal growth of silicon for solar cells. In the face of the destruction of the global environment,the degradationofworld-widenaturalresourcesandtheexha- tion of energy sources in the twenty-?rst century, we all have a sincere desire for a better/safer world in the future. In these days, we strongly believe that it is important for us to rapidly developanewenvironment-friendlycleanenergyconversionsystemusingsolar energyastheultimatenaturalenergysource. Forinstance,mostofournatural resources and energy sources will be exhausted within the next 100 years. Speci?cally, the consumption of oil, natural gas, and uranium is a serious problem. Solar energy is the only ultimate natural energy source. Although 30% of total solar energy is re?ected at the earth's surface, 70% of total solar energy can be available for us to utilize. The available solar energy amounts to severalthousand times larger than the world's energy consumption in 2000 of about 9,000 Mtoe (M ton oil equivalent). To manage 10% of the world's energy consumption at 2050 by solar energy, we must manufacture 40 GW solar cells per year continuously for 40 years. The required silicon feedstock is about 400,000 ton per year. We believe that this is an attainable target, since it can be realized by increasing the world production of silicon feedstock by 12times asmuchasthe presentproductionat2005.

This book deals with the important technological aspects of the growth of GaN single crystals by HVPE, MOCVD, ammonothermal and flux methods for the purpose of free-standing GaN wafer production. Leading experts from industry and academia report in a very comprehensive way on the current state-of-the-art of the growth technologies and optical and structural properties of the GaN crystals are compared.

Over the years, many successful attempts have been chapters in this part describe the well-known processes made to describe the art and science of crystal growth, such as Czochralski, Kyropoulos, Bridgman, and o- and many review articles, monographs, symposium v- ing zone, and focus speci cally on recent advances in umes, and handbooks have been published to present improving these methodologies such as application of comprehensive reviews of the advances made in this magnetic elds, orientation of the growth axis, intro- eld. These publications are testament to the grow- duction of a pedestal, and shaped growth. They also ing interest in both bulk and thin- lm crystals because cover a wide range of materials from silicon and III–V of their electronic, optical, mechanical, microstructural, compounds to oxides and uorides. and other properties, and their diverse scienti c and The third part, Part C of the book, focuses on - technological applications. Indeed, most modern ad- lution growth. The various aspects of hydrothermal vances in semiconductor and optical devices would growth are discussed in two chapters, while three other not have been possible without the development of chapters present an overview of the nonlinear and laser many elemental, binary, ternary, and other compound crystals, KTP and KDP. The knowledge on the effect of crystals of varying properties and large sizes. The gravity on solution growth is presented through a c- literature devoted to basic understanding of growth parison of growth on Earth versus in a microgravity mechanisms, defect formation, and growth processes environment.

'Polymineral-Metasomatic Crystallogenesis'is dedicated to the foundations of polymineral crystallogenesis in solutions typically occurring in nature. Effects, laws, and mechanisms of a metasomatic crystal replacement, joint crystal growth of different phases, mixed crystal formation, and aggregate re-crystallization as well as oriented overgrowth (epitaxy and quasi-epitaxy) and crystal habit origin are considered experimentally. The behaviour of these processes in nature are discussed in addition to pseudomorphs, poikilitic crystals (and other replacement forms), features of rapakivi structure, fluorite morphology, and many more. The concept is a generalization of the classic theory on crystallogenesis which is complicated by phase interaction in polymineral systems.'Polymineral-Metasomatic Crystallogenesis'is designed for chemists, geologists, physicists, and postgraduates and advanced undergraduate students of these fields.

This book is the first book dealing with structural crystallography of inorganic oxysalts in general. A special emphasis is placed upon structural topology and methods of its description. The latter include graph theory, nets, 2-D and 3-D tilings, polyhedra, etc. The structures considered range from minerals to organically templated oxysalts, for all of which this book provides a unified approach to structure interpretation and classification. Most of the structures have been analysed from the proposed viewpoint for the first time and it has been shown that they possess the same topological genealogy and relationships, sometimes despite their obvious chemical differences. In order to expand the range of oxysalts considered, the book offers not only traditional schemes but also alternative approaches such as anion topologis, anion-centered polyhedra and cation arrays. As such, this book can be considered as a comprehensive introduction into the amazingly complex and diverse world of inorganic oxysalts.

Single Crystal Growth of Semiconductors from Metallic Solutions covers the four principal growth techniques currently in use for the growth of semiconductor single crystals from metallic solutions. Providing an in-depth review of the state-of-the-art of each, both experimentally and by numerical simulations. The importance of a close interaction between the numerical and experimental aspects of the processes is also emphasized. Advances in the fields of electronics and opto-electronics are hampered by the limited number of substrate materials which can be readily produced by melt-growth techniques such as the Czochralski and Bridgman methods. This can be alleviated by the use of alternative growth techniques, and in particular, growth from metallic solutions. The principal techniques currently in use are: Liquid Phase Epitaxy; Liquid Phase Electroepitaxy; the Travelling Heater Method, and; Liquid Phase Diffusion. Single Crystal Growth of Semiconductors from Metallic Solutions will serve as a valuable reference tool for researchers, and graduate and senior undergraduate students in the field of crystal growth. It covers most of the models developed in recent years. The detailed development of basic and constitutive equations and the associated interface and boundary conditions given for each technique will be very valuable to researchers for the development of their new models.• Describes the fundamentals of crystal growth modelling• Providing a state-of-the art description of the mathematical and experimental growth processes • Allows reader to gain clear insight into the practical and mathematical aspects of the topic

How do crystals nucleate and grow? Why and how do crystals form such a wide variety of morphologies, from polyhedral to dendritic and spherulitic forms? These are questions that have been posed since the seventeenth century, and are still of vital importance today both for modern technology, and to understand the Earth's interior and the formation of minerals by living organisms. In this book, Ichiro Sunagawa sets out clearly the atomic processes behind crystal growth, and describes case studies of complex systems from diamond, calcite and pyrite, to crystals formed through biomineralization, such as the aragonite of shells, and apatite of teeth. Essential reading for advanced graduates and researchers in mineralogy and materials science.

Crystals are the unacknowledged pillars of modern technology. The modern technological developments depend greatly on the availability of suitable single crystals, whether it is for lasers, semiconductors, magnetic devices, optical devices, superconductors, telecommunication, etc. In spite of great technological advancements in the recent years, we are still in the early stage with respect to the growth of several important crystals such as diamond, silicon carbide, PZT, gallium nitride, and so on. Unless the science of growing these crystals is understood precisely, it is impossible to grow them as large single crystals to be applied in modern industry. This book deals with almost all the modern crystal growth techniques that have been adopted, including appropriate case studies. Since there has been no other book published to cover the subject after the Handbook of Crystal Growth, Eds. DTJ Hurle, published during 1993-1995, this book will fill the existing gap for its readers.The book begins with''Growth Histories of Mineral Crystals''by the most senior expert in this field, Professor Ichiro Sunagawa. The next chapter reviews recent developments in the theory of crystal growth, which is equally important before moving on to actual techniques. After the first two fundamental chapters, the book covers other topics like the recent progress in quartz growth, diamond growth, silicon carbide single crystals, PZT crystals, nonlinear optical crystals, solid state laser crystals, gemstones, high melting oxides like lithium niobates, hydroxyapatite, GaAs by molecular beam epitaxy, superconducting crystals, morphology control, and more. For the first time, the crystal growth modeling has been discussed in detail with reference to PZT and SiC crystals.

“Electrocrystallization is a particular case of a first order phase transition” and “Electrocrystallization is a particular case of electrochemical kinetics” are two statements that I have heard and read many times. I do not like them for a simple reason: it is annoying to see that the subject to which you have devoted more than 30 years of your life may be considered as a “particular case”. Therefore, I decided to write this book in which Electrocrystallization is the main subject. To become competent in the field of Electrocrystallization one should possess knowledge of Electrochemistry, Nucleation and Crystal Growth, which means knowledge of Physical Chemistry, Physics and Mathematics. That is certainly difficult and in most cases those who study Electrocrystallization are either more electrochemists, or more physical chemists, or more physicists, very often depending on whom has been their teacher. Of course, there are scientists who consider themselves equally good in all those fields. Very frequently they are, unfortunately, equally bad. The difference is essential but strange enough, it is sometimes not easy to realize the truth immediately.

This clearly illustrated explanation of the basic principles of crystals may be used as a text or supplementary sourcebook by high-school students (for which it was originally written), students at the junior college or undergraduate level, or the general reader with an interest in science.

Physicochemical Hydrodynamics: The Role of Convection and Fluid Flow in Solidification and Crystal Growth focuses on the processes, methodologies, reactions, and approaches involved in solidification and crystal growth brought about by convection and fluid flow. The selection first offers information on the techniques of crystal growth, convection in Czochralski growth melts, and Marangoni effects in crystal growth melts. Discussions focus on crystal growth under reduced gravity, Marangoni effects in growth from a crucible, thermocapillary convection in floating zones, near-field flow, Czochralski bulk flow, and melt, solution, and vapor growth. The text then examines the effect of convective flow on morphological stability and time-dependent natural convection in crystal growth systems. The manuscript elaborates on the effects of fluid flow on the solidification of industrial castings and ingots and application of holographic interferometry to hydrodynamic phenomena in crystal growth. Topics include effects of fluid flow on crystal structure, importance of macrosegregation defects in castings, value of convection in crystal growth, and occurrence of thermal oscillations in fluids. The selection is a dependable reference for readers interested in the role of convection and fluid flow in solidification and crystal growth.

Epitaxial Growth, Part A is a compilation of review articles that describe various aspects of the growth of single-crystal films on single-crystal substrates. The collection contains topics on the historical development of epitaxy, the nucleation of thin films, the structure of the interface between film and substrate, and the generation of defects during film growth. The text also provides descriptions of the methods used to prepare and examine thin films and a list of the overgrowth-substrate combinations studied. Mineralogists, materials engineers and scientists, and physicists will find this book a great source of insight.

By introducing the superspace formalism, the methods of structure analysis of incommensurate structures have achieved in the past few years a full maturity. The superspace description is also becoming in the field of quasicrystals the main tool to approach a systematic method of structure determination of these materials. According to the program of the Workshop, these proceedings are an introduction to the formalism and practice of structure determination of modulated structures (incommensurate and commensurate) and quasiperiodic systems, mainly under the unifying framework of the superspace description. Accordingly, a large set of tutorial introductory chapters written by well-known specialists are included. The main refinement programs available for incommensurate structures are presented by their authors. The book also contains the most recent contributions from more than thirty of the participants in the Workshop, focusing on the problem of the structure analysis of these typical materials by means of diffraction methods.

Volume I - Fundamentals addresses the underlying scientific principles relevant to all the techniques of crystal growth. Following a Foreword by Professor Sir Charles Frank and an historical introduction, the first part contains eight chapters devoted to thermodynamic, kinetic and crystallographic aspects including computer simulation by molecular dynamics and Monte Carlo methods. The second part, comprising a further seven chapters, is devoted to bulk transport effects and the influence of transport-limited growth on the stability of both isolated growth forms (such as the dendrite) and arrays, and on the cooperative effects which lead to pattern formation. All the presentations are superbly authoritative.

Written for physicists, chemists, and engineers specialising in crystal and film growth, semiconductor electronics, and various applications of thin films, this book reviews promising scientific and engineering trends in thin films and thin-films materials science. The first part discusses the physical characteristics of the processes occurring during the deposition and growth of films, the principal methods of obtaining semiconductor films and of reparing substrate surfaces on which crystalline films are grown, and the main applications of films. The second part contains data on epitaxial interfaces and on ways of reducing transition regions in films and film-type devices, on the processes of crystallization and recrystallization of amorphous films, and on thermodynamic conditions, mechanisms and kinetic parameters of accelerated crystallization.