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This research text presents the synthesis, characterisation, and advanced technological applications of novel nanocarbons, with a focus on graphane, graphyne, graphdiyne, graphene nanoribbon, onion like carbons and carbon nanotori. The book covers the various applications of novel nanocarbons, such as in solar cells and flexible electronics, provides updates on the effects of doping and electronic properties of electrode materials based on novel nanocarbons, and references further research and application-oriented innovations using these new carbon nanostructures. It also provides new updates on the effect of doping and structural twist on the electrochemical performance of electrode materials based on novel nanocarbons. This book will appeal to researchers and graduate students working with novel nanocarbon allotropes, including disciplines such as physics, chemistry, materials science, and chemical engineering. Key Features Presents the synthesis, characterisation, and advanced technological applications of novel nanocarbons Focuses on graphane, graphyne, graphdiyne, graphene nanoribbon, onion like carbons and carbon nanotori Covers the applications of novel nanocarbons in solar cells, flexible electronics, supercapacitor batteries and next-generation energy storage devices Includes cutting-edge research on new carbon nanomaterials (2D nanosystems) challenging graphene Covers the effect of doping and electronic properties of nanocarbons for quantum devices Discusses the commercialisation, shortcomings and future prospects of nanocarbons

Nanocarbon chemistry and physics is a fast-developing, broad research area – the Nobel prizes in 1996 and 2010 awarded to two key discoveries in the field, and several other nanocarbon achievements of comparable importance. Owing to this rapid growth, the nanocarbon landscape fundamentally changes every few years, creating a need to survey the field on a regular basis to update the books that have become incomplete or even obsolete. As such, this book focuses on fullerenes and metallofullerenes and also on the related areas of nanotubes and graphenes. All the covered research topics provide important fundamental knowledge for the natural sciences, but also for applications in molecular electronics, superconductivity, catalysis, photovoltaics and medical diagnostics. The current nanocarbon research activities have particularly high application potential in the conversion of solar energy, future molecular memories, non-conventional materials for optoelectronics,and new treatments for civilization diseases. Offering a truly up-to-date critical survey of nanocarbon science, its concepts and highlights, it follows the concept of a handbook: it addresses key topics systematically, from historical background, methodological aspects, current important issues, and application potential, all supplied with extensive referencing. With individual chapters written by leading experts with extensive research experience, it is a comprehensive reference resource for graduate students and active researchers alike.

This reference text provides fundamental knowledge of functional carbon materials ranging from fullerene, carbon dots, carbon fibers and nanofibers, carbon nanotubes, graphene, graphite, graphyne, diamonds, activated carbon and carbon aerogels. Each chapter. The book explores the properties and structure of each material, providing a discussion of the latest exciting developments in research, and acting as a comprehensive introduction to functional carbon materials. Current research and future challenges are discussed throughout, with a particular focus on the wide-ranging engineering applications of each material. The text also discusses the latest novel carbon types, including graphyne. The key audience for the book includes researchers working on functional carbon materials. It will be particularly valuable for early career researchers looking for an authoritative introduction to the field.Key Features:Provides fundamental knowledge of the wide variety of functional carbon materials, including structure, properties, current research status and future challengesIncludes the wide-ranging engineering applications of each materialCovers fullerene, carbon dots, carbon fibers and nanofibers, carbon nanotubes, graphene, graphite, graphyne, diamonds, activated carbon and carbon aerogelsDiscusses novel carbon types such as graphyneProvides an authoritative reference for researchers and those seeking a comprehensive introduction to the field

This two-volume sourcebook is the most comprehensive reference for carbon nanomaterials, bringing together the physics, chemistry, materials science, molecular biology and engineering of all carbon nanomaterial types that are important in electronics, energy, biomedical and environmental applications. Each chapter addresses the fundamental properties, growth mechanisms, processing and functionalization of a particular nanocarbon. The first volume covers graphene, fullerenes, nanotubes and nanodiamonds. The second volume focuses on nanoparticles, nanocapsules, nanofibers, nanoporous structures and nanocomposites.

This reference text presents a conceptual framework for understanding room-temperature electron and phonon transport through molecules and other quantum objects. The flow of electricity through molecules is explained at the boundary of physics and chemistry, providing an authoritative introduction to molecular electronics for physicists, and quantum transport for chemists. Professor Lambert provides a pedagogical account of the fundamental concepts needed to understand quantum transport and thermoelectricity in molecular-scale and nanoscale structures. The material provides researchers and advanced students with an understanding of how quantum transport relates to other areas of materials modelling, condensed matter and computational chemistry. After reading the book, the reader will be familiar with the basic concepts of molecular-orbital theory and scattering theory, which underpin current theories of quantum transport. Key FeaturesIntroduces molecular electronics for physicists, and quantum transport for chemists.Presents a conceptual framework for understanding room-temperature electron and phonon transport through molecules and other quantum objects.Provides a pedagogical account of quantum-interference-enhanced electrical and thermal properties of single molecules and self-assembled monolayers. Provides readers with an understanding of how quantum transport relates to other areas of materials modelling, condensed matter or computational chemistry. Discusses concepts needed to engineer the properties of molecules and create new functions. Includes MATLAB codes to allow the reader to expand the examples presented in the book.

21st Century Nanoscience - A Handbook: Low-Dimensional Materials and Morphologies (Volume 4) will be the most comprehensive, up-to-date large reference work for the field of nanoscience. Handbook of Nanophysics by the same editor published in the fall of 2010 and was embraced as the first comprehensive reference to consider both fundamental and applied aspects of nanophysics. This follow-up project has been conceived as a necessary expansion and full update that considers the significant advances made in the field since 2010. It goes well beyond the physics as warranted by recent developments in the field. This fourth volume in a ten-volume set covers low-dimensional materials and morphologies.Key Features: Provides the most comprehensive, up-to-date large reference work for the field. Chapters written by international experts in the field. Emphasises presentation and real results and applications. This handbook distinguishes itself from other works by its breadth of coverage, readability and timely topics. The intended readership is very broad, from students and instructors to engineers, physicists, chemists, biologists, biomedical researchers, industry professionals, governmental scientists, and others whose work is impacted by nanotechnology. It will be an indispensable resource in academic, government, and industry libraries worldwide. The fields impacted by nanophysics extend from materials science and engineering to biotechnology, biomedical engineering, medicine, electrical engineering, pharmaceutical science, computer technology, aerospace engineering, mechanical engineering, food science, and beyond.

This 21st Century Nanoscience Handbook will be the most comprehensive, up-to-date large reference work for the field of nanoscience. Handbook of Nanophysics, by the same editor, published in the fall of 2010, was embraced as the first comprehensive reference to consider both fundamental and applied aspects of nanophysics. This follow-up project has been conceived as a necessary expansion and full update that considers the significant advances made in the field since 2010. It goes well beyond the physics as warranted by recent developments in the field. Key Features: Provides the most comprehensive, up-to-date large reference work for the field. Chapters written by international experts in the field. Emphasises presentation and real results and applications. This handbook distinguishes itself from other works by its breadth of coverage, readability and timely topics. The intended readership is very broad, from students and instructors to engineers, physicists, chemists, biologists, biomedical researchers, industry professionals, governmental scientists, and others whose work is impacted by nanotechnology. It will be an indispensable resource in academic, government, and industry libraries worldwide. The fields impacted by nanoscience extend from materials science and engineering to biotechnology, biomedical engineering, medicine, electrical engineering, pharmaceutical science, computer technology, aerospace engineering, mechanical engineering, food science, and beyond.

Effects of many-body interactions and superconducting correlations have become central questions in the quantum transport community. While most previous works investigating current fluctuations in nanodevices have been restricted to the stationary regime, Seoane's thesis extends these studies to the time domain. It provides relevant information about the time onset of electronic correlations mediated by interactions and superconductivity. This knowledge is essential for the development of fast electronic devices, as well as novel applications requiring fast manipulations, such as quantum information processing. In addition, the thesis establishes contact with issues of broad current interest such as non-equilibrium quantum phase transitions.

The thesis tackles one of the most difficult problems of modern nanoscale science and technology - exploring what governs thermal phenomena at the nanoscale, how to measure the temperatures in devices just a few atoms across, and how to manage heat transport on these length scales. Nanoscale heat generated in microprocessor components of only a few tens of nanometres across cannot be effectively fed away, thus stalling the famous Moore's law of increasing computer speed, valid now for more than a decade. In this thesis, Jean Spièce develops a novel comprehensive experimental and analytical framework for high precision measurement of heat flows at the nanoscale using advanced scanning thermal microscopy (SThM) operating in ambient and vacuum environment, and reports the world's first operation of cryogenic SThM. He applies the methodology described in the thesis to novel carbon-nanotube-based effective heat conductors, uncovers new phenomena of thermal transport in two- dimensional (2D) materials such as graphene and boron nitride, thereby discovering an entirely new paradigm of thermoelectric cooling and energy production using geometrical modification of 2D materials.

On-surface synthesis is appearing as an extremely promising strategy to create organic nanoarchitectures with atomic precision. Molecular building blocks holding adequate functional groups are dosed onto surfaces that support or even drive their covalent linkage. The surface confinement and the frequent lack of solvents (most commonly being performed under vacuum conditions) create a completely new scenario fully complementary to conventional chemistry. In a pedagogical way and based on the most recent developments, this volume presents our current understanding in the field, addressing fundamental reaction mechanisms, synthetic strategies to influence the reactions according to our needs, as well as the ultimate growth and characterization of functional materials.Verging on chemistry, physics and materials science, the book is aimed at students and researchers interested in nanochemistry, surface science, supramolecular materials and molecular devices.Chapters'Mechanistic insights into surface-supported chemical reactions','Reactivity on and of Graphene Layers: Scanning Probe Microscopy Reviels'and'Bottom-up fabrication of atomically precise graphene nanoribbons'of this book are available open access under a CC BY 4.0 license at link.springer.com

This book discusses recent progress in endohedral fullerenes – their production and separation techniques, as well as their characterization and properties. Furthermore, the book delves into the all-important issue of stability by investigating electron transfer between the encapsulated metal species and the carbon cage. It also reviews spin-based phenomena caused by the shielding of endohedral spin by the fullerene, and analyzes formation of the spin states by charge transfer as studied by electron spin resonance. Tuning of charge states of endohedral species and of spin states of both the cage and the cluster are explained. Finally, the book considers the recent discovery of magnetism in some endohedral fullerenes, and the potential for quantum computing.

The Carbon Nanomaterials Sourcebook contains extensive, interdisciplinary coverage of carbon nanomaterials, encompassing the full scope of the field-from physics, chemistry, and materials science to molecular biology, engineering, and medicine-in two comprehensive volumes.Written in a tutorial style, this first volume of the sourcebook:Focuses on g

Endohedral fullerenes represent a novel family of carbon nanostructures, which are characterized by a robust fullerene cage with atoms, ions, or clusters trapped in its interior. Since the first separation of the endohedral metallofullerene La@C82 in 1991, a large variety of endohedral structures have been isolated and their endohedral nature has been proved by experimental studies. Within the past two decades, the world of endohedral fullerenes was significantly enlarged by the clusterfullerenes and the new carbon cages including non-IPR (IPR=isolated pentagon rule) structures. Resulting from the charge transfer from the encaged species to the fullerene cage, endohedral fullerenes hold a lot of fascinating properties inaccessible by the empty fullerenes, and consequently promise potential applications in biomedicine, molecular electronics and photonics etc.The book provides a comprehensive overview of endohedral fullerenes focused on the new advances in the past decade, including its fundamentals (structures), synthesis, isolation, characterization, properties, functionalization as well as the applications, thus representing the most updated and broad review of this exciting field.

Nanomaterials attract tremendous attention in recent researches. Although extensive research has been done in this field it still lacks a comprehensive reference work that presents data on properties of different Nanomaterials. This Handbook of Nanomaterials Properties will be the first single reference work that brings together the various properties with wide breadth and scope.

This book presents some of the latest achievements in nanotechnology and nanomaterials from leading researchers in Ukraine, Europe, and beyond. It features contributions from participants in the 2nd International Summer School “Nanotechnology: From Fundamental Research to Innovations” and International Research and Practice Conference “Nanotechnology and Nanomaterials”, NANO-2013, which were held in Bukovel, Ukraine on August 25-September 1, 2013. These events took place within the framework of the European Commission FP7 project Nanotwinning, and were organized jointly by the Institute of Physics of the National Academy of Sciences of Ukraine, University of Tartu (Estonia), University of Turin (Italy), and Pierre and Marie Curie University (France). Internationally recognized experts from a wide range of universities and research institutions share their knowledge and key results on topics ranging from nanooptics, nanoplasmonics, and interface studies to energy storage and biomedical applications.

Novel physical solutions, including new results in the field of adaptive methods and inventive approaches to inverse problems, original concepts based on high harmonic imaging algorithms, intriguing vibro-acoustic imaging and vibro-modulation technique, etc. were successfully introduced and verified in numerous studies of industrial materials and biomaterials in the last few years. Together with the above mentioned traditional academic and practical avenues in ultrasonic imaging research, intriguing scientific discussions have recently surfaced and will hopefully continue to bear fruits in the future. The goal of this book is to provide an overview of the recent advances in high-resolution ultrasonic imaging techniques and their applications to biomaterials evaluation and industrial materials. The result is a unique collection of papers presenting novel results and techniques that were developed by leading research groups worldwide. This book offers a number of new results from well-known authors who are engaged in aspects of the development of novel physical principles, new methods, or implementation of modern technological solutions into current imaging devices and new applications of high-resolution imaging systems. The ultimate purpose of this book is to encourage more research and development in the field to realize the great potential of high resolution acoustic imaging and its various industrial and biomedical applications.

As nanotechnology has developed over the last two decades, some nanostructures, such as nanotubes, nanowires, and nanoparticles, have become very popular. However, recent research has led to the discovery of other, less-common nanoforms, which often serve as building blocks for more complex structures.In an effort to organize the field, the Handbook of Less-Common Nanostructures presents an informal classification based mainly on the less-common nanostructures. A small nanotechnological encyclopedia, this book: Describes a range of little-known nanostructures Offers a unifying vision of the synthesis of nanostructures and the generalization of rare nanoforms Includes downloadable resources with color versions of more than 100 nanostructures Explores the fabrication of rare nanostructures, including modern physical, chemical, and biological synthesis techniques The Handbook of Less-Common Nanostructures discusses a classification system not directly related to the dimensionality and chemical composition of nanostructure-forming compounds or composite. Instead, it is based mainly on the less-common nanostructures. Possessing unusual shapes and high surface areas, these structures are potentially very useful for catalytic, medical, electronic, and many other applications.

Ultra-cold atomic ensembles have emerged in recent years as a powerful tool in many-body physics research, quantum information science and metrology. This thesis presents an experimental and theoretical study of the coherent properties of trapped atomic ensembles at high densities, which are essential to many of the aforementioned applications. The study focuses on how inter-particle interactions modify the ensemble coherence dynamics, and whether it is possible to extend the coherence time by means of external control. The thesis presents a theoretical model which explains the effect of elastic collision of the coherence dynamics and then reports on experiments which test this model successfully in the lab. Furthermore, the work includes the first implementation of dynamical decoupling with ultra-cold atomic ensembles. It is demonstrated experimentally that by using dynamical decoupling the coherence time can be extended 20-fold. This has a great potential to increase the usefulness of these ensembles for quantum computation.

The Mathematics and Topology of Fullerenes presents a comprehensive overview of scientific and technical innovations in theoretical and experimental studies. Topics included in this multi-author volume are: Clar structures for conjugated nanostructures; counting polynomials of fullerenes; topological indices of fullerenes; the wiener index of nanotubes; toroidal fullerenes and nanostars; C60 Structural relatives: a topological study; local combinatorial characterization of fullerenes; computation of selected topological indices of C60 and C80 Fullerenes via the Gap Program; 4valent- analogues of fullerenes; a detailed atlas of Kekule structures of C60. The Mathematics and Topology of Fullerenes is targeted at advanced graduates and researchers working in carbon materials, chemistry and physics.

Carbon nanotubes (CNTs), discovered in 1991, have been a subject of intensive research for a wide range of applications. These one-dimensional (1D) graphene sheets rolled into a tubular form have been the target of many researchers around the world. This book concentrates on the semiconductor physics of carbon nanotubes, it brings unique insight into the phenomena encountered in the electronic structure when operating with carbon nanotubes. This book also presents to reader useful information on the fabrication and applications of these outstanding materials. The main objective of this book is to give in-depth understanding of the physics and electronic structure of carbon nanotubes. Readers of this book should have a strong background on physical electronics and semiconductor device physics. This book first discusses fabrication techniques followed by an analysis on the physical properties of carbon nanotubes, including density of states and electronic structures. Ultimately, the book pursues a significant amount of work in the industry applications of carbon nanotubes.

Providing the framework for breakthroughs in nanotechnology, this landmark publication is the first comprehensive reference to cover both fundamental and applied physics at the nanoscale. After discussing the theoretical principles and measurements of nanoscale systems, the organization of the set follows the historical development of nanoscience. Each peer-reviewed chapter presents a didactic treatment of the physics underlying the nanoscale materials, applications, and detailed experimental results. State-of-the-art scientific content is enriched with fundamental equations and illustrations, many in color.

The aim of this book is to present a formulation of the non-equilibrium physics in nanoscale systems in terms of many-body states and operators and, in addition, discuss a diagrammatic approach to Green functions expressed by many-body states. The intention is not to give an account of strongly correlated systems as such. Thus, the focus of this book ensues from the typical questions that arise when addressing nanoscale systems from a practical point of view, e.g. current-voltage asymmetries, negative differential conductance, spin-dependent tunneling. The focus is on nanoscale systems constituted of complexes of subsystems interacting with one another, under non-equilibrium conditions, in which the local properties of the subsystems are preferably being described in terms of its (many-body) eigenstates.

The scanning probe microscopy?eld has been rapidly expanding. It is a demanding task to collect a timely overview of this?eld with an emphasis on technical dev- opments and industrial applications. It became evident while editing Vols. I–IV that a large number of technical and applicational aspects are present and rapidly - veloping worldwide. Considering the success of Vols. I–IV and the fact that further colleagues from leading laboratories were ready to contribute their latest achie- ments, we decided to expand the series with articles touching?elds not covered in the previous volumes. The response and support of our colleagues were excellent, making it possible to edit another three volumes of the series. In contrast to to- cal conference proceedings, the applied scanning probe methods intend to give an overview of recent developments as a compendium for both practical applications and recent basic research results, and novel technical developments with respect to instrumentation and probes. The present volumes cover three main areas: novel probes and techniques (Vol. V), charactarization (Vol. VI), and biomimetics and industrial applications (Vol. VII). Volume V includes an overview of probe and sensor technologies including integrated cantilever concepts, electrostatic microscanners, low-noise methods and improved dynamic force microscopy techniques, high-resonance dynamic force - croscopy and the torsional resonance method, modelling of tip cantilever systems, scanning probe methods, approaches for elasticity and adhesion measurements on the nanometer scale as well as optical applications of scanning probe techniques based on near?eld Raman spectroscopy and imaging.

The Nobel Prize of 1986 on Sc- ning Tunneling Microscopy sig- led a new era in imaging. The sc- ning probes emerged as a new i- trument for imaging with a pre- sion suf?cient to delineate single atoms. At?rst there were two – the Scanning Tunneling Microscope, or STM, and the Atomic Force Mic- scope, or AFM. The STM relies on electrons tunneling between tip and sample whereas the AFM depends on the force acting on the tip when it was placed near the sample. These were quickly followed by the - gneticForceMicroscope,MFM,and the Electrostatic Force Microscope, EFM. The MFM will image a single magnetic bit with features as small as 10nm. With the EFM one can monitor the charge of a single electron. Prof. Paul Hansma at Santa Barbara opened the door even wider when he was able to image biological objects in aqueous environments. At this point the sluice gates were opened and a multitude of different instruments appeared. There are signi?cant differences between the Scanning Probe Microscopes or SPM, and others such as the Scanning Electron Microscope or SEM. The probe microscopes do not require preparation of the sample and they operate in ambient atmosphere, whereas, the SEM must operate in a vacuum environment and the sample must be cross-sectioned to expose the proper surface. However, the SEM can record 3D image and movies, features that are not available with the scanning probes.