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The purpose of this easy-to-use handbook is to provide a quick, accessible reference to nucleobase complexes. It describes these complexes with reference to methods of preparation, their characterization, and their toxicity and therapeutic indices. It lists the modes of coordination together with the relevant spectral data and major methods of investigation. This concise resource guide also includes data on the uncomplexed bases, such as solubility, pk, accepted structures in the solid state and solutions, and the natural occurrence of the base. Investigators in the fields of transition metal chemistry, biological inorganic chemistry and those working in medical laboratories will find this handbook indispensable.

This book presents the recent research on sulfur-containing heterocyclic scaffolds that are crucial for biological processes. The numerous synthetic techniques utilized for the design and synthesis of different sized S-heterocycles, particularly biologically active frameworks with their pharmacological significance, are discussed in this book. This book is a useful reference for students, researchers and professionals working in the chemical and pharmaceutical industries.

Metal Organic Frameworks: Fundamentals to Advanced offers a substantial and complete treatment of published results. The book includes a summary of current research, along with an in- depth explanation of Metal organic frameworks (MOFs) and applications in this versatile area. Metal organic frameworks (MOFs) are structured frameworks made up of metal ions and organic molecules. These materials are similar to sponges and can absorb, retain and remove molecules from their pores. As a result, metal-organic frameworks (MOFs) are the most rapidly evolving substances in chemistry with the highest surface areas due to their well-ordered pore structure.The exciting and vast surface area allows for more chemical reactions and molecule adsorption, hence this new resource provides the newest updates on the topics covered.Covers the synthetic advantages and versatile applications of metal-organic frameworks (MOFs) due to their organic-inorganic hybrid nature and unique porous structureIncludes energy applications such as batteries, fuel storage, fuel cells, hydrogen evaluation reactions and super capacitorsFeatures information on using MOFs as a replacement to conventional engineering materials as they are lightweight, less costly, environmentally-friendly and sustainable

Volume 2 of the Handbook of Colorant Chemistry focuses on paints, painting and drawing systems used by the painter and craftsman. It describes in detail structure of oil, watercolor, acrylic and ceramic paints, inks, toners, and other drawing systems. From presenting molecular compositions of common paints and inks to a historical look at color chemistry, the author offers an in-depth look at the world of color. The complementary “Volume 1: Dyes and Pigments Fundamentals” (ISBN 978-3-11-077699-7) focuses on paints, painting and drawing systems used by the painter and craftsman. The book is supplemented by a comprehensive bibliography with references to standard works, monographs, and original papers. The reader is provided with a unique overview of the fi eld of color chemistry.

Transition-Metal-Catalyzed C-H Functionalization of Heterocycles A comprehensive guide to recent advances in this field Constituting the majority of all known compounds, heterocycles are structures that incorporate one or more heteroatoms within their core, thus exhibiting properties that are quite different from their all-carbon analogs. They are fundamental to all fields of chemistry and, therefore, their synthesis and modification has attracted a great deal of attention in the recent years. In this vein, transition-metal-catalyzed C-H bond functionalization forms a crucial tool for generating and analyzing heterocyclic compounds. Transition-Metal-Catalyzed C-H Functionalization of Heterocycles, Two-Volume Set, showcases diverse C-H functionalization methodologies and their incorporation into the latest research. The chapters serve as an essential tool depicting detailed site-selective functionalization of heterocyclic cores, along with a comprehensive discussion on their mechanistic approaches. Readers of Transition-Metal-Catalyzed C-H Functionalization of Heterocycles, Two-Volume-Set will also find: A detailed introduction to C-H activation along with the mechanistic aspects of transition-metal-catalyzed C-H bond activation reactions Easy-to-use structures with each chapter dedicated to a type of heterocycle and its specific functionalization methodologies A leading team of international authors in C-H bond functionalization Transition-Metal-Catalyzed C-H Functionalization of Heterocycles, Two-Volume-Set is a valuable guide for students and researchers in organic synthesis and process development, in both academic and industrial contexts.

Volume 25, entitled Modern Avenues in Metal-Nucleic Acid Chemistry, of the series Metal Ions in Life Sciences (MILS), provides a timely overview of selected relevant developments in a field which previously had a pronounced focus on fundamental chemistry aspects such as coordination principles, structural chemistry, and consequences for biological processes and disease-related medicinal issues. More recently, also as a consequence of the advent of supramolecular chemistry, advancements in nanochemistry, and new bio-analytical methods, novel aspects of this field have emerged. MILS-25 gives a state-of-the-art account on the present state of research in this field, addressing, among others, porous materials, non-covalent interactions, stimuli-responsive bioconjugates, DNA-templated metal arrays and nanoclusters, genotyping, guanine quadruplexes, and riboswitches. It consists of 15 comprehensive chapters with over 1600 citations, 160 figures (90 of them in color), with key contributions from 40 international experts from Europe, Asia, and America. It is an essential resource for scientists from numerous disciplines, ranging from materials science to biochemistry, by way of classical chemistry and physics. It offers an update on nucleic acid – metal complex bioconjugates and their applications It provides an insight into coordination polymers involving nucleic acid components It covers a wide range of nucleic acids, from DNA duplexes, triplexes and quadruplexes to RNA

Advances in Organometallic Chemistry, Volume 80, the latest release in this longstanding serial, is known for its comprehensive coverage of topics in organometallic synthesis, reactions, mechanisms, homogeneous catalysis, and more. It is ideal for a wide range of researchers involved in organometallic chemistry, with this updated release including chapters on Organometallic-like reactivity of group 10 metal-heteroatom sigma bonds, Organometallic interactions between metal nanoparticles and carbon-based molecules: a surface reactivity rationale, Group VI Allenylidene Complexes, and more.Contains contributions from leading authorities in the field of organometallic chemistryCovers topics in organometallic synthesis, reactions, mechanisms, homogeneous catalysis, and moreInforms and updates readers on the latest developments in the fieldCarefully edited to provide easy-to-read material

Organozinc reagents are less reactive than Grignard reagents but they　are much more chemoselective. Since the　Negishi cross-coupling reaction developed by Ei-ichi Negishi, who was awarded the Nobel Price in chemistry in 2010, a number of cross-coupling reactions involving organozinc derivatives and transition metal catalysts (Pd, Ni, Fe, Co, Cu, …) has been tuned up to form C-C bonds. This book on'Organozinc derivatives and transition metal catalysts'has been　written by experts in the field and is a complement to the book entitled'Grignard reagents and transition metal catalysts'(a De Gruyter book, edited by J. Cossy). Grignard reagents or organozinc reagents, that is the question? From a given substrate, what is the best organometallic　reagent and the best transition metal to form a C-C bond by using a cross-coupling reaction? The solution might be found in these two books.

Lanthanides: Fundamentals and Applications provides the fundamentals, new research, promising applications and future outlooks of lanthanide compounds and lanthanide-based materials. The book begins with an introduction, including key concepts, oxidation states and sources, extraction and separation of the lanthanides, followed by spectroscopic and magnetic properties, and metals, crystals and compounds. Organometallic compounds, coordination compounds, molecular magnetic materials and luminescent materials are covered before a discussion of specific lanthanide applications. Spintronics, bioimaging, photoelectric materials, catalysis and nuclear applications are discussed. This comprehensive resource is ideal for researchers and students studying inorganic and materials chemistry, in both academia and industry. Includes comprehensive and in-depth coverage of lanthanides Features the most current research progress on lanthanides Covers a combination view of fundamental research and specific applications of the lanthanides, including spintronics, bioimaging and additives for photoelectric materials

Comprehensive Inorganic Chemistry III, a ten-volume reference work, is intended to cover fundamental principles, recent discoveries, and significant applications of elements and their compounds. Authored by renowned experts in the field and edited by a world-class editorial board, each chapter provides a thorough and in-depth overview of the topic covered, featuring resources which will be useful to students, researchers, faculty as well as those in the industry. Comprehensive Inorganic Chemistry III focuses on main group chemistry, biological inorganic chemistry, solid state and materials chemistry, catalysis, and new developments in electrochemistry and photochemistry, as well as NMR and diffraction methods for studying inorganic compounds. The work expands on our 2013 work Comprehensive Inorganic Chemistry II while also adding new volumes on cutting-edge research areas and techniques for studying inorganic compounds. Researchers seeking background information on a specific problem involving the synthesis of inorganic compounds, as well as applications for numerous elements from the periodic table, and their compounds, will be able to rely on and refer to this authoritative scientific resource time and again. This new work complements Comprehensive Coordination Chemistry III (2021) and Comprehensive Organometallic Chemistry IV (2022), constituting a formidable trio of reference resources covering the whole of modern inorganic chemistry. Presents a comprehensive review of fundamental principles, recent discoveries and important applications of elements and their compounds, offering readers a ‘one-stop', comprehensive resource for access to a wealth of information to fully support their research and activities in this area Provides an excellent overview of the field that is an ideal resource for researchers and professionals Includes interdisciplinary chapters written by experts from around the world in the fields of chemistry, crystallography, materials science, optics, physics, and biochemistry

This book provides the reader with a comprehensive introduction to the topic of organometallic chemistry. With an easy to follow structure covering both nontransition metals and transition metals as well as the applications of organometallic reagents in organic synthesis, this book is a must-have for the organometallic chemist.

Tellurium, a well-known chalcogen, finds potential applications in various fields from chemistry to other branches of science such as nanotechnology and macromolecular science. However, its safety must also be taken into consideration when exploring its industrial applications. This book explores the breadth of tellurium‘s applications, outlines strategies for industrial use, and describes the safety concerns of this element.

Carbon-carbon and carbon-heteroatom bond-forming reactions are the backbone of synthetic organic chemistry. Scientists are constantly developing and improving these techniques in order to maximize the diversity of synthetically available molecules. These techniques must be developed in a sustainable manner in order to limit their environmental impact. This book highlights green carbon-carbon and carbon-heteroatom bond forming reactions.

Essential reference for researchers and experts in industry highlighting the rapidly growing field of hydroxyapatite-based catalysts and their application in various chemical processes. Hydroxyapatite (Ca10(PO4)6(OH)2) is the main mineral component of human and animal bones. It is largely applied in the field of biomaterials due to its biocompatibility. Recently, hydroxyapatite-based materials have especially gained a lot of attention by researchers in catalysis, as they are versatile and have shown precious properties of a good catalyst and catalyst support such as excellent ion-exchange capacity, high porosity, very low water solubility, controlled basicity/acidity, and good thermal stability at high temperatures. Design and Applications of Hydroxyapatite-Based Catalysts gives a detailed overview of the synthesis, characterization, and use of hydroxyapatite-based materials in catalysis. It covers synthetic hydroxyapatites (from pure chemicals or waste), natural apatites and materials from eggshells and animal bones. The application of hydroxyapatite-based catalysts in selective oxidation, deoxygenation, selective hydrogenation, dehydrogenation reactions, organic synthesis, as well as reforming processes and production of energy carriers is reviewed. Moreover, electrocatalysis and photocatalysis using hydroxyapatite-based materials are discussed. Kinetic and mechanism studies of various chemical pro-cesses over hydroxyapatite-based catalysts are also presented. This is the first book solely dedicated to hydroxyapatite-based materials and their use in catalysis. Covers synthesis and characterization, surface and structure studies, kinetic and mechanism aspects, and various applications in heterogeneous catalysis, electrocatalysis, and photocatalysis. Aimed at further stimulating research in the field Design and Applications of Hydroxyapatite-Based Catalysts is an indispensable source-of-information for researchers in academia and industry working in catalysis.

Volume 1 From Antraquinonoid Pigments to Color Fundamentals With contributions on various industrially important dyes, inorganic and organic pigments, on color fundamentals and colorants in various application systems (building materials, coatings, cosmetics, plastics, printing inks) A comprehensive overview on all important dyes, inorganic and organic pigments supplemented by information on all relevant applications and color fundamentals The chapters are clearly structured and arranged in alphabetical order in the 3-volumes.

Comprehensive Organometallic Chemistry, Fifteen Volume Set is the market-leading resource covering all areas of this critical sub-discipline of chemistry. Divided into 15 clear sections, it provides expert coverage of the synthesis, structures, bonding and reactivity of all organometallic compounds, including the mechanisms of the reactions. Applications of organometallic chemistry, such as the role of these compounds as reagents and catalysts for organometallic transformations, and their participation in bioorganometallic chemistry, is then covered. This is a vibrant area, as illustrated by the fact that the 2001, 2005 and 2010 Nobel prizes in Chemistry are all concerned with organometallic chemistry. This new edition will therefore again provide an invaluable and efficient learning resource for all researchers and educators looking for up-to-date analysis of a particular aspect of organometallic chemistry. Comprehensive – CHEC IV will offer a comprehensive review of current heterocycles research and critical insight into the future direction of the field with an emphasis on useful and reliable synthesis and reactions, negating the need for individual searches in the primary literature and across various databases Reputation – The 4th edition will match the impressive reputation of the previous editions as the go-to foundational reference in heterocyclic chemistry Clearly structured - Meticulously organized, articles are split into 15 sections on key topics and clearly cross-referenced to allow students, researchers and professionals to find relevant information quickly and easily Interdisciplinary - chapters written by academics and practitioners from various fields and regions will ensure that the knowledge within is easily understood by and applicable to a large audience

The second edition of Metal Ions in Biochemistry deals with the multidisciplinary subject of bio-inorganic chemistry, encompassing the disciplines of inorganic chemistry, biochemistry and medicine.The book deals with the role of metal ions in biochemistry, emphasising that biochemistry is mainly the chemistry of metal-biochemical complexes. Hence, the book starts with the structures of biochemicals and the identification of their metal binding sites. Thermodynamic and kinetic properties of the complexes are explained from the point of view of the nature of metal-ligand bonds. Various catalytic and structural roles of metal ions in biochemicals are discussed in detail.Features The role of Na+ and K+ in brain chemistry. The role of zinc insulin in glucose metabolism and its enhancement by vanadium and chromium compounds. Discussion of the role of zinc signals, zinc fingers and cascade effect in biochemistry. Haemoglobin synthesis and the role of vitamin B12 in it. The role of lanthanides in biochemical systems. A detailed discussion of the role of non-metals in biochemistry, a topic missing in most of the books on bio-inorganic chemistry. The study of bio-inorganic chemistry makes biochemists rethink the mechanistic pathways of biochemical reactions mediated by metal ions. There is a realisation of the role of metal complexes and inorganic ions as therapeutics such as iron in leukaemia, thalassemia and sickle cell anaemia, iodine in hypothyroidism and zinc, vanadium and chromium in glucose metabolism. The most recent realisation is of the use of zinc in the prevention and treatment of COVID-19.

In this sixth edition of Jack Jie Li's seminal'Name Reactions', the author has added three or more synthetic applications of name reactions to reflect the recent advances in organic chemistry. As in previous editions, each reaction is delineated by its detailed step-by-step, electron-pushing mechanism and supplemented with the original and the latest references, especially from review articles. This book is not only an indispensable resource for advanced undergraduate and graduate students for learning and preparing exams, but is also a good reference book for all organic chemists in both industry and academia. Unlike other books on name reactions in organic chemistry, Name Reactions, A Collection of Detailed Reaction Mechanisms and Synthetic Applications focuses on the reaction mechanisms. It covers over 300 classical as well as contemporary name reactions.

The origin of life has been investigated by many researchers from various research fields, such as Geology, Geochemistry, Physics, Chemistry, Molecular Biology, Astronomy and so on. Nevertheless, the origin of life remains unsolved. One of the reasons for this could be attributed to the different approaches that researchers have used to understand the events that happened on the primitive Earth. The origins of the main three members of the fundamental life system, as gene, genetic code and protein, could be only separately understood with these approaches. Therefore, it is necessary to understand the origins of gene, the genetic code, tRNA, metabolism, cell structure and protein not separately but comprehensively under a common concept in order to understand the origin of life, because the six members are intimately related to each other. In this monograph, the author offers a comprehensive hypothesis to explain the origin of life under a common concept. At the same time, the author offers the [GADV] hypothesis contrasting it with other current hypotheses and discusses the results of analyses of genes/proteins and the experimental data available in the exploration of the current knowledge in the field. This book is of interest for science students, researchers and the general public interested in the origin of life.

This book provides researchers in the fields of organic chemistry, organometallic chemistry and homogeneous catalysis with an overview of significant recent developments in the area of metal-ligand cooperativity, with a focus on pincer architectures. The various contributions highlight the widespread impact of M–L co-operativity phenomena on modern organometallic chemistry and catalyst development. The development of efficient and selective catalytic transformations relies on the understanding and fine control of the various elementary reactions that constitutes a catalytic cycle. Co-operative ligands, which actively participate in bond making and bond breaking together to the metal they support, open up new avenues in this area. In particular, buttressing a weak or reactive metal-ligand bond by flanking coordinating arms in a pincer ligand design is proving a versatile strategy to access robust metal complexes that exhibit unusual and selective reactivity patterns.

This dictionary contains 739 entries with about 1400 references to the primary literature. Details on the composition, performance, sensitivity and other pertinent properties of Energetic Materials such as High Explosives, Propellants, Pyrotechnics, as well as important ingredients such as Oxidizers, Fuels, Binders, and Modifiers are given and presented partly in over 180 tables with more than 240 structural formulas. In detail the dictionary gives elaborate descriptions of 460 Chemical Substances 170 Pyrotechnic Compositions 360 High Explosive and Propellant Formulations In addition, the basic physical and thermochemical properties of 435 pure substances (elements & compounds) typically occuring as ingredients or reaction products are given too. 150 Figures, schemes and diagrams explain Applications, Test methods, Scientific facilities, and finally Individuals closely tied with the development and investigation of Energetic Materials. The book is intended for readers with a technical or scientific background, active in governmental agencies, research institutes, trade and industry, concerned with the procurement, development, manufacture, investigation and use of Energetic Materials, such as High Explosives, Propellants, Pyrotechnics, Fireworks and Ammunition. The book serves both as a daily reference for the experienced as well as an introduction for the newcomer to the field.

This book provides an overview of the latest developments in the field of nanoparticle catalysis. It not only discusses established topics in detail, but also explores several emerging topics. Catalysis with nanoparticles is expanding exponentially and is attracting significant interest due to the many exciting findings being reported. Mastering the synthesis, characterization, stabilization and use of these catalysts offers numerous possibilities that far exceed those of classic heterogeneous and homogeneous catalysis.

In Zinc Oxide: Production, Properties and Applications, the authors first provide a summary of the natural sources available for the synthesis of zinc oxide nanoparticles, enlisting some plant-mediated synthesized zinc oxide nanoparticles showing promising antimicrobial, antioxidant, cytotoxic and photocatalytic properties. Important technological opportunities and challenges emphasizing the electrical and optoelectronic features of elongated zinc oxide nanoparticle nanosystems are reviewed. The various nonlinear optical phenomenon observed in zinc oxide thin film, inlcuding nonlinear absorption, nonlinear refraction, nonlinear scattering and harmonic generations are introduced. Selected literature on the use of zinc oxide nanoparticles for the immobilization of enzymes is reviewed, as well as the use of zinc oxide nanoparticle/enzyme systems in the fabrication of biosensors. The authors explore transition metal doped zinc oxide nanoparticles for a wide range of catalytic organic reactions, further exploring their catalytic applications for organic transformations at mild reaction conditions. The basic concepts behind the development of nanostructured zinc oxide nanoparticles, including the solid state reaction, hydrothermal method, solvothermal method and co-precipitation method are discussed. Lastly, a facile, eco-friendly synthesis of zinc oxide nanoparticles using the peel extract of Musa paradisiaca L, Punica granatum L, and Citrus reticulata Blanco as bioreducing agent is reported.

Advances in Organometallic Chemistry, Volume 74, the latest release in this longstanding serial, is known for its comprehensive coverage of topics in organometallic synthesis, reactions, mechanisms, homogeneous catalysis, and more. It is ideal for a wide range of researchers involved in organometallic chemistry, with this updated release including chapters on Metal dendrimers used in biomedical applications, Sigma-bond activation reactions induced by unsaturated osmium (IV) complexes with bulky phosphines, Base metal pincer complexes, and more. Contains contributions from leading authorities in the field of organometallic chemistry Covers topics in organometallic synthesis, reactions, mechanisms, homogeneous catalysis, and more Informs and updates readers on the latest developments in the field Carefully edited to provide easy-to-read material

Visible light is an abundant source of energy. While the conversion of light energy into electrical energy (photovoltaics) is highly developed and commercialized, the use of visible light in chemical synthesis is far less explored. Chemical photocatalysts that mimic principles of biological photosynthesis utilize visible light to drive endothermic or kinetically hindered reactions.

Organoselenium Chemistry is a unique resource in this branch of organic/organometallic chemistry. The authors give an overview of synthesis strategies, introduce bioactive and environmentally friendly organoselenium compounds and discuss their applications from organic synthesis to the clinic.

Introduces students to the basics of bioinorganic chemistry This book provides the fundamentals for inorganic chemistry and biochemistry relevant to understanding bioinorganic topics. It provides essential background material, followed by detailed information on selected topics, to give readers the background, tools, and skills they need to research and study bioinorganic topics of interest to them. To reflect current practices and needs, instrumental methods and techniques are referred to and mixed in throughout the book. Bioinorganic Chemistry: A Short Course, Third Edition begins with a chapter on Inorganic Chemistry and Biochemistry Essentials. It then continues with chapters on: Computer Hardware, Software, and Computational Chemistry Methods; Important Metal Centers in Proteins; Myoglobins, Hemoglobins, Superoxide Dismutases, Nitrogenases, Hydrogenases, Carbonic Anhydrases, and Nitrogen Cycle Enzymes. The book concludes with chapters on Nanobioinorganic Chemistry and Metals in Medicine. Readers are also offered end-of-section summaries, conclusions, and thought problems. Reduces size of the text from previous edition to match the first, keeping it appropriate for a one-semester course Offers primers and background materials to help students feel comfortable with research-level bioinorganic chemistry Emphasizes select and diverse topics using extensive references from current scientific literature, with more emphasis on molecular biology in the biochemistry section, leading to a discussion of CRISPR technology Adds new chapters on hydrogenases, carbonic anhydrases, and nitrogen cycle enzymes, along with a separate chapter on nanobioinorganic chemistry Features expanded coverage of computer hardware and software, metalloenzymes, and metals in medicines Supplemented with a companion website for students and instructors featuring Powerpoint and JPEG figures and tables, arranged by chapter Appropriate for one-semester bioinorganic chemistry courses, Bioinorganic Chemistry: A Short Course, Third Edition is ideal for upper-level undergraduate and beginning graduate students. It is also a valuable reference for practitioners and researchers in need of a general introduction to the subject, as well as chemists requiring an accessible reference.

Design of new processes that avoid the use of toxic reagents has been the focus of intense research of late. Catalysis by metals and non-metals offers diverse opportunities for the development of new organic reactions with promising range of selectivities—chemoselectivity, regioselectivity, diastereoselectivity, and enantioselectivity. Furthermore, these transformations frequently occur under mild conditions, tolerate a broad array of functional groups, and proceed with high stereoselectivity. The area of catalysis is sometimes referred to as a ‘foundational pillar'of green chemistry. Catalytic reactions often reduce energy requirements and decrease separations because of increased selectivity; they are also capable of permitting the use of renewable feedstocks of less toxic reagents or minimizing the quantities of reagents needed. New catalytic organic synthesis methodologies have, thus, offered several possibilities for considerable improvement in the eco-compatibility of fine chemical production. Hence, these catalytic methodologies have emerged as powerful tools for the efficient and chemoselective synthesis of heterocyclic molecules.Key Features: Presents the synthesis of different five-membered heterocycles. Contains the most up-to-date information in this fast-moving field. Covers novel catalytic approaches used in the study and application of catalysts in synthetic organic reactions. Presents new methodologies for the synthesis of heterocycles.

Metal-Sulfur clusters play an essential role in living organisms through the unique character of sulfur-metal bonding. The new volume in prestigious Metal Ions in Life Sciences explores different transition metal complexes with sulfur, their biosynthesis and biological functions in regulation of gene expression, catalysis of important metabolic reactions and protein structure arrangement.

Advances in Organometallic Chemistry, Volume 73, the latest release in this longstanding serial, is known for its comprehensive coverage of topics in organometallic synthesis, reactions, mechanisms, homogeneous catalysis, and more. It is ideal for a wide range of researchers involved in organometallic chemistry, including synthetic protocols, mechanistic studies and practical applications. Specific chapters in this new release include Metal carbonyl promoted multicomponent coupling of alkyne for synthesis of heterocyclic compounds, Group 10 metal(0) complexes stabilized by phosphorus and carbon donor ligands, Synthesis of Nitrogen-containing Molecules via Transition Metal-Catalyzed Reactions on Isoxazoles, Anthraniils and Benzoisoxazoles, and more. Contains contributions from leading authorities in the field of organometallic chemistry Covers topics in organometallic synthesis, reactions, mechanisms, homogeneous catalysis, and more Informs and updates readers on the latest developments in the field Carefully edited to provide easy-to-read material

Palladacycles: Catalysis and Beyond provides an overview of recent research in palladacycles in catalysis for cross-coupling and similar reactions. In the quest for developing highly efficient and robust palladium-based catalysts for C-C bond formation via cross-coupling reactions, palladacycles have played a significant role. In recent years, they have found a wide variety of applications, ranging from catalysts for cross-coupling and related reactions, to their more recent application as anticancer agents. This book explores early examples of the use of palladacyclic complexes in catalysis employing azobenzene and hydrazobenzene as coordinating ligands. Its applications in processes such as selective reduction of alkenes, alkynes, or nitroalkanes are also covered. Palladacycles: Catalysis and Beyond reveals the tremendous advances that have taken place in the potential applications of palladacycles as versatile catalysts in academia and industry. It is a valuable resource for synthetic chemists, organometallic chemists, and chemical biologists. Reviews the importance and various applications of palladacycles in academic research and industry, including industrial scale applications Includes the impact of palladacycles on coupling reactions and potential applications as anticancer agents Features coverage of nano and colloidal catalysis via palladacyclic degradation

Sprengstoffe, Treibmittel, Pyrotechnika ist ein Lexikon mit 686 alphabetisch geordneten Sacheinträgen. Es beschreibt die physikalisch-chemischen Eigenschaften, Leistung, Empfindlichkeit, GHS- sowie REACH-Einstufung von 415 gängigen chemischen Metallen, Nichtmetallen und Verbindungen, die als Explosivstoffe, Oxidatoren, Brennstoffe, Bindemittel und Additive zum Einsatz kommen sowie die thermochemischen Eigenschaften von 435 Reinstoffen die als Reaktionsprodukte auftreten können. Außerdem informiert das Lexikon über die Zusammensetzung, Leistung und Empfindlichkeit von knapp 300 Sprengstoff- und Treibmittelformulierungen sowie von ca. 150 pyrotechnischen Sätzen. Daneben werden zivile und militärische Anwendungen für Explosivstoffe, deren chemische und physikalische Grundlagen, Prüfverfahren, Institutionen sowie schließlich auch Personen beschrieben, die sich international um die Entwicklung und Untersuchung von Explosivstoffen verdient gemacht haben. 100 zum Teil farbige Abbildungen, 160 Tabellen, 228 Strukturformeln, über 1200 Literaturstellen zur Primärliteratur, 1700 Einträge im Sachverzeichnis sowie die englische Übersetzung aller Sacheinträge machen das Buch zu einem unverzichtbaren Standardwerk für alle Leser, die mit Sprengstoffen, Treibmitteln, pyrotechnischen Sätzen, Feuerwerkskörpern und Munition befasst sind. Sprengstoffe, Treibmittel, Pyrotechnika ist zur fachlichen Einarbeitung beim Berufseinstieg, als auch zur Weiterbildung im täglichen Gebrauch geeignet. Über den Autor Dr. Ernst-Christian Koch, FRSC studierte und promovierte im Fach Chemie an der Technischen Universität Kaiserslautern (TUK). Er ist seit über zwanzig Jahren aktiv im Bereich der Forschung und Entwicklung von Explosivstoffen. Dr. Koch ist Inhaber der Lutradyn Energetic Materials Science & Technology Consulting in Kaiserslautern. Aus den Rezensionen zur 1. Auflage „(...) Das Wissen um Explosivstoffe kann wohl kaum besser komprimiert dargestellt und zusammengefasst werden als in diesem Lexikon'-- Rezension von Truppendienst, Magazin des Österreichischen Bundesheers, zur 1. Auflage „Dem Autor ist es gelungen, umfangreiches und komplexes Fachwissen übersichtlich und verständlich (…) aufzuzeigen.'-- Rezension von Sprenginfo, Fachzeitschrift des Deutschen Sprengverbandes e.V., zur 1. Auflage

Chapter contribution from Ben Feringa, Nobel Laureate in Chemistry 2016.Atropisomerism and Axial Chirality provides a global survey of the chemistry of axially chiral compounds including biaryls, heterobiaryls, non-biaryl atropisomers, allenes and spyrocyclic derivatives. From the perspective of a synthetic organic chemist, this book provides a unique compilation of the available methodologies for their synthesis, with emphasis on the most efficient and modern strategies, a review of the huge amount of practical applications in the field of asymmetric catalysis, either as transition metal ligands or as organocatalysts, and an overview of their occurrence as bioactive compounds and natural products.The first of its kind, this book serves as a general introduction and a practical reference to advanced chemistry students and researchers, while also offering creative ideas for further developments in the field.

Fluorine in Life Sciences: Pharmaceuticals, Medicinal Diagnostics and Agrochemicals, volume four in Alain Tressaud's Progress in Fluorine Science series, presents a critical, multidisciplinary overview of the contributions of fluorinated products to solve important global issues in various life science fields, particularly in medicinal chemistry, molecular imaging techniques and agriculture. Edited by recognized experts, this book provides unique coverage of the wide-ranging uses and implications of fluorine and fluorinated compounds. Topics include medicinal monitoring and diagnosis, 19F MRI in medicine and in vivo cell tracking, 18F-labeled radiopharmaceuticals, brain imaging and neurology, risk assessment of reactive metabolites in drug discovery, and more. Edited by Alain Tressaud, past Chair and founder of the CNRS French Fluorine Network, each book in the collection also includes the work of highly-respected volume editors and contributors from both academia and industry who bring valuable and varied content to this active field. Covers a wide range of topics - from organic and physical chemistry, to pharmaceuticals, agrochemicals and medical diagnostics Describes major modern syntheses and unique reaction mechanisms yielding fluorine compounds in these diverse life science settings Features contributions from a wealth of global experts Acts as the fourth volume in Alain Tressaud's Progress in Fluorine Science

This volume highlights recent progress on the fundamental chemistry and mechanistic understanding of metallocofactors, with an emphasis on the major development in these areas from the perspective of bioinorganic chemistry. Metallocofactors are essential for all forms of life and include a variety of metals, such as iron, molybdenum, vanadium, and nickel. Structurally fascinating metallocofactors featuring these metals are present in many bacteria and mediate remarkable metabolic redox chemistry with small molecule substrates, including N2, CO, H2, and CO2. Current interest in understanding how these metallocofactors function at the atomic level is enormous, especially in the context of sustainably feeding and fueling our planet; if we can understand how these cofactors work, then there is the possibility to design synthetic catalysts that function similarly.

This expanded, revised, and updated second edition of Innovations in Green Chemistry and Green Engineering provides a comprehensive introduction to the state-of-the-art in this key area of sustainability research. Processes that meet the objectives of green chemistry and chemical engineering minimize waste and energy use, and eliminate toxic by-products. Given the ubiquitous nature of products from chemical processes in our lives, green chemistry and chemical engineering are vital components of any sustainable future. Peer-reviewed articles from worldwide experts present the latest developments on topics ranging from organic batteries and green catalytic transformations to green nanoscience and nanotoxicology. Now under the leadership of distinguished Editors from the Chinese Academy of Sciences, this volume in the Encyclopedia of Sustainability Science and Technology, Second Edition, is an essential, one-stop reference for professionals in researchand industry. The book also fills the need for an authoritative course text in environmental and green chemistry and chemical engineering at the upper-division undergraduate and graduate levels.

Build a strong foundation in physical-inorganic chemistry with this internationally renowned text. Inorganic Chemistry, 5th edition, Global edition, by Catherine E Housecroft and Alan G Sharpe, is a widely respected introduction to the physical-inorganic principles of chemistry. With new research, this edition introduces you to the descriptive chemistry of the elements and the role played by inorganic chemistry in our everyday lives. Its carefully developed pedagogical approach helps you engage with topics using striking visuals to consolidate your understanding. The text covers topics such as molecular symmetry and bonding in polyatomic molecules, teaching you to apply your learnt knowledge to the real world. This updated edition includes: The most recent advances in inorganic chemistry. An extended periodic table of the elements. Updated chapters to include new ‘super-heavy'elements. Three-dimensional molecular structures which bring the world of inorganic chemistry to life. With an array of features to support your learning, Inorganic Chemistry serves as a comprehensive introduction perfect for chemistry students. This title comes with a Companion Website.

Palladium-Catalyzed Modification of Nucleosides, Nucleotides and Oligonucleotides describes the procedures and protocols related to the modification of nucleosides, nucleotides and oligonucleotides via Pd-mediated cross-coupling processes. The book highlights the growing area of nucleic acid modification and how Pd-mediated coupling reactions can assist this development. Users will find key synthetic protocols for these reactions in this latest volume in the Latest Trends in Palladium Chemistry series. As most of the research in the field of antiviral agents has centered on the use of modified nucleosides that have exhibited promising activity, this book provides an up-to-date reference for both professionals in industry and other interested parties. Provides synthetic routes for useful nucleoside molecules, information otherwise found only through time-consuming literature searches Covers metal-mediated and metal-catalyzed cross coupling processes of nucleosides and related compounds Includes Suzuki-Miyaura, Stille and Sonogashira reactions, as well as C-H bond functionalization Highlights the growing area of nucleic acid modification and how Pd-mediated coupling reactions can assist

...von geladen bis explosiv, von gefährlich bis wohlriechend! Die 2. Auflage des erfolgreichen Wörterbuchs der Chemie von Cole mit nunmehr 32.500 Begriffen aus allen Bereichen der Allgemeinen und Theoretischen Chemie, von Anorganik zur Organik, der Physikalischen Chemie, Biochemie, Nuklearchemie und Polymerchemie. Auch Begrifflichkeiten von Geräten, Methoden oder aus der Analytik werden in beiden Sprachen zur Verfügung gestellt. Das Wörterbuch der Chemie ist ein unentbehrlicher Begleiter für Wissenschaftler, Übersetzer, Dozenten und Studenten, Lehrer und Schüler, die sich zwischen Reagenzglas, Bunsenbrenner und „Hightech-Synthesechemie“ ganz zu Hause fühlen.Thematische Begriffsfelder (clusters) ermöglichen die zusammenhängende Erschließung eines Themas und erleichtern die Arbeit beim Übersetzen.

This book will describe Ruthenium complexes as chemotherapeutic agent specifically at tumor site. It has been the most challenging task in the area of cancer therapy. Nanoparticles are now emerging as the most effective alternative to traditional chemotherapeutic approach. Nanoparticles have been shown to be useful in this respect. However, in view of organ system complicacies, instead of using nanoparticles as a delivery tool, it will be more appropriate to synthesize a drug of nanoparticle size that can use blood transport mechanism to reach the tumor site and regress cancer. Due to less toxicity and effective bio-distribution, ruthenium (Ru) complexes are of much current interest. Additionally, lumiscent Ru-complexes can be synthesized in nanoparticle size and can be directly traced at tissue level. The book will contain the synthesis, characterization, and applications of various Ruthenium complexes as chemotherapeutic agents. The book will also cover the introduction to chemotherapy, classification of Ru- complexes with respect to their oxidation states and geometry, Ruthenium complexes of nano size: shape and binding- selectivity, binding of ruthenium complexes with DNA, DNA cleavage studies and cytotoxicity. The present book will be more beneficial to researchers, scientists and biomedical. Current book will empower specially to younger generation to create a new world of ruthenium chemistry in material science as well as in medicines. This book will be also beneficial to national/international research laboratories, and academia with interest in the area of coordination chemistry more especially to the Ruthenium compounds and its applications.

All living things contain carbon in some form, as it is the primary component of macromolecules including proteins, lipids, nucleic acids (RNA and DNA), and carbohydrates. As a matter of fact, it is the backbone of all organic (chemistry) compounds forming different kinds of bonds. Carbon: The Black, the Gray and the Transparent is not a complete scientific history of the material, but a book that describes key discoveries about this old faithful element while encouraging broader perspectives and approaches to its research due to its vast applications. All allotropes of carbon are described in this book, along with their properties, uses, and methods of procurement or manufacturing. Black carbon is represented by coal, gray carbon is represented by graphite, and transparent carbon is represented by diamond.

Das Buch beschreibt naturwissenschaftliche und technologische Zusammenhänge der Ernährung und Gesundheit aus biologischer, chemischer und biochemischer Sicht.

This book provides an overview of polymer nanocomposites and hybrid materials with polyhedral oligomeric silsesquioxanes (POSS). Among inorganic nanoparticles, functionalized POSS are unique nano-building blocks that can be used to create a wide variety of hybrid and composite materials, where precise control of nanostructures and properties is required. This book describes the influence of incorporation of POSS moieties into (organic) polymer matrices on the mechanical, thermal and flammability behavior of composites and hybrid organic-inorganic materials. Importantly, POSS-containing materials can be bio-functionalized by linking e.g. peptides and growth factors through appropriate surface modification in order to enhance the haemo-compatibility of cardiovascular devices made of these materials. This volume includes descriptions of synthesis routes of POSS and POSS-containing polymeric materials (e.g. based on polyolefines, epoxy resins and polyurethanes), presentation of POSS'role as flame retardants and as biocompatible linker, as well as the depiction of decomposition and ageing processes.

Volume 18, entitled Metallo-Drugs: Development and Action of Anticancer Agents of the series Metal Ions in Life Sciences centers on biological, medicinal inorganic chemistry. The serendipitous discovery of the antitumor activity of cis-diamminodichloroplatinum(II) (cisplatin) by Barnett Rosenberg in the 1960s is a landmark in metallodrug-based chemotherapy. The success of cisplatin in the clinic, followed by oxaliplatin and carboplatin, along with their drawbacks relating mainly to resistance development and severe toxicity, initiated research on polynuclear platinum complexes and on Pt(IV) complexes as prodrugs. Furthermore, the indicated shortcomings led to the exploration of other transition and main group metal ions, among them Ru(II/III), Au(I/III), Ti(IV), V(IV/V), and Ga(III) including also the essential metal ions Fe(II/III), Cu(I/II), and Zn(II). Ionic as well as covalent and non-covalent interactions between structurally very different complexes and biomolecules like nucleic acids, proteins, and carbohydrates are studied and discussed with regard to their possible anticancer actions. Hence, MILS-18 summarizes the research at the forefront of medicinal inorganic chemistry, including studies on the next-generation, tailor-made anticancer drugs. All this and more is treated in an authoritative and timely manner in the 17 stimulating chapters of this book, written by 39 internationally recognized experts from 10 nations (from the US via Europe to China and Australia). The impact of this vibrant research area is manifested by more than 2700 references, nearly 150 illustrations (more than half in color) and several comprehensive tables. Metallo-Drugs: Development and Action of Anticancer Agents is an essential resource for scientists working in the wide range from enzymology, material sciences, analytical, organic, and inorganic biochemistry all the way through to medicine including the clinic... not forgetting that it also provides excellent information for teaching.

Pincer Compounds: Chemistry and Applications offers valuable state-of-the-art coverage highlighting highly active areas of research—from mechanistic work to synthesis and characterization. The book focuses on small molecule activation chemistry (particularly H2 and hydrogenation), earth abundant metals (such as Fe), actinides, carbene-pincers, chiral catalysis, and alternative solvent usage. The book covers the current state of the field, featuring chapters from renowned contributors, covering four continents and ranging from still-active pioneers to new names emerging as creative strong contributors to this fascinating and promising area. Over a decade since the publication of Morales-Morales and Jensen's The Chemistry of Pincer Compounds (Elsevier 2007), research in this unique area has flourished, finding a plethora of applications in almost every single branch of chemistry—from their traditional application as very robust and active catalysts all the way to potential biological and pharmaceutical applications. Describes the chemistry and applications of this important class of organometallic and coordination compounds Includes contributions from global leaders in the field, featuring pioneers in the area as well as emerging experts conducting exciting research on pincer complexes Highlights areas of promising and active research, including small molecule activation, earth abundant metals, and actinide chemistry

The series Topics in Heterocyclic Chemistry presents critical reviews on present and future trends in the research of heterocyclic compounds. Overall the scope is to cover topics dealing with all areas within heterocyclic chemistry, both experimental and theoretical, of interest to the general heterocyclic chemistry community. The series consists of topic related volumes edited by renowned editors with contributions of experts in the field. All chapters from Topics in Heterocyclic Chemistry are published Online First with an individual DOI. In references, Topics in Heterocyclic Chemistry is abbreviated as Top Heterocycl Chem and cited as a journal.

This volume on iron-sulfur proteins includes chapters that discuss how microbes, plants, and animals synthesize these complex prosthetic groups, and why it is important to understand the chemistry and biogenesis of iron sulfur proteins. In addition to their vital importance in mitochondrial respiration, numerous iron sulfur proteins are important in maintenance of DNA integrity. Multiple rare human diseases with different clinical presentations are caused by mutations of genes in the iron sulfur cluster biogenesis pathway. Understanding iron sulfur proteins is important for understanding a rapidly expanding group of metabolic pathways important in all kingdoms of life, and for understanding processes ranging from nitrogen fixation to human disease.

Modern Inorganic Synthetic Chemistry, Second Edition captures, in five distinct sections, the latest advancements in inorganic synthetic chemistry, providing materials chemists, chemical engineers, and materials scientists with a valuable reference source to help them advance their research efforts and achieve breakthroughs. Section one includes six chapters centering on synthetic chemistry under specific conditions, such as high-temperature, low-temperature and cryogenic, hydrothermal and solvothermal, high-pressure, photochemical and fusion conditions. Section two focuses on the synthesis and related chemistry problems of highly distinct categories of inorganic compounds, including superheavy elements, coordination compounds and coordination polymers, cluster compounds, organometallic compounds, inorganic polymers, and nonstoichiometric compounds. Section three elaborates on the synthetic chemistry of five important classes of inorganic functional materials, namely, ordered porous materials, carbon materials, advanced ceramic materials, host-guest materials, and hierarchically structured materials. Section four consists of four chapters where the synthesis of functional inorganic aggregates is discussed, giving special attention to the growth of single crystals, assembly of nanomaterials, and preparation of amorphous materials and membranes. The new edition's biggest highlight is Section five where the frontier in inorganic synthetic chemistry is reviewed by focusing on biomimetic synthesis and rationally designed synthesis. Focuses on the chemistry of inorganic synthesis, assembly, and organization of wide-ranging inorganic systems Covers all major methodologies of inorganic synthesis Provides state-of-the-art synthetic methods Includes real examples in the organization of complex inorganic functional materials Contains more than 4000 references that are all highly reflective of the latest advancement in inorganic synthetic chemistry Presents a comprehensive coverage of the key issues involved in modern inorganic synthetic chemistry as written by experts in the field

Microwave Chemistry has changed the way to work in chemical laboratories and is an established state-of-the-art technology to accelarate and enhance chemical processes. This book not only gives an overview of the technology, its historical development and theoretical background, but also presents its exceptionally broad spectrum of applications. Microwave Chemistry enables graduate students and scientist to learn and apply its methods successfully.

The series Topics in Heterocyclic Chemistry presents critical reviews on present and future trends in the research of heterocyclic compounds. Overall the scope is to cover topics dealing with all areas within heterocyclic chemistry, both experimental and theoretical, of interest to the general heterocyclic chemistry community. The series consists of topic related volumes edited by renowned editors with contributions of experts in the field. All chapters from Topics in Heterocyclic Chemistry are published Online First with an individual DOI. In references, Topics in Heterocyclic Chemistry is abbreviated as Top Heterocycl Chem and cited as a journal