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This book provides a comprehensive overview of a series of bismuth oxyhalide compounds of BiOX (X=F, Cl, Br, I), in terms of their microstructure, electronic/band structure, preparation techniques, optical properties and their applications. The book brings together, for the first time, a compilation of advances in this area, including results achieved at the authors'lab (such as ultra-microscopy characterization by means of aberration-corrected STEM), offering a valuable guide for researchers and students alike.