Search

[Display omitted] • Ru nanoparticles (NPs) anchored on heterointerface of 1 T-MoS 2 and carbon paper (Ru@1T-MoS 2 /CFP) is designed. • The Ru 2 @MoS 2 -85 %/CFP presents superb HER performance with overpotential of 19 mV and a low Tafel slope of 29 mV dec–1. • The strong interaction between 1 T-MoS 2 and OH* makes OH* migrate from Ru to MoS 2 , alleviating the poisoning of Ru sites. • Ru NPs close to the interface of 1 T-MoS2/CFP can achieve an optimal hydrogen adsorption energy for high HER performance. Ru is considered as highly efficient Pt-free catalyst in hydrogen evolution reaction (HER) due to its fast water dissociation kinetics. However, its strong affinity to OH* and H* greatly limits its HER performance. Herein, Ru nanoparticles (NPs) anchored on the mixed substrates of MoS 2 (different 1T contents) and carbon fiber paper (Ru@MoS 2 -1T%/CFP) is designed and synthesized with three kinds of interfaces (MoS 2 /CFP, Ru/CFP, and Ru/MoS 2) as excellent electrocatalyst for HER. Particularly, the Ru 2 @MoS 2 -85%/CFP presents superb HER performance with overpotential of 19 mV at 10 mA cm−2, a low Tafel slope of 29 mV dec–1 and stability of up to 10 days, outperforming reported Ru-based catalysts and Pt/C. The experimental and DFT studies disclose that the hydroxyl migration-assisted dissociation of water and interface-engineering desorption of H 2 process, occurring at the mutually hybridized interface sites of Ru/MoS 2 /CFP, simultaneously speed Volmer/Tafel processes. Compared to Ru, the stronger interaction of 1T-MoS 2 to OH* makes OH* migrate from Ru to MoS 2 , alleviating the poisoning of Ru sites. Also, only Ru NPs close to the interface of 1T-MoS 2 /CFP can achieve an optimal hydrogen adsorption energy for high HER performance. This designed strategy provides a novel idea for preparing supported Ru catalysts for excellent HER performance. [ABSTRACT FROM AUTHOR]

• By controlling the concentration of Li-ions, the phase composition of high entropy oxide (HEO) can be regulated. • A high concentration of point defects (i.e., oxygen vacancies) and extended defects (such as dislocations and stacking faults) can be introduced into the spinel phase. • Successful control over defect engineering in spinel-rocksalt dual-phase HEO has been achieved through phase-selective regulation. • The incorporation of an intergrown interface improves the conductivity and structural stability of electrode materials. This paper presents the effectiveness of phase-selective regulation in the Mg-Co-Ni-Mn-Zn-O-based spinel-rocksalt dual-phase high entropy oxide (HEO) for achieving novel electrochemical properties. The key factor distinguishing spinel from rocksalt in response to Li-ion incorporation is the separation of ions at tetrahedral sites, which offers greater structural adjustability and enables incoordinate defect regulation of individual phases. The optimized Li incorporation facilitates a high concentration of point defects (specifically oxygen vacancies) and appropriately extended defects (such as dislocations and stacking fault) in the spinel phase, accompanied by a spinel-rocksalt intergrown interface. These exquisite adjustments improve the conductivity, structural stability, and specific capacity of the HEO electrode material. Nevertheless, the ever-increasing Li content triggers the transformation from a spinel-rocksalt dual-phase HEO to a single-phase rocksalt HEO, resulting in serious lattice distortion and excessive defects that hinder the efficient transport of Li-ion, ultimately leading to unsatisfactory electrochemical performance. Thus, phase-selective engineering facilitates the determination of appropriate defects that synergistically interact with the intergrown interface and the dual-phase structure. The optimized HEO20 exhibits outstanding electrochemical performance, with a high initial discharge capacity of 2049.8 mAh g−1 at 0.1C and a high-rate capability of 502.9 mAh g−1 at 2C. Moreover, it demonstrates remarkable battery capacity retention of 99.5% after 1300 cycles at 0.5C and a stable cycle performance of 717.3 mAh g−1. [ABSTRACT FROM AUTHOR]

• K.S Bfr can store Cd2+ in protein cavities in vitro. • The engineering bacteria with K.S Bfr can enhance the removal of Cd2+ from water. • Bacterioferritin up-regulates the ribosomal metabolic pathway. Cadmium can enter water through various industrial pollutants, posing serious threats to the ecological environment and human health. This study unveiled an effective method for removing Cd2+ from water by introducing bacterioferritin, known as Candidatus Kuenenia stuttgartiensis (K.S Bfr), into engineering bacteria (EB) to facilitate metal ion removal via K.S Bfr storage. Additionally, the paper explores the mechanism behind Cd2+ removal by EB using K.S Bfr. The binding kinetics revealed that EB's Cd2+ binding capacity was significantly higher than that of wild bacteria, and Cd2+ was found to enter the protein cavity of K.S Bfr in vitro. When exposed to Cd2+ concentrations ranging from 0 to 2.5 mM, EB demonstrated a survival rate above 70 %, whereas wild bacteria's survival rate remained below 50 %. The superior Cd2+ removal capacity of EB can be attributed to the intracellular storage capacity of K.S Bfr. Tandem Mass Tags quantitative proteomics analysis showed that EB mitigated cytotoxicity mainly by up-regulating the expression of binding, homeostasis, efflux, and ribosome-related proteins. K.S Bfr was identified as a major pathway for bacteria to remove Cd2+ since it provided independent storage space for Cd2+ and ensured intracellular metal ion homeostasis. This study presents an effective strategy for treating metal wastewater, offering promising new applications for bioremediation. [ABSTRACT FROM AUTHOR]