Search

This book presents the current status of CO2 utilization from fundamental studies to industrial tests. With the development of renewable energy, carbon dioxide will become an important feedstock for the synthesis of fuels and chemicals, and CO2 utilization must be the final solution for the carbon dioxide issues. This book discusses the effective techniques for activating inert carbon dioxide and various approaches for CO2 conversion, such as homogeneous catalytic conversion, homogeneous catalytic conversion, heterogeneous catalytic conversion, photocatalytic conversion, electrocatalytic conversion, photo-thermal catalytic conversion, plasma-chemical/plasma-catalytic conversion, and bio-catalytic conversion. It also addresses the electronic and geometric structural effects of the supported catalyst on the activity and selectivity of the conversion of carbon dioxide. The significant effects from single atom catalyst to nanoparticle are also discussed, and process intensification in catalyst preparation and reaction is highlighted. Furthermore, this book contains chapters with theoretical studies, including functional theory, which has played an important role in the catalyst design, the explanation of the reaction mechanism, and in understanding the synergy of reaction and heat and mass transfer. Given its scope, this book appeals to a wider readership, especially for researchers in the field of CO2 utilization.

This brief explains the principles and fundamentals of carbon dioxide utilization and highlights the transformation to fuels and value-added chemicals such as formic acid and methanol. It is divided into six chapters, including an introduction to the basics of CO2 utilization and transformation of CO2 to formic acid and methanol with homogeneous and heterogeneous catalysts, respectively. The brief will appeal to a wide readership of academic and industrial researchers focusing on homogeneous and heterogeneous catalysis, organometallic chemistry, green chemistry, energy conversion and storage.

​The series Topics in Current Chemistry Collections presents critical reviews from the journal Topics in Current Chemistry organized in topical volumes. The scope of coverage is all areas of chemical science including the interfaces with related disciplines such as biology, medicine and materials science. The goal of each thematic volume is to give the non-specialist reader, whether in academia or industry, a comprehensive insight into an area where new research is emerging which is of interest to a larger scientific audience. Each review within the volume critically surveys one aspect of that topic and places it within the context of the volume as a whole. The most significant developments of the last 5 to 10 years are presented using selected examples to illustrate the principles discussed. The coverage is not intended to be an exhaustive summary of the field or include large quantities of data, but should rather be conceptual, concentrating on the methodological thinking that will allow the non-specialist reader to understand the information presented. Contributions also offer an outlook on potential future developments in the field.

This compendium of accounts reveals the unique perspectives of many scientists who made major contributions to the Nobel Prize-winning discovery of C60 buckminsterfullerene but who have not previously published personal accounts. The introduction attempts to provide a rational framework for understanding how this discovery came about and how firmly

This book provides an analysis of the reaction mechanisms relevant to a number of processes in which CO2 is converted into valuable products. Several different processes are considered that convert CO2 either in specialty chemicals or in bulk products or fuels. For each reaction, the mechanism is discussed and the assessed steps besides the dark sites of the reaction pathway are highlighted. From the insertion of CO2 into E-X bonds to the reduction of CO2 to CO or other C1 molecules or else to C2 or Cn molecules, the reactions are analysed in order to highlight the known and obscure reaction steps. Besides well known reaction mechanisms and energy profiles, several lesser known situations are discussed. Advancing knowledge of the latter would help to develop efficient routes for the conversion of CO2 into valuable products useful either in the chemical or in the energy industry. The content of this book is quite different from other books reporting the use of CO2. On account of its clear presentation, “Reaction Mechanisms in Carbon Dioxide Conversion” targets in particular researchers, teachers and PhD students.