51,051 results
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2. Chitosan-adhered graphene/nano iron tetroxide carbon paper electrode for the detection of hexavalent chromium.
- Author
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Liangyi Tian, Ting Huang, Yilei Xiang, Yichun Bi, Zihan Yu, Jihuan Xie, Jingping Qiu, Lemin Chen, and Linbin Jiang
- Subjects
- *
CARBON electrodes , *CARBON paper , *HEXAVALENT chromium , *MAGNETITE , *IRON , *GRAPHENE , *CHROMIUM compounds - Abstract
This report presents an investigation into the use of carbon paper electrodes prepared from chitosan-adhered graphene magnetite nanoparticles for the analysis of Cr(VI). The preparation and storage of carbon paper electrodes is a simple process, and these electrodes are easier to replace than electrodes modified by more conventional methods. The electrochemical detection of Cr(VI) using square wave adsorption cathodic dissolution voltammetry (SWAdCSV) with high selectivity and sensitivity, as well as the optimum conditions for the preparation of the electrodes and the electrode parameters affecting the SWAdCSV signal, were the main points of focus of the investigation. Cr(VI) was detected linearly in the range of 4-40 μg L-1 with a detection limit of 2.84 μg L-1. The electrode output precision, calculated as %RSD, was 7.16% (n = 6), and this was the measurement used for the detection of Cr(VI) in standard and test samples with recoveries between 89% and 114%. The results were consistent with those obtained using the standard UV-Vis spectrophotometric method with a paired t-test at 95% confidence level. [ABSTRACT FROM AUTHOR]
- Published
- 2024
- Full Text
- View/download PDF
3. Corrugated Graphene Paper Reinforced Silicone Resin Composite for Efficient Interface Thermal Management.
- Author
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Wang, Bo-Wen, Zhang, Heng, He, Qing-Xia, Yu, Hui-Tao, Qin, Meng-Meng, and Feng, Wei
- Subjects
- *
THERMAL interface materials , *THERMAL resistance , *INTERFACIAL resistance , *GRAPHENE , *THERMAL conductivity , *COMPOSITE materials - Abstract
With the rapid development of high-power-density electronic devices, interface thermal resistance has become a critical barrier for effective heat management in high-performance electronic products. Therefore, there is an urgent demand for advanced thermal interface materials (TIMs) with high cross-plane thermal conductivity and excellent compressibility to withstand increasingly complex operating conditions. To achieve this aim, a promising strategy involves vertically arranging highly thermoconductive graphene on polymers. However, with the currently available methods, achieving a balance between low interfacial thermal resistance, bidirectional high thermal conductivity, and large-scale production is challenging. Herein, we prepared a graphene framework with continuous filler structures in in-plane and cross-plane directions by bonding corrugated graphene to planar graphene paper. The interface interaction between the graphene paper framework and polymer matrix was enhanced via surface functionalization to reduce the interface thermal resistance. The resulting three-dimensional thermal framework endows the polymer composite material with a cross-plane thermal conductivity of 14.4 W·m−1·K−1 and in-plane thermal conductivity of 130 W·m−1·K−1 when the thermal filler loading is 10.1 wt%, with a thermal conductivity enhancement per 1 wt% filler loading of 831%, outperforming various graphene structures as fillers. Given its high thermal conductivity, low contact thermal resistance, and low compressive modulus, the developed highly thermoconductive composite material demonstrates superior performance in TIM testing compared with TFLEX-700, an advanced commercial TIM, effectively solving the interfacial heat transfer issues in electronic systems. This novel filler structure framework also provides a solution for achieving a balance between efficient thermal management and ease of processing. [ABSTRACT FROM AUTHOR]
- Published
- 2024
- Full Text
- View/download PDF
4. A Flexible Reduced Graphene Oxide‐based Paper for Supercapattery Design: Effect of Polyindole Thin Films and Zinc Oxide Nanoparticles.
- Author
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Mollamehmetoğlu, Esra Atalay and Alanyalıoğlu, Murat
- Subjects
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ZINC oxide thin films , *ZINC oxide , *NANOPARTICLES , *GRAPHENE , *ENERGY density , *FLEXIBLE electronics - Abstract
Flexible graphene‐based paper electrodes (FGPEs) are a new class of study and the research on this electrode material has been carried out for approximately ten years. FGPEs have many advantages compared to classical solid electrodes such as being flexible, foldable, adaptable to flexible electronics, being cut, easily shaped, and effective and adjustable modification. In this work, the applicability of FGPEs modified with polyindole (PIN) thin films and zinc oxide nanoparticles (ZnO‐NPs) to energy‐storage systems as a supercapattery design is presented, and especially the limitations of ZnO‐NPs for energy‐storage applications are revealed to inform researchers working for a similar purpose. Capacitance calculations have been performed using both cyclic voltammetry (CV) and galvanostatic charge‐discharge (GCD) experiments. It was observed that the rGO/PIN paper demonstrated almost 30 times more energy‐storage capacity than that of the rGO/PIN/ZnO paper due to the electrochemical instability of ZnO‐NPs on the flexible electrode platform at the applied potential region in 1.0 M HClO4 solution. The rGO/PIN paper with a highly flexible property exhibited an energy density of 74.5 W h cm−2 and a power density of 2258 W cm−2 at a current density of 2.2 mA cm−2, revealing hopeful results for future modular and flexible approaches. [ABSTRACT FROM AUTHOR]
- Published
- 2024
- Full Text
- View/download PDF
5. Structure‐Foldable and Performance‐Tailorable PI Paper‐Based Triboelectric Nanogenerators Processed and Controlled by Laser‐Induced Graphene.
- Author
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Yang, Weixiong, Han, Mingguang, Liu, Fu, Wang, Dan, Gao, Yan, Wang, Guantao, Ding, Xilun, and Luo, Sida
- Subjects
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NANOGENERATORS , *POLYIMIDES , *CARBON-based materials , *GRAPHENE , *FRICTION materials , *OPEN-circuit voltage , *SMART structures - Abstract
Laser‐induced graphene (LIG) technology has provided a new manufacturing strategy for the rapid and scalable assembling of triboelectric nanogenerators (TENG). However, current LIG‐based TENG commonly rely on polymer films, e.g., polyimide (PI) as both friction material and carbon precursor of electrodes, which limit the structural diversity and performance escalation due to its incapability of folding and creasing. Using specialized PI paper composed of randomly distributed PI fibers to substantially enhance its foldability, this work creates a new type of TENG, which are structurally foldable and stackable, and performance tailorable. First, by systematically investigating the laser power‐regulated performance of single‐unit TENG, the open‐circuit voltage can be effectively improved. By further exploiting the folding process, multiple TENG units can be assembled together to form multi‐layered structures to continuously expand the open‐circuit voltage from 5.3 to 34.4 V cm−2, as the increase of friction units from 1 to 16. Last, by fully utilizing the unique structure and performance, representative energy‐harvesting and smart‐sensing applications are demonstrated, including a smart shoe to recognize running motions and power LEDs, a smart leaf to power a thermometer by wind, a matrix sensor to recognize writing trajectories, as well as a smart glove to recognize different objects. [ABSTRACT FROM AUTHOR]
- Published
- 2024
- Full Text
- View/download PDF
6. Flexible and electrically robust graphene-based nanocomposite paper with hierarchical microstructures for multifunctional wearable devices
- Author
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Zhen-Hua Tang, Wei-Bin Zhu, Jun-Zhang Chen, Yuan-Qing Li, Pei Huang, Kin Liao, and Shao-Yun Fu
- Subjects
Graphene ,Bamboo fibers ,Microspheres ,Pressure sensors ,Joule heating devices ,Technology ,Engineering (General). Civil engineering (General) ,TA1-2040 - Abstract
Multifunctional and flexible wearable devices play a crucial role in a wide range of applications, such as heath monitoring, intelligent skins, and human-machine interactions. Developing flexible and conductive materials for multifunctional wearable devices with low-cost and high efficiency methods are highly desirable. Here, a conductive graphene/microsphere/bamboo fiber (GMB) nanocomposite paper with hierarchical surface microstructures is successfully fabricated through a simple vacuum-assisted filtration followed by thermo-foaming process. The as-prepared microstructured GMB nanocomposite paper exhibits not only a high volume electrical conductivity of ∼45 S/m but also an excellent electrical stability (i.e., relative changes in resistance are less than 3% under stretching, folding, and compressing loadings) due to its unique structure features. With this microstructured nanocomposite paper as active sensing layer, microstructured pressure sensors with a high sensitivity (−4 kPa−1), a wide sensing range (0–5 kPa), and a rapid response time (about 140 ms) are realized. In addition, benefitting from the outstanding electrical stability and mechanical flexibility, the microstructured nanocomposite paper is further demonstrated as a low-voltage Joule heating device. The surface temperature of the microstructured nanocomposite paper rapidly reaches over 80 °C when applying a relatively low voltage of 7 V, indicating its potential in human thermotherapy and thermal management.
- Published
- 2023
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7. Optimizing graphene content in scaffolds for evenly distributed crumpled MoS2 paper wads as anodes for high-performance Li-ion batteries.
- Author
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Shabir, Abgeena, Khan, Firoz, Hor, Abbas Ali, Hashmi, S A, Julien, C M, and Islam, S S
- Subjects
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LITHIUM-ion batteries , *GRAPHENE , *ANODES , *MOLYBDENUM disulfide , *COMPOSITE structures , *GRAPHITE - Abstract
Lithium-ion batteries (LIBs) have revolutionized portable electronics, yet their conventional graphite anodes face capacity limitations. Integrating graphene and 3D molybdenum disulfide (MoS2) offers a promising solution. Ensuring a uniform distribution of 3D MoS2 nanostructures within a graphene matrix is crucial for optimizing battery performance and preventing issues like agglomeration and capacity degradation. This study focuses on synthesizing a uniformly distributed paper wad structure by optimizing a composite of reduced graphene oxide RGO@MoS2 through structural and morphological analyses. Three composites with varying graphene content were synthesized, revealing that the optimized sample containing 30 mg RGO demonstrates beneficial synergy between MoS2 and RGO. The interconnected RGO network enhances reactivity and conductivity, addressing MoS2 aggregation. Experimental results exhibit an initially superior capacity of 911 mAh g−1, retained at 851 mAh g−1 even after 100 cycles at 0.1 A g−1 current density, showcasing improved rate efficiency and long-term stability. This research underscores the pivotal role of graphene content in customizing RGO@MoS2 composites for enhanced LIB performance. [ABSTRACT FROM AUTHOR]
- Published
- 2024
- Full Text
- View/download PDF
8. Structural Stability and Disorder Level of Moderately Reduced Paper-like Graphene Oxide Investigated with Micro-Raman Analysis.
- Author
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Janulewicz, Karol Adam, Fok, Tomasz, Bartosewicz, Bartosz, Bartnik, Andrzej, Fiedorowicz, Henryk, and Wachulak, Przemysław
- Subjects
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GRAPHENE oxide , *STRUCTURAL stability , *GRAPHENE - Abstract
This paper discusses the results of the micro-Raman analysis performed on paper-like graphene oxide (GO) samples consisting of many functionalised graphene layers and annealed at moderate temperatures (≤500 °C) under vacuum conditions (p ≃ 10−4 mbar). The analysis of the standalone samples revealed that the obtained material is characterised by a noticeable disorder level but still stays below the commonly accepted threshold of high or total disorder. GO formed in a simple way showed two spectral bands above 1650 cm−1 recorded very rarely or not at all and their origin has been discussed in detail. The results also confirmed the metastable character of multilayer GO after the annealing process at moderate temperatures as the C/O ratio was kept between 2 and 3 and the spectral features were stable within the annealing temperature range. [ABSTRACT FROM AUTHOR]
- Published
- 2024
- Full Text
- View/download PDF
9. A Facile Graphene Conductive Polymer Paper Based Biosensor for Dopamine, TNF-α, and IL-6 Detection
- Author
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Md Ashiqur Rahman, Ramendra Kishor Pal, Nazmul Islam, Robert Freeman, Francois Berthiaume, Aaron Mazzeo, and Ali Ashraf
- Subjects
cancer detection ,conductive polymers ,dopamine detection ,graphene ,paper-based biosensor ,Chemical technology ,TP1-1185 - Abstract
Paper-based biosensors are a potential paradigm of sensitivity achieved via microporous spreading/microfluidics, simplicity, and affordability. In this paper, we develop decorated paper with graphene and conductive polymer (herein referred to as graphene conductive polymer paper-based sensor or GCPPS) for sensitive detection of biomolecules. Planetary mixing resulted in uniformly dispersed graphene and conductive polymer ink, which was applied to laser-cut Whatman filter paper substrates. Scanning electron microscopy and Raman spectroscopy showed strong attachment of conductive polymer-functionalized graphene to cellulose fibers. The GCPPS detected dopamine and cytokines, such as tumor necrosis factor-alpha (TNF-α), and interleukin 6 (IL-6) in the ranges of 12.5–400 µM, 0.005–50 ng/mL, and 2 pg/mL–2 µg/mL, respectively, using a minute sample volume of 2 µL. The electrodes showed lower detection limits (LODs) of 3.4 µM, 5.97 pg/mL, and 9.55 pg/mL for dopamine, TNF-α, and IL-6 respectively, which are promising for rapid and easy analysis for biomarkers detection. Additionally, these paper-based biosensors were highly selective (no serpin A1 detection with IL-6 antibody) and were able to detect IL-6 antigen in human serum with high sensitivity and hence, the portable, adaptable, point-of-care, quick, minute sample requirement offered by our fabricated biosensor is advantageous to healthcare applications.
- Published
- 2023
- Full Text
- View/download PDF
10. Structural colored water rewritable paper enabled by assembled graphene laminates/ SiO2 amorphous colloidal arrays hierarchical structure.
- Author
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Luo, Site, He, Yang, Li, Yangjie, Zhang, Bin, Gao, Wenjin, and Yu, Haihu
- Subjects
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ELECTRONIC paper , *COLLOIDAL crystals , *STRUCTURAL colors , *INK-jet printers , *GRAPHENE , *COMPOSITE structures - Abstract
Rewritable paper is of great significance for environmental and sustainable development. Specially, the water rewritable paper based on hydrochromism has aroused extensive research interesting for being clean, convenient and compatible with the current ink jet printer. Nevertheless, previously reported water rewritable paper requires complex and time-consuming fabricating process. Here, we report a facile strategy to fabricate structural colored water rewritable paper simply via two step infiltration on commercially available paper. After infiltration of graphene laminates and SiO 2 colloidal spheres in sequence, the obtained paper is integrated with assembled graphene laminates (AGLs)/amorphous colloidal arrays (ACAs) hierarchical composite structure. Owing to the advantageous micro-topography, selective separation capacity and high visible light absorption property of the underlying AGLs, SiO 2 ACAs with vivid structure color can be realized. Moreover, the hydrochomism of the hierarchical composite structure is resulted from the synergistic contribution of the hydrophilic structural color and the visible light absorption property of AGLs. Our strategy is based on the environmental-friendly structural color and convenient to realized, which offers a promising alternative to rapidly fabricate colored water rewritable paper. [Display omitted] [ABSTRACT FROM AUTHOR]
- Published
- 2023
- Full Text
- View/download PDF
11. Paper-based laser-induced graphene for sustainable and flexible microsupercapacitor applications.
- Author
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Coelho, João, Correia, Ricardo F., Silvestre, Sara, Pinheiro, Tomás, Marques, Ana C., Correia, M. Rosário P., Pinto, Joana Vaz, Fortunato, Elvira, and Martins, Rodrigo
- Subjects
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GRAPHENE , *PAPER chromatography , *BORAX , *ENERGY storage , *VOLTAGE control - Abstract
Laser-induced graphene (LIG) is as a promising material for flexible microsupercapacitors (MSCs) due to its simple and cost-effective processing. However, LIG-MSC research and production has been centered on non-sustainable polymeric substrates, such as polyimide. In this work, it is presented a cost-effective, reproducible, and robust approach for the preparation of LIG structures via a one-step laser direct writing on chromatography paper. The developed strategy relies on soaking the paper in a 0.1 M sodium tetraborate solution (borax) prior to the laser processing. Borax acts as a fire-retardant agent, thus allowing the laser processing of sensitive substrates that other way would be easily destroyed under the high-energy beam. LIG on paper exhibiting low sheet resistance (30 Ω sq−1) and improved electrode/electrolyte interface was obtained by the proposed method. When used as microsupercapacitor electrodes, this laser-induced graphene resulted in specific capacitances of 4.6 mF cm−2 (0.015 mA cm−2). Furthermore, the devices exhibit excellent cycling stability (> 10,000 cycles at 0.5 mA cm−2) and good mechanical properties. By connecting the devices in series and parallel, it was also possible to control the voltage and energy delivered by the system. Thus, paper-based LIG-MSC can be used as energy storage devices for flexible, low-cost, and portable electronics. Additionally, due to their flexible design and architecture, they can be easily adapted to other circuits and applications with different power requirements. [ABSTRACT FROM AUTHOR]
- Published
- 2023
- Full Text
- View/download PDF
12. Lab‐on‐Paper Approach in lieu of Microfluidic Paper Assisted Platform: 'ASSURED' sensing through Modified Graphene Quantum Dots.
- Author
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Agrawal, Neha, Baghel, Doli, Prasad, Dipti N., and Kohli, Ekta
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QUANTUM dots , *CRAYONS , *GRAPHENE , *FLUORESCENCE quenching , *PENETRATION mechanics , *WAXES , *SENSES - Abstract
Microfluidic based sensors are one of the emerging alternatives for bringing solutions studies on paper platforms. Microfluidic paper assisted platform was developed over here through a simple, easy, cost effective and instrument free process. The self‐same method of waxing through crayoning, was estimated thoroughly on different paper platforms. Varied parameter including type of crayoning, way of patterning, color effect, wicking rate and channel optimization was performed on paper milieus. Optimized time of baking for obtaining controlled penetration ranges from 2 min to 8 min depending on the type of paper used. Wax crayoning was preferred over oil pasteling for making hydrophobic barriers uniformly, solid as well fully penetrated within paper inner layers. Fabrication through this easy cost‐effective route allows a formation of hydrophilic reaction or sensing zone of 0.25 cm2 with sufficient reactive area. Further sensing of dopamine on paper platform was carried using paper chip adsorbed with fluorescent modified graphene quantum dots as sensing material. The patterned paper showed advantage as only few microliter (5 μl to 10 μl) range of sample volume was required for testing. Fluorescence quenching with increase of concentration was witnessed where around 25–75 μM dopamine concentration was positively tested through naked eye; which for the first time was demonstrated here via robust wax crayoning method for developing paper based biosensor. [ABSTRACT FROM AUTHOR]
- Published
- 2024
- Full Text
- View/download PDF
13. Carbon Paper Modified with Functionalized Poly(diallyldimethylammonium chloride) Graphene and Gold Phytonanoparticles as a Promising Sensing Material: Characterization and Electroanalysis of Ponceau 4R in Food Samples.
- Author
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Stozhko, Natalia Yu., Khamzina, Ekaterina I., Bukharinova, Maria A., Tarasov, Aleksey V., Kolotygina, Veronika Yu., Lakiza, Natalia V., and Kuznetcova, Ekaterina D.
- Subjects
- *
CARBON paper , *ELECTROCHEMICAL analysis , *GRAPHENE , *GOLD nanoparticles , *IMPEDANCE spectroscopy , *CHLORIDES , *ELECTROACTIVE substances - Abstract
This paper presents a novel eco-friendly sensing material based on carbon paper (CP) volumetrically modified with a composite nanomodifier that includes functionalized poly(diallyldimethylammonium chloride) graphene (PDDA-G) and phytosynthesized gold nanoparticles (phyto-AuNPs). The functionalization of graphene was justified by Fourier-transform infrared spectroscopy. The phyto-AuNPs (d = 6 nm) were prepared by "green" synthesis with the use of strawberry leaf extract. The sensing material was characterized using scanning electron microscopy, electrochemical impedance spectroscopy, and voltammetry. The research results indicated a more than double increase in the electroactive surface area; a decrease in the resistance of electron transfer on nanocomposite-modified CP, compared to bare CP. The phyto-AuNPs/PDDA-G/CP was used for the electrosensing of the synthetic dye Ponceau 4R. The oxidation signal of colorant enhanced 4-fold on phyto-AuNPs/PDDA-G/CP in comparison to CP. The effect of the quantity of nanomodifier, solution pH, potential scan rate, accumulation parameters, and differential pulse parameters on the peak current of Ponceau 4R was studied. Under optimal conditions, excellent sensory characteristics were established: LOD 0.6 nM and LR 0.001–2 μM for Ponceau 4R. High selectivity and sensitivity enable the use of the sensor for analyzing the content of Ponceau 4R in food products (soft drinks, candies, and popsicles) without additional sample preparation. [ABSTRACT FROM AUTHOR]
- Published
- 2022
- Full Text
- View/download PDF
14. Microwave Absorption Properties of Double-Layer Absorbing Material Based on Carbonyl Iron and Graphene Composites
- Author
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Shao, Zhiwei, Zhao, Qin, Gao, Xiang, Li, Fang, Filipe, Joaquim, Editorial Board Member, Ghosh, Ashish, Editorial Board Member, Prates, Raquel Oliveira, Editorial Board Member, Zhou, Lizhu, Editorial Board Member, Pan, Linqiang, editor, Zhao, Dongming, editor, Li, Lianghao, editor, and Lin, Jianqing, editor
- Published
- 2023
- Full Text
- View/download PDF
15. Effect of Graphene Content on the Mechanical Properties of PMMA Composites
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Guanhong, Sun, China Society of Automotive Engineers, Angrisani, Leopoldo, Series Editor, Arteaga, Marco, Series Editor, Panigrahi, Bijaya Ketan, Series Editor, Chakraborty, Samarjit, Series Editor, Chen, Jiming, Series Editor, Chen, Shanben, Series Editor, Chen, Tan Kay, Series Editor, Dillmann, Rüdiger, Series Editor, Duan, Haibin, Series Editor, Ferrari, Gianluigi, Series Editor, Ferre, Manuel, Series Editor, Hirche, Sandra, Series Editor, Jabbari, Faryar, Series Editor, Jia, Limin, Series Editor, Kacprzyk, Janusz, Series Editor, Khamis, Alaa, Series Editor, Kroeger, Torsten, Series Editor, Li, Yong, Series Editor, Liang, Qilian, Series Editor, Martín, Ferran, Series Editor, Ming, Tan Cher, Series Editor, Minker, Wolfgang, Series Editor, Misra, Pradeep, Series Editor, Möller, Sebastian, Series Editor, Mukhopadhyay, Subhas, Series Editor, Ning, Cun-Zheng, Series Editor, Nishida, Toyoaki, Series Editor, Oneto, Luca, Series Editor, Pascucci, Federica, Series Editor, Qin, Yong, Series Editor, Seng, Gan Woon, Series Editor, Speidel, Joachim, Series Editor, Veiga, Germano, Series Editor, Wu, Haitao, Series Editor, Zamboni, Walter, Series Editor, and Zhang, Junjie James, Series Editor
- Published
- 2023
- Full Text
- View/download PDF
16. High strength, flexible, and conductive graphene/polypropylene fiber paper fabricated via papermaking process
- Author
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Cao, Shan, Ge, Wenjiao, Yang, Yang, Huang, Quanbo, and Wang, Xiaohui
- Published
- 2022
- Full Text
- View/download PDF
17. Ciprofloxacin-, Cefazolin-, and Methicilin-Soaked Graphene Paper as an Antibacterial Medium Suppressing Cell Growth.
- Author
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Nasiłowska, Barbara, Bombalska, Aneta, Kutwin, Marta, Lange, Agata, Jaworski, Sławomir, Narojczyk, Kamila, Olkowicz, Klaudia, and Bogdanowicz, Zdzisław
- Subjects
- *
GRAPHENE , *CELL growth , *GRAPHENE oxide , *INHIBITION (Chemistry) , *PSEUDOMONAS aeruginosa , *CIPROFLOXACIN - Abstract
This paper presents the results of research on the impact of graphene paper on selected bacterial strains. Graphene oxide, from which graphene paper is made, has mainly bacteriostatic properties. Therefore, the main goal of this research was to determine the possibility of using graphene paper as a carrier of a medicinal substance. Studies of the degree of bacterial inhibition were performed on Staphylococcus aureus and Pseudomonas aeruginosa strains. Graphene paper was analyzed not only in the state of delivery but also after the incorporation of the antibiotics ciprofloxacin, cefazolin, and methicillin into its structures. In addition, Fourier-Transform Infrared Spectroscopy, contact angle, and microscopic analysis of bacteria on the surface of the examined graphene paper samples were also performed. Studies have shown that graphene paper with built-in ciprofloxacin had a bactericidal effect on the strains of Staphylococcus aureus and Pseudomonas aeruginosa. In contrast, methicillin, as well as cefazolin, deposited on graphene paper acted mainly locally. Studies have shown that graphene paper can be used as a carrier of selected medicinal substances. [ABSTRACT FROM AUTHOR]
- Published
- 2024
- Full Text
- View/download PDF
18. Fabrication of flexible and sensitive laser-patterned serpentine-structured graphene–CNT paper for strain sensor applications
- Author
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Singh, Karamvir, Gupta, Monish, and Tripathi, C. C.
- Published
- 2022
- Full Text
- View/download PDF
19. Flexible graphene/silver nanoparticles/aluminum film paper for high-performance electromagnetic interference shielding
- Author
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Xiang Li, Yifei Qu, Xiu Wang, Huiyang Bian, Weibing Wu, and Hongqi Dai
- Subjects
Aluminum film-paper ,AgNPs ,Graphene ,Electromagnetic shielding ,Materials of engineering and construction. Mechanics of materials ,TA401-492 - Abstract
Rubber and plastic are widely acted as substrates in flexible electromagnetic shielding (EMS) materials. However, these materials have several drawbacks in practical applications, such as potential environmental concerns and difficulties in degrading. In this work, a biodegradability paper-based material composed of electromagnetic wave loss layer (graphene/ silver nanoparticles (AgNPs) coating) and reflective layer (aluminum film layer) was successfully fabricated. The electromagnetic wave loss layer constructed three-dimensional (3D) electric conductive network to facilitate the timely transfer of electrons and heat energy obtained from electromagnetic waves. Meanwhile, the reflective layer received electrons and heat from the electric conductive network and make a small quantity of transmission wave back to the wave loss layer. The resulting material exhibited an ultrahigh electromagnetic interference shielding effectiveness (EMI SE) of 92.29 dB within 8–13 GHz, electrical conductivity of 4431 S/m, mechanical properties with a tensile strength of 32 MPa and elongation at break of 6.65%. Compared to the traditional EMS materials, the composite material integrated with excellent EMI SE, heat transfer performance, and weatherability, which has potential applications in microelectronics, high integrated circuits, and flexible electronic fields.
- Published
- 2022
- Full Text
- View/download PDF
20. Preparation of lignocellulose/graphene composite conductive paper
- Author
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Wang, Ruibin, Bian, Huiyang, Ji, Hairui, and Yang, Rendang
- Published
- 2018
- Full Text
- View/download PDF
21. Polymer Bulk Composites with Strong Noncovalent Interface Interactions
- Author
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Savchenko, Denys, Pashchenko, Eugen, Kukharenko, Svitlana, Kaidash, Oksana, Riabchenko, Serhii, Cavas-Martínez, Francisco, Series Editor, Chaari, Fakher, Series Editor, di Mare, Francesca, Series Editor, Gherardini, Francesco, Series Editor, Haddar, Mohamed, Series Editor, Ivanov, Vitalii, Series Editor, Kwon, Young W., Series Editor, Trojanowska, Justyna, Series Editor, Tonkonogyi, Volodymyr, editor, Oborskyi, Gennadii, editor, and Pavlenko, Ivan, editor
- Published
- 2022
- Full Text
- View/download PDF
22. Enhanced Power Density of Alcohol Biofuel Cell by Polymer‐assisted Crosslinks of 3D Graphene on Carbon Paper as the Bioanode.
- Author
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Shi, Yuhe, Li, Lin, and Zhang, Ling
- Subjects
- *
CARBON paper , *POWER density , *X-ray photoelectron spectra , *GRAPHENE , *BIOMASS energy - Abstract
Herein, we successfully construct the 3D biocompatible graphene through crosslinking 2D graphene nanosheet onto carbon fiber paper with poly(diallyldimethylammonium chloride) (PDDA) as anode of the alcohol biofuel cell. Compared with the bioanode without 3D graphene, the current density and output power of PDDA‐graphene‐ADH bioanode is increased by 23 % and 41 % at a high concentration of ethanol at pH 8.9, suggesting the stabilization role of graphene in enzyme loading. The study provides us a deep analysis on structures and performances of the bioanode incl. electrochemistry, X‐ray photoelectron spectra, and atomic force microscopy images, which is significant to develop the new methods to construct 3D porous electrodes in energy conversion device. [ABSTRACT FROM AUTHOR]
- Published
- 2022
- Full Text
- View/download PDF
23. Ab Initio Computer Modeling of a Diamond-Like 5–7 Bilayer
- Author
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Greshnyakov, Vladimir, Belenkov, Evgeny, Filipe, Joaquim, Editorial Board Member, Ghosh, Ashish, Editorial Board Member, Prates, Raquel Oliveira, Editorial Board Member, Zhou, Lizhu, Editorial Board Member, Jordan, Vladimir, editor, Tarasov, Ilya, editor, and Faerman, Vladimir, editor
- Published
- 2022
- Full Text
- View/download PDF
24. Fe3O4/functional exfoliation graphene on carbon paper nanocomposites for supercapacitor electrode
- Author
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Li, Yanfei, Yu, Jie, Chen, Shouhui, Huang, Zhenzhong, and Wang, Li
- Published
- 2018
- Full Text
- View/download PDF
25. A Facile Graphene Conductive Polymer Paper Based Biosensor for Dopamine, TNF-α, and IL-6 Detection.
- Author
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Rahman, Md Ashiqur, Pal, Ramendra Kishor, Islam, Nazmul, Freeman, Robert, Berthiaume, Francois, Mazzeo, Aaron, and Ashraf, Ali
- Subjects
- *
IMMUNOGLOBULINS , *TUMOR necrosis factors , *INTERLEUKIN-6 , *GRAPHENE , *CONDUCTING polymers , *DOPAMINE , *BIOSENSORS - Abstract
Paper-based biosensors are a potential paradigm of sensitivity achieved via microporous spreading/microfluidics, simplicity, and affordability. In this paper, we develop decorated paper with graphene and conductive polymer (herein referred to as graphene conductive polymer paper-based sensor or GCPPS) for sensitive detection of biomolecules. Planetary mixing resulted in uniformly dispersed graphene and conductive polymer ink, which was applied to laser-cut Whatman filter paper substrates. Scanning electron microscopy and Raman spectroscopy showed strong attachment of conductive polymer-functionalized graphene to cellulose fibers. The GCPPS detected dopamine and cytokines, such as tumor necrosis factor-alpha (TNF-α), and interleukin 6 (IL-6) in the ranges of 12.5–400 µM, 0.005–50 ng/mL, and 2 pg/mL–2 µg/mL, respectively, using a minute sample volume of 2 µL. The electrodes showed lower detection limits (LODs) of 3.4 µM, 5.97 pg/mL, and 9.55 pg/mL for dopamine, TNF-α, and IL-6 respectively, which are promising for rapid and easy analysis for biomarkers detection. Additionally, these paper-based biosensors were highly selective (no serpin A1 detection with IL-6 antibody) and were able to detect IL-6 antigen in human serum with high sensitivity and hence, the portable, adaptable, point-of-care, quick, minute sample requirement offered by our fabricated biosensor is advantageous to healthcare applications. [ABSTRACT FROM AUTHOR]
- Published
- 2023
- Full Text
- View/download PDF
26. Bi-MOF-Derived Carbon Wrapped Bi Nanoparticles Assembly on Flexible Graphene Paper Electrode for Electrochemical Sensing of Multiple Heavy Metal Ions.
- Author
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Hu, Min, He, Hu, Xiao, Fei, and Liu, Chen
- Subjects
- *
ELECTROCHEMICAL electrodes , *METAL ions , *GRAPHENE , *ELECTROCHEMICAL sensors , *NANOPARTICLES , *ANALYSIS of heavy metals - Abstract
The development of nanohybrid with high electrocatalytic activity is of great significance for electrochemical sensing applications. In this work, we develop a novel and facile method to prepare a high-performance flexible nanohybrid paper electrode, based on nitrogen-doped carbon (NC) wrapped Bi nanoparticles (Bi-NPs) assembly derived from Bi-MOF, which are decorated on a flexible and freestanding graphene paper (GP) electrode. The as-obtained Bi-NPs encapsulated by an NC layer are uniform, and the active sites are increased by introducing a nitrogen source while preparing Bi-MOF. Owing to the synergistic effect between the high conductivity of GP electrode and the highly efficient electrocatalytic activity of Bi-NPs, the NC wrapped Bi-NPs (Bi-NPs@NC) modified GP (Bi-NPs@NC/GP) electrode possesses high electrochemically active area, rapid electron-transfer capability, and good electrochemical stability. To demonstrate its outstanding functionality, the Bi-NPs@NC/GP electrode has been integrated into a handheld electrochemical sensor for detecting heavy metal ions. The result shows that Zn2+, Cd2+, and Pb2+ can be detected with extremely low detection limits, wide linear range, high sensitivity, as well as good selectivity. Furthermore, it demonstrates outstanding electrochemical sensing performance in the simultaneous detection of Zn2+, Cd2+, and Pb2+. Finally, the proposed electrochemical sensor has achieved excellent repeatability, reproducibility, stability, and reliability in measuring real water samples, which will have great potential in advanced applications in environmental systems. [ABSTRACT FROM AUTHOR]
- Published
- 2023
- Full Text
- View/download PDF
27. Graphene Aerogel Modified Carbon Paper as Anode for Lithium‐Ion Batteries.
- Author
-
Angelopoulou, Pinelopi, Vrettos, Katerina, Georgakilas, Vasilios, and Avgouropoulos, George
- Subjects
- *
CARBON paper , *LITHIUM-ion batteries , *GRAPHENE , *PHENYLENEDIAMINES , *CHEMICAL bonds , *ELECTRODES - Abstract
Carbon paper‐supported graphene aerogels are examined as anode electrodes for lithium‐ion batteries, employing a hydrothermal process and a freeze‐drying step. Triethylenetetramine (TETA) and o‐phenylenediamine (OPD) prove to promote graphene aerogel formation and its chemical bonding onto the surface of carbon paper. The electrochemical results demonstrate that the electrode treated with the former diamine has a remarkable rate capability with higher capacities as compared with the electrode treated with the latter diamine and better stability. [ABSTRACT FROM AUTHOR]
- Published
- 2020
- Full Text
- View/download PDF
28. Insights into electrochemical behavior in laser-scribed electrochemical paper-based analytical devices
- Author
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Nikola Tasić, Alisson Bezerra Martins, Xue Yifei, Márcio Sousa Góes, Daniel Martín-Yerga, Lanqun Mao, Thiago R.L.C. Paixão, and Luís Moreira Gonçalves
- Subjects
Cellulose substrate ,Electroanalysis ,Electrochemical simulation ,Graphene ,Nanomaterials ,Paper-based electroanalytical devices ,Industrial electrochemistry ,TP250-261 ,Chemistry ,QD1-999 - Abstract
Laser-scribed electrochemical paper-based devices (LS-ePADs) are emerging as a greener alternative to conventional carbon electrochemical sensors since their fabrication does not involve the use of chemicals and the resulting devices show good reproducibility, scalability, and interesting electrochemical properties. This work evaluates the electrochemical properties of LS-ePADs using techniques such as cyclic voltammetry and electrochemical impedance spectroscopy (EIS), together with surface characterization by Raman spectroscopy and scanning electron microscopy. The voltammetric behavior of the porous electrode can be described as diffusional to the top electrode layer. Since the porous structure could affect the mass transport, EIS was used to prove that transport resistance is not limiting the charge transfer process in the electrode response. The graphene-based material that forms the electrode surface, identified by Raman spectroscopy, allows a considerably fast electron transfer between the LS-ePADs and the ferri/ferrocyanide molecules.
- Published
- 2020
- Full Text
- View/download PDF
29. A Hierarchically Structured Graphene/Ag Nanowires Paper as Thermal Interface Material.
- Author
-
Lv, Le, Ying, Junfeng, Chen, Lu, Tao, Peidi, Sun, Liwen, Yang, Ke, Fu, Li, Yu, Jinhong, Yan, Qingwei, Dai, Wen, Jiang, Nan, and Lin, Cheng-Te
- Subjects
- *
THERMAL interface materials , *GRAPHENE , *INTEGRATING circuits , *THERMAL properties , *THERMAL conductivity , *HEAT sinks , *NANOWIRES - Abstract
With the increase in heat power density in modern integrating electronics, thermal interface materials (TIM) that can efficiently fill the gaps between the heat source and heat sinks and enhance heat dissipation are urgently needed owing to their high thermal conductivity and excellent mechanical durability. Among all the emerged TIMs, graphene-based TIMs have attracted increasing attention because of the ultrahigh intrinsic thermal conductivity of graphene nanosheets. Despite extensive efforts, developing high-performance graphene-based papers with high through-plane thermal conductivity remains challenging despite their high in-plane thermal conductivity. In this study, a novel strategy for enhancing the through-plane thermal conductivity of graphene papers by in situ depositing AgNWs on graphene sheets (IGAP) was proposed, which could boost the through-plane thermal conductivity of the graphene paper up to 7.48 W m−1 K−1 under packaging conditions. In the TIM performance test under actual and simulated operating conditions, our IGAP exhibits strongly enhanced heat dissipation performance compared to the commercial thermal pads. We envision that our IGAP as a TIM has great potential for boosting the development of next-generation integrating circuit electronics. [ABSTRACT FROM AUTHOR]
- Published
- 2023
- Full Text
- View/download PDF
30. Laser-induced graphene from paper for non-enzymatic uric acid electrochemical sensing in urine
- Author
-
Bohdan Kulyk, Sónia O. Pereira, António J.S. Fernandes, Elvira Fortunato, Florinda M. Costa, Nuno F. Santos, CENIMAT-i3N - Centro de Investigação de Materiais (Lab. Associado I3N), DCM - Departamento de Ciência dos Materiais, and UNINOVA-Instituto de Desenvolvimento de Novas Tecnologias
- Subjects
Flexible electronics ,Chemistry(all) ,Materials Science(all) ,SDG 3 - Good Health and Well-being ,Electrochemical biosensors ,Paper-LIG ,SDG 13 - Climate Action ,General Materials Science ,Human urine ,General Chemistry ,Graphene ,Uric acid - Abstract
This work was developed within the scope of project i3N (LA/P/0037/2020. I.P. N. F. Santos thanks i3N for the BPD Grant BPD/UI96/5177/2020. S. O. Pereira thanks i3N for the BPD Grant BPD/UI96/5808/2017. The authors also thank Jonas Deuermeier for the XPS measurements. Publisher Copyright: © 2022 Elsevier Ltd Laser-induced graphene from paper (paper-LIG) was applied in non-enzymatic electrochemical sensing of uric acid (UA) in human urine. Paper-LIG was formed by CO2 laser modification of paper into a 3D graphene arrangement. Kinetic analysis of paper-LIG electrodes returned effective heterogeneous electron transfer standard rate constants of 1.4 × 10−3 cm s−1 and 7.8 × 10−4 cm s−1 for [Ru(NH3)6]2+/3+ and [Fe(CN)6]4−/3− redox probes, respectively. These electrodes were able to detect and quantify uric acid in PBS within the 10–300 μM range at pH between 5.6 and 7.4. At pH 7.4, a linear response (R2 = 0.999) from 10 to 250 μM was achieved, with a limit of detection of 3.97 μM and a sensitivity of 0.363 μA cm−2 μM−1. Paper-LIG electrodes denoted adequate selectivity in synthetic urine as well as in ascorbic acid (AA) and dopamine (DA)-containing electrolytes. Determination of urinary UA content in human samples returned a concentration of c.a. 1.8–1.9 mM, within the range for healthy individuals. Recoveries of samples spiked with 50 and 100 μM UA were 100.6% and 95.4%, respectively, with satisfactory reproducibility and stability. These cheap, lightweight, flexible, and eco-friendly paper-LIG biosensors for non-enzymatic quantification of UA in human urine pave the way to widespread application in the detection of other important biomarkers. publishersversion published
- Published
- 2022
31. Multilayer graphene in situ formed in carbonized waste paper with the synergism of nickel and sodium.
- Author
-
Cong, Yao, Jin, Qiaoran, Huang, Qi, and Xu, Zijie
- Subjects
- *
WASTE paper , *AMORPHOUS carbon , *GRAPHENE , *NICKEL , *METAL crystals , *GRAPHITE - Abstract
Multilayer graphene (MLG) is in situ formed in a matrix of amorphous carbon prepared from carbonized waste paper at 750 °C. The resulting samples are systematically characterized by morphology, spectroscopy, diffractometry, nitrogen adsorption–desorption and electrochemistry. The carbon structure with six layered graphene can be formed in a matrix of amorphous carbon at such a low temperature. The resulting sample displays a specific surface area of 862 m2 g−1, a meso-pore volume of 0.55 cm3 g−1 and a capacitance of 214 F g−1, which are correspondingly 2.16, 2.29 and 2.14 times higher than those of the sample prepared directly from carbonized waste paper. Although the sample displays the basic characteristics of amorphous carbon, MLG is mostly found to be formed around the regular nickel crystal face in the amorphous carbon matrix. It is also found that the formation of MLG can be affected by the coexistence of nickel crystals and sodium metal. The optimized porous structural characteristics, including the specific surface area, and the micro- and meso-pore volumes, result from the rearrangement of graphite microcrystallites, giving an improved capacitive performance. [ABSTRACT FROM AUTHOR]
- Published
- 2021
- Full Text
- View/download PDF
32. Impedance Spectroscopy Characterization of a Graphene-Based Solar Cell with Improved Contacts
- Author
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Matacena, Ilaria, Zocco, Daniele, Guerriero, Pierluigi, Lisi, Nicola, Lancellotti, Laura, Bobeico, Eugenia, Veneri, Paola Delli, Daliento, Santolo, Angrisani, Leopoldo, Series Editor, Arteaga, Marco, Series Editor, Panigrahi, Bijaya Ketan, Series Editor, Chakraborty, Samarjit, Series Editor, Chen, Jiming, Series Editor, Chen, Shanben, Series Editor, Chen, Tan Kay, Series Editor, Dillmann, Rüdiger, Series Editor, Duan, Haibin, Series Editor, Ferrari, Gianluigi, Series Editor, Ferre, Manuel, Series Editor, Hirche, Sandra, Series Editor, Jabbari, Faryar, Series Editor, Jia, Limin, Series Editor, Kacprzyk, Janusz, Series Editor, Khamis, Alaa, Series Editor, Kroeger, Torsten, Series Editor, Liang, Qilian, Series Editor, Martín, Ferran, Series Editor, Ming, Tan Cher, Series Editor, Minker, Wolfgang, Series Editor, Misra, Pradeep, Series Editor, Möller, Sebastian, Series Editor, Mukhopadhyay, Subhas, Series Editor, Ning, Cun-Zheng, Series Editor, Nishida, Toyoaki, Series Editor, Pascucci, Federica, Series Editor, Qin, Yong, Series Editor, Seng, Gan Woon, Series Editor, Speidel, Joachim, Series Editor, Veiga, Germano, Series Editor, Wu, Haitao, Series Editor, Zhang, Junjie James, Series Editor, Zamboni, Walter, editor, and Petrone, Giovanni, editor
- Published
- 2020
- Full Text
- View/download PDF
33. An Impedance-Based Life-Monitoring Technique for a Graphene Water Filter
- Author
-
Bellucci, Stefano, Cataldo, Antonino, Ferrigno, Luigi, Giovannetti, Samuele, Maffucci, Antonio, Angrisani, Leopoldo, Series Editor, Arteaga, Marco, Series Editor, Panigrahi, Bijaya Ketan, Series Editor, Chakraborty, Samarjit, Series Editor, Chen, Jiming, Series Editor, Chen, Shanben, Series Editor, Chen, Tan Kay, Series Editor, Dillmann, Rüdiger, Series Editor, Duan, Haibin, Series Editor, Ferrari, Gianluigi, Series Editor, Ferre, Manuel, Series Editor, Hirche, Sandra, Series Editor, Jabbari, Faryar, Series Editor, Jia, Limin, Series Editor, Kacprzyk, Janusz, Series Editor, Khamis, Alaa, Series Editor, Kroeger, Torsten, Series Editor, Liang, Qilian, Series Editor, Martín, Ferran, Series Editor, Ming, Tan Cher, Series Editor, Minker, Wolfgang, Series Editor, Misra, Pradeep, Series Editor, Möller, Sebastian, Series Editor, Mukhopadhyay, Subhas, Series Editor, Ning, Cun-Zheng, Series Editor, Nishida, Toyoaki, Series Editor, Pascucci, Federica, Series Editor, Qin, Yong, Series Editor, Seng, Gan Woon, Series Editor, Speidel, Joachim, Series Editor, Veiga, Germano, Series Editor, Wu, Haitao, Series Editor, Zhang, Junjie James, Series Editor, Zamboni, Walter, editor, and Petrone, Giovanni, editor
- Published
- 2020
- Full Text
- View/download PDF
34. Atomistic Modelling and Simulation of Transmission Electron Microscopy Images: Application to Intrinsic Defects of Graphene
- Author
-
Guedj, Cyril, Jaillet, Léonard, Rousse, François, Redon, Stéphane, Kacprzyk, Janusz, Series Editor, Pal, Nikhil R., Advisory Editor, Bello Perez, Rafael, Advisory Editor, Corchado, Emilio S., Advisory Editor, Hagras, Hani, Advisory Editor, Kóczy, László T., Advisory Editor, Kreinovich, Vladik, Advisory Editor, Lin, Chin-Teng, Advisory Editor, Lu, Jie, Advisory Editor, Melin, Patricia, Advisory Editor, Nedjah, Nadia, Advisory Editor, Nguyen, Ngoc Thanh, Advisory Editor, Wang, Jun, Advisory Editor, Obaidat, Mohammad S., editor, Ören, Tuncer, editor, and Rango, Floriano De, editor
- Published
- 2020
- Full Text
- View/download PDF
35. Graphene Based Printable Conductive Wax for Low‐Power Thermal Actuation in Microfluidic Paper‐Based Analytical Devices.
- Author
-
Brito‐Pereira, Ricardo, Ribeiro, Clarisse, Costa, Pedro, Correia, Vitor, Cardoso, Vanessa F., and Lanceros‐Mendez, Senentxu
- Subjects
- *
GRAPHENE , *MICROFLUIDIC devices , *PROOF of concept , *TEMPERATURE control , *PRINTMAKING , *SYSTEMS design - Abstract
Wax printing is one of the most widely used techniques to print hydrophobic barriers on hydrophilic microfluidic paper‐based analytical devices (µPADs) based on its simplicity, speed, and low cost, allowing large‐scale production. Nonetheless, its function is just passive, without any action on fluids. Thus, this work proposes multifunctional hydrophobic composites based on conductive graphene nanoplatelets (GNPs) integrated into the wax matrix to allow a dual role of barrier and heater, the latter being required in a large variety of temperature‐sensitive reactions and microfluidic applications. The effect of GNP weight content on the physicochemical properties of the wax, printed wax, and generated heating are evaluated. Wax prints with mechanical stability and adequate impregnation through the paper are obtained after post‐thermal curing. With respect to the functional response, controlled temperatures ranging from room temperature to ≈107 °C can be achieved after just 10 s. Two proofs of concept are presented involving thermochromic inks, specific printed systems designs, and low‐power batteries. The benefits of µPADs allied to the increased functionality and performance of the developed waxes, hold great promise to meet the requirements for a next generation of versatile, effective, and accurate µPADs for an increasing number of applications. [ABSTRACT FROM AUTHOR]
- Published
- 2023
- Full Text
- View/download PDF
36. Laser induced freestanding graphene papers for multifunctional composites
- Author
-
International Conference on Composite Materials (22nd : 2019 : Melboune, VIC.), Wang, Yanan, and Luo, Sida
- Published
- 2019
37. Intercalated oligomer doubles plasticity for strong and conductive graphene papers and composites.
- Author
-
Shen, Kai, Li, Peng, Lin, Jiahao, Wang, Ziqiu, Cai, Gangfeng, Ming, Xin, Liu, Yingjun, Gao, Chao, and Xu, Zhen
- Subjects
- *
WRINKLE patterns , *GRAPHENE , *PROCESS capability , *GRAPHENE oxide , *YOUNG'S modulus , *ELECTROMAGNETIC interference - Abstract
Disordered wrinkles inevitably appear in the fluid assembly process of graphene and heavily depress performances of assembled graphene papers. Achieving high plasticity enables the post modulation to rearrange wrinkles by stretching. Here, we obtain an over 100% improved plasticity by intercalating oligomer into graphene oxide (GO) laminates and fabricate strong, stiff and conductive graphene papers (GPs) via post stretching. The intercalated oligomer activates the mobilization of GO sheets and achieves high plasticity of solid GO papers. The improved plasticity allows high stretching ratio and the post-stretched GP features regular orientation (0.95) of graphene sheets and aligned fine wrinkles. The crystalline GPs have a high tensile strength up to 1.3 GPa, Young's modulus of 92.9 GPa and highly electrical conductivity (1.05 × 105 S m−1). The greatly improved plasticity by oligomer extends the processing capability of graphene materials and the strong and conductive GP can be assembled in high performance nanocomposites with excellent electromagnetic interference shielding effectiveness (EMI SE). [Display omitted] • Intercalating oligomer greatly enhances plasticity of graphene oxide laminates for the improved interlayer friction. • The greatly enhanced plasticity enables to efficiently eliminate disordered wrinkles of assembled graphene sheets. • The crystalline graphene paper (GP) exhibits superior mechanical and electrical properties. • The (GP-based) laminated composite shows high tensile strength and electromagnetic interference shielding effectiveness. [ABSTRACT FROM AUTHOR]
- Published
- 2023
- Full Text
- View/download PDF
38. Paper-Based Humidity Sensors as Promising Flexible Devices, State of the Art, Part 2: Humidity-Sensor Performances.
- Author
-
Korotcenkov, Ghenadii, Simonenko, Nikolay P., Simonenko, Elizaveta P., Sysoev, Victor V., and Brinzari, Vladimir
- Subjects
HUMIDITY ,DETECTORS ,RADIO frequency identification systems ,GRAPHENE - Abstract
This review article covers all types of paper-based humidity sensor, such as capacitive, resistive, impedance, fiber-optic, mass-sensitive, microwave, and RFID (radio-frequency identification) humidity sensors. The parameters of these sensors and the materials involved in their research and development, such as carbon nanotubes, graphene, semiconductors, and polymers, are comprehensively detailed, with a special focus on the advantages/disadvantages from an application perspective. Numerous technological/design approaches to the optimization of the performances of the sensors are considered, along with some non-conventional approaches. The review ends with a detailed analysis of the current problems encountered in the development of paper-based humidity sensors, supported by some solutions. [ABSTRACT FROM AUTHOR]
- Published
- 2023
- Full Text
- View/download PDF
39. H2O2 biosensor based on horseradish peroxidase immobilized onto the zinc sulphide–graphene–chitosan modified carbon paper electrode
- Author
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Suganthi, G, Ramanathan, Giriprasath, Arockiadoss, T, and Sivagnanam, Uma Tiruchirapalli
- Published
- 2021
- Full Text
- View/download PDF
40. An Electroactive and Self‐Assembling Bio‐Ink, based on Protein‐Stabilized Nanoclusters and Graphene, for the Manufacture of Fully Inkjet‐Printed Paper‐Based Analytical Devices
- Author
-
Alessandro Silvestri, Silvia Vázquez‐Díaz, Giuseppe Misia, Fabrizio Poletti, Rocío López‐Domene, Valeri Pavlov, Chiara Zanardi, Aitziber L. Cortajarena, and Maurizio Prato
- Subjects
Biomaterials ,engineered proteins ,inkjet printing ,water-based inks ,electrochemical paper-based analytical devices ,graphene ,biosensors ,electrocatalysis ,Settore CHIM/01 - Chimica Analitica ,General Materials Science ,General Chemistry ,Biotechnology - Published
- 2023
41. One-Step Fabrication of Paper-Based Inkjet-Printed Graphene for Breath Monitor Sensors.
- Author
-
Lim, Wei Yin, Goh, Choon-Hian, Yap, Keenan Zhihong, and Ramakrishnan, Narayanan
- Subjects
CAPACITIVE sensors ,WEARABLE technology ,HOME care services ,GRAPHENE ,DETECTORS ,HUMIDITY ,STANDARD deviations - Abstract
Irregularities in breathing patterns can be detected using breath monitor sensors, and this help clinicians to predict health disorders ranging from sleep disorders to heart failures. Variations in humidity during the inhalation and exhalation of breath have been utilized as a marker to detect breath patterns, and graphene-based devices are the favored sensing media for relative humidity (RH). In general, most graphene-based RH sensors have been used to explore resistance change as a measurement parameter to calibrate against the RH value, and they are prone to noise interference. Here, we fabricated RH sensors using graphene ink as a sensing medium and printed them in the shape of interdigital electrodes on glossy paper using an office inkjet printer. Further, we investigated the capacitance change in the sensor for the RH changes in the range of 10–70%. It exhibited excellent sensitivity with 0.03 pF/% RH, good stability, and high intraday and interday repeatability, with relative standard deviations of 1.2% and 2.2%, respectively. Finally, the sensor was embedded into a face mask and interfaced with a microcontroller, and capacitance change was measured under three different breathing situations: normal breathing, deep breathing, and coughing. The result show that the dominant frequency for normal breath is 0.22 Hz, for deep breath, it is 0.11 Hz, and there was no significant dominant cough frequency due to persistent coughing and inconsistent patterns. Moreover, the sensor exhibited a short response and recovery time (<5 s) during inhalation and exhalation. Thus, the proposed paper-based RH sensor is promising wearable and disposable healthcare technology for clinical and home care health applications. [ABSTRACT FROM AUTHOR]
- Published
- 2023
- Full Text
- View/download PDF
42. Development of graphene-based sensors on paper substrate for the measurement of pH value of analyte
- Author
-
Lee, Chia-Yi, Lei, Kin Fong, Tsai, Shiao-Wen, and Tsang, Ngan-Ming
- Published
- 2016
- Full Text
- View/download PDF
43. Synergistic impact of graphene and carbon nanotubes on waste paper for hybrid nanocomposite substrates
- Author
-
Damnalı, Osman F. and Eskizeybek, Volkan
- Published
- 2019
- Full Text
- View/download PDF
44. Effect of Temperature on the Fracture Strength of Perfect and Defective MonoLayered Graphene
- Author
-
Gupta, Kritesh Kumar, Dey, Sudip, Davim, J. Paulo, Series Editor, Narayanan, R. Ganesh, editor, Joshi, Shrikrishna N., editor, and Dixit, Uday Shanker, editor
- Published
- 2019
- Full Text
- View/download PDF
45. In-situ joule heating-triggered nanopores generation in laser-induced graphene papers for capacitive enhancement
- Author
-
Fu Liu, Guantao Wang, Meihong He, Yanan Wang, Yuxiang Zhu, and Sida Luo
- Subjects
Fabrication ,Materials science ,business.industry ,Graphene ,Capacitive sensing ,General Chemistry ,Capacitance ,law.invention ,Nanopore ,Amorphous carbon ,law ,Optoelectronics ,General Materials Science ,business ,Joule heating ,Graphene oxide paper - Abstract
Laser-induced graphene (LIG) technology featuring low-cost, high-efficiency and scalability has presented great advantages in micro-supercapacitors (MSCs) fabrication. However, the limited capacitance of LIG based MSCs is still hindering their further development. Herein, we introduce joule heating as a critical in-situ treatment merged with the assembly of laser-induced graphene paper based MSCs (LIGP-MSCs) toward capacitive enhancement. By increasing heating-treatment temperature from ∼20 to 500 °C, the number of nanopores in LIGP continuously increases, attributed to the gradual decomposition of amorphous carbon components. The resulting joule-heated LIGP (J-LIGP) with improved specific surface area (160.97–533.49 m2/g) and pore volume (0.179–0.553 cm3/g) as well as superhydrophilic surface is highly suitable to be employed as J-LIGP-MSCs microelectrodes. By investigating process dependent performance, the J-LIGP-MSCs heated at 500 °C for 60 min delivers a significantly improved specific areal capacitance (CA) of 13.71 mF/cm2 at 10 mV/s, which is approximately six-fold higher than that of unheated LIGP-MSCs. By further exploring and optimizing the process efficiency, J-LIGP-MSCs with a CA of 12.61 mF/cm2 has been achieved by 550 °C heating for only 5 min. Along with superior mechanical flexibility, cyclability and structural modularity, the proposed in-situ joule heating treatment is finally proved to be a universal approach for consistently enhancing the CA of LIG based MSCs processed under various chemical modifications.
- Published
- 2022
46. A One-step Hydrothermal Method of Nitrogen-doped Graphene Quantum Dots Decorated Graphene for Fabrication of Paper-based Fluorescent Composite
- Author
-
Yu Bian, Beihai He, and Junrong Li
- Subjects
Nitrogen-doped graphene quantum dots ,Cellulose ,Composite paper ,Graphene ,Fluorescence ,Biotechnology ,TP248.13-248.65 - Abstract
A facile approach for producing fluorescent composite paper containing nitrogen-doped graphene quantum dots (N-GQDs) and graphene on the surface of the modified fibers was implemented from the exfoliation of graphite oxide (GO) using a one-step hydrothermal method. The properties of the composite paper were characterized by X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), scanning electron microscopy (SEM), transmission electron microscopy (TEM), ultraviolet visible spectroscopy (UV), photoluminescence spectroscopy (PL), and confocal laser scanning microscopy (CLSM). The results indicated that the GO was reduced to graphene sheets, and the N-GQDs nanoparticles were deposited on the surface of these sheets. The composite paper remained undamaged, with a three-dimensional structure and smooth fibers during the hydrothermal process, and the average particle size of N-GQDs was less than 10 nm. Photoluminescence measurements showed that the composite paper had a strong ultraviolet absorption in the range of 200 to 340 nm, and the band edge emission occurred at 475 nm. The CLSM image of composite paper exhibited a well-defined excitonic emission feature with an excitation wavelength of 405 nm.
- Published
- 2016
- Full Text
- View/download PDF
47. Heterocyclic aramid nanoparticle-assisted graphene exfoliation for fabrication of pristine graphene-based composite paper
- Author
-
Mo, Yao, Liu, Qi, Fan, Jinchen, Shi, Penghui, Min, Yulin, and Xu, Qunjie
- Published
- 2015
- Full Text
- View/download PDF
48. High strength, flexible, and conductive graphene/polypropylene fiber paper fabricated via papermaking process
- Author
-
Quanbo Huang, Wenjiao Ge, Shan Cao, Yang Yang, and Xiaohui Wang
- Subjects
Polypropylene ,Materials science ,Polymers and Plastics ,Graphene ,Materials Science (miscellaneous) ,Papermaking ,Composite number ,Conductivity ,law.invention ,chemistry.chemical_compound ,Synthetic fiber ,chemistry ,law ,Materials Chemistry ,Ceramics and Composites ,Fiber ,Composite material ,Graphene oxide paper - Abstract
Graphene paper with good mechanical strength, flexibility, and high conductivity is an emerging functional material for wide applications, but its feasible and scalable preparation remains a challenge. Herein, a high strength, flexible, and conductive graphene/polypropylene (PP) fiber paper was prepared by a traditional papermaking process. In the composite paper, graphene nanosheets were well stabilized on the PP fibers forming a stable three-dimensional conductive interleaved network. Chitosan was found able to build a polar active interface on PP fibers and graphene nanosheets, which can not only promote PP fiber dispersion in water yielding a uniform pulp, but also favor the retention of graphene in the composite paper. As a result, the composite paper presents high strength (15.32 MPa), good conductivity (11,995 S/m), shielding effectiveness (31.1 dB), water resistance, fungi-proof, and thermal conductivity (10.17 W m−1 k−1) properties. This work demonstrates the feasibility of large-scale preparation of graphene composite paper with commercial synthetic fibers through a traditional papermaking process, and expands the potential industrial application of graphene materials. Graphene/chitosan co-aggregates were absorbed on the surface of graphene/chitosan/PP fiber under the electrostatic interaction of CPAM to form graphene/PP fiber.
- Published
- 2021
49. A Graphene-PEDOT:PSS Modified Paper-Based Aptasensor for Electrochemical Impedance Spectroscopy Detection of Tumor Marker
- Author
-
Yi-Kuang Yen, Chen-Hsiang Chao, and Ya-Shin Yeh
- Subjects
electrochemical impedance spectroscopy ,carcinoembryonic antigen ,paper-based device ,graphene ,conductive polymer ,aptamer ,Chemical technology ,TP1-1185 - Abstract
A graphene and poly (3,4-ethylenedioxythiophene):poly(styrenesulfonate) (PEDOT:PSS) modified conductive paper-based electrochemical impedance spectroscopy (EIS) aptasensor has been successfully fabricated by a simple and continuous coating process. A graphene/PEDOT:PSS modified paper electrode forms the nanocomposite providing a conductive and sensitive substrate for further aptamer functionalization of the biosensor. This low-cost paper-based aptasensor exhibits its sensitivity to carcinoembryonic antigens (CEA) in standard buffer solutions and human serum samples in a linear range of 0.77−14 ng·mL−1. The limit of detection (LOD) is found to be 0.45 ng·mL−1 and 1.06 ng·mL−1 for CEA in both samples, separately. This aptamer-based sensing device was also evaluated and received a good correlation with the immunoassay detection method. The proposed paper-based aptasensor has demonstrated its potential as a rapid simple point-of-care analytical platform for early cancer diagnosis in less developed areas where manufacturing facilities, analytical instruments, and trained specialists are limited.
- Published
- 2020
- Full Text
- View/download PDF
50. Flexible Graphene Paper Modified Using Pt&Pd Alloy Nanoparticles Decorated Nanoporous Gold Support for the Electrochemical Sensing of Small Molecular Biomarkers.
- Author
-
Sun, Encheng, Gu, Zhenqi, Li, Haoran, Liu, Xiao, Li, Yuan, and Xiao, Fei
- Subjects
PLATINUM nanoparticles ,NANOPARTICLES ,GRAPHENE ,BIOMARKERS ,GOLD ,BODY fluids - Abstract
The exploration into nanomaterial-based nonenzymatic biosensors with superb performance in terms of good sensitivity and anti-interference ability in disease marker monitoring has always attained undoubted priority in sensing systems. In this work, we report the design and synthesis of a highly active nanocatalyst, i.e., palladium and platinum nanoparticles (Pt&Pd-NPs) decorated ultrathin nanoporous gold (NPG) film, which is modified on a homemade graphene paper (GP) to develop a high-performance freestanding and flexible nanohybrid electrode. Owing to the structural characteristics the robust GP electrode substrate, and high electrochemically catalytic activities and durability of the permeable NPG support and ultrafine and high-density Pt&Pd-NPs on it, the resultant Pt&Pd-NPs–NPG/GP electrode exhibits excellent sensing performance of low detection limitation, high sensitivity and anti-interference capability, good reproducibility and long-term stability for the detection of small molecular biomarkers hydrogen peroxide (H
2 O2 ) and glucose (Glu), and has been applied to the monitoring of H2 O2 in different types of live cells and Glu in body fluids such as urine and fingertip blood, which is of great significance for the clinical diagnosis and prognosis in point-of-care testing. [ABSTRACT FROM AUTHOR]- Published
- 2024
- Full Text
- View/download PDF
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