1. Peroxidase-Like Activity of Silver Nanoparticles Loaded Filter Paper and its Potential Application for Sensing.
- Author
-
Alula, Melisew Tadele and Feke, Kuda
- Subjects
- *
FILTER paper , *SERS spectroscopy , *SILVER nanoparticles , *SCANNING electron microscopy , *NANOPARTICLES analysis , *CHEMICAL reduction , *CATALYTIC activity - Abstract
Nanozymes are nanomaterials that possess intrinsic enzyme mimicking activity. In this study, the application of silver nanoparticles coated filter paper (AgNPs/FP) that exhibits a peroxidase-like catalytic activity as a potential sensor is reported. A simple chemical reduction method was used to produce AgNPs/FP. The formation of the particles on filter paper were characterized using scanning electron microscopy (SEM), X-ray diffraction (XRD), and surface-enhanced Raman spectroscopy (SERS). In the presence of hydrogen peroxide, AgNPs/FP oxidized the colorless o-phenylenediamine (OPD) and 3,3′,5,5′-tetramethylbenzidine (TMB) solutions to a yellow colored 2,3-diaminophenazine (DAP) and deep blue colored oxidized TMB (oxTMB), respectively. In the presence of thiocyanate, however, the peroxidase-like activity was inhibited in a concentration dependent manner. This makes the AgNPs/FP a promising catalyst and employed for colorimetric detection of thiocyanate via inhibition of the peroxidase-like activity. The application can be further extended to other environmentally and biologically important analytes. [ABSTRACT FROM AUTHOR]
- Published
- 2023
- Full Text
- View/download PDF