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This work describes a novel technique for the measurement of inorganic arsenic in water by generating arsine gas and detecting the conductivity of moving protons, H+ (aqueous or aq), produced by the reaction: Ag+ (aq) + AsH3 (gas, g) → AgAsH2 (solid, s) + H+ (aq). The detection is based on an electrochemical gradient of protons in a confined porous substrate (filter paper) and measures the change in the conductance due to the higher mobility of H+ compared to other ions. The conductance was measured with a pair of silver electrodes attached to opposite sides of the substrate with a bipolar pulse conductance technique. The method is established in theory and in practice. The theoretical equation for conductance change shows that a constant increase in conductance is directly proportional to the As(total) concentration. The method is validated with a standard reference material and applied to the measurement of the groundwater sample. [ABSTRACT FROM AUTHOR]

Although the Paralympic Games have been around for over 60 years, women remain underrepresented in almost all aspects of the Paralympic Movement. It has been suggested that a way to increase women's involvement is through the implementation of mixed-gender events. On paper, this approach makes sense. However, when it comes to the implementation of mixed-gender opportunities for women, it is less clear how effective these events are in increasing participation by women in Para sport. Through document analysis and interviews with athletes and organizers of mixed-gender Paralympic sport, we explore the various strategies that four mixed-gender sports have used to address the issue of gender parity. Using critical feminist theories, we illustrate how larger social, political, and cultural ideas about gender influence women's experiences within these events and discuss the potential of using mixed-gender initiatives to address gender parity within the Paralympic Movement. [ABSTRACT FROM AUTHOR]

To develop special insulating paper is of great significance to promote the service life of transformers. Using molecular simulation to guide the development of special insulating paper can greatly reduce the trial-and-error rate and waste of resources in traditional experiments. The effect of different types of polysilsesquioxane (POSS) on cellulose insulating paper was investigated by using molecular simulation. This paper investigated the thermal stability and mechanical properties and electrical characteristics of caged POSS, semi-caged POSS, and ladder-like POSS doped cellulose insulating paper. The results show that POSS with all types can enhance the performance of cellulose insulating paper, and ladder-like POSS possess the best modification effect. The glass transition temperature was increased by 58 K, and the bulk modulus, shear modulus, and elastic modulus of cellulose insulating paper doped with ladder-like POSS can improve up to 27.07%, 45.67%, and 41.28%, respectively. Meanwhile, the dielectric properties of ladder-like POSS modified insulating paper are also significantly improved. The findings of this paper propose a method for the preparation of ladder-like POSS modified insulating paper, which provides theoretical guidance for the experimental preparation of special insulating paper. [ABSTRACT FROM AUTHOR]

Treatment of cryptococcal meningitis relies primarily on flucytosine (5FC), which is also used to treat candidiasis and infections caused by Cryptococcus neoformans. High dosages of this drug, despite its therapeutic properties, may cause hazardous side effects such as bone marrow suppression, hepatotoxicity, and gastrointestinal toxicity. The detection of trace amounts of 5FC medication may aid in tracking the treatment's efficacy and mitigating unwanted effects. Surface-enhanced Raman spectroscopy (SERS) is a rapid, reliable, and precise approach for detecting extremely low amounts of biological and chemical compounds. A filter paper-based SERS biosensor coated with silver nanoparticles (AgNPs) were employed to detect the 5FC drug. The AgNPs fabricated via the chemical reduction method were characterized by FE-SEM, TEM, XRD, AFM, and UV-Vis spectroscopy. Plasmonic active sites were made by coating the filter paper substrate with AgNPs to detect the 5FC drug's molecular vibrations. As the 5FC drug was coated onto the filter paper substrate, the AgNPs interacted with it, allowing for the detection of very low concentrations of the drug. The SERS filter paper substrate could detect concentrations of 5FC as low as 10−10 M. The Raman spectra and peak signals obtained experimentally were also simulated and validated using the density functional theory (DFT) approach. Six sets of measurements were taken, and the average RSD was obtained to be 4.62%. The experimentally measured enhancement factor for recognizing molecular vibrations of the 5FC was 9.065 × 107, and it was numerically estimated as 10.044 × 107. Therefore, the fabricated SERS-based filter paper substrate is useful for drug monitoring since they can detect even trace amounts of the targeted drug. [ABSTRACT FROM AUTHOR]

This study investigated converting abundant paper mill waste, de‐inked paper sludge (DPS), into value‐added medium‐density fiberboard (MDF) panels. The objective was to repurpose this solid waste into a valuable material that aligns with the principles of a circular economy. Previous research has examined the addition of paper sludge to wood composites, but there is limited information on the specific incorporation of DPS into MDF production. This investigation offers new insights into this application. MDF panels were manufactured using hardwood fibers, with varying levels of urea‐formaldehyde resin (10% and 12% by weight) and different loadings of DPS (ranging from 0% to 50% by weight). X‐ray diffraction analysis revealed the presence of defective DPS fiber crystals. Contact angle measurements confirmed that DPS had poor wettability, corresponding to increased water absorption. As more DPS was incorporated, the mechanical properties of the panels progressively weakened due to defective fibers and poor adhesion between the fibers and the matrix. This was evident in scanning electron microscopy micrographs, which showed an escalation in interfacial flaws. Increasing the resin dosage noticeably improved the internal bond strength and reduced moisture uptake across all levels of DPS. However, at a DPS loading of 50%, the properties of the panels deteriorated by 36%–57% compared to the control MDF. Additionally, thickness swelling and water absorption increased significantly with higher DPS content, primarily due to the hydrophilic nature of the fibers. Based on optimization, it was determined that a DPS loading of 20% with a resin content of 12% provided the best balance between performance, waste utilization, cost, and moisture resistance. The reuse of abundant paper sludge supports the goals of a circular economy. However, strategies are required to tailor the processing methods and enable higher levels of recycled material without excessively compromising the key attributes of the product. Further research should focus on enhancing the quality of DPS and its compatibility with wood fibers and resin to enhance the performance of the composite material. Highlights: DPS from recycled paper mill assessed for MDF production with wood fibers and resinIncreasing DPS loading caused reductions in strength and adhesion of panelsWater absorption and thickness swelling markedly rose with more DPS additionIt was attributed to hydrophilic fibers and disrupted fiber‐matrix bondingOptimal formulation was 20% DPS loading and 12% resin content, balancing performance, waste utilization, and cost. [ABSTRACT FROM AUTHOR]

The filter paper (FP) method, a cost-effective, versatile, and convenient approach, has found extensive application in analyzing fine-grained soils, enabling the successful measurement of a broad spectrum of total and matric suctions. However, using the FP method in sand with a limited range of suction profiles has been notably underrepresented in the existing literature. Therefore, this study investigated the applicability of the contact FP method in establishing soil water retention curves (SWRCs) using five distinct FP calibration curves for 10 poorly graded sands. Among these calibration curves, the one presented by Chandler yielded the highest suction values, which were followed by those of ASTM. Furthermore, the FP results were subjected to fitting with a mathmatical model, which led to the observation that the overall trends in the obtained SWRCs displayed smooth sigmoidal shapes, resulting in a complete and coherent SWRCs. The SWRC results of five sand samples were assessed through validation against the hanging column technique (HCT) results, indicating a high degree of concordance and affirming the suitability of the FP method for sands characterized by a limited suction profile. Notably, the entire range of suction values fell within the 0.01–20 kPa range based on the calibration curves presented by Chandler and ASTM for all the examined sand samples, except sands 9 and 10. Furthermore, the suction values were unobtainable using the two aforementioned calibration curves within the ranges of 0.01–1.47 kPa and 0.01–0.172 kPa. [ABSTRACT FROM AUTHOR]

Polyethylene-, polyvinylidene chloride-, and per- and polyfluoroalkyl substance-coated paper generate microplastics or fluorochemicals in the environment. Here, we report an approach for the development of oil-resistant papers using an environmentally friendly, fluorine-free, water-dispersible poly(dimethylsiloxane) (PDMS) coating on kraft paper. Carboxylic-functionalized PDMS (PDMS-COOH) was synthesized and subsequently neutralized with ammonium bicarbonate to obtain a waterborne emulsion, which was then coated onto kraft paper. The water resistance of the coated paper was determined via Cobb60 measurements. The Cobb60 value was reduced to 2.70 ± 0.14 g/m2 as compared to 87.6 ± 5.1 g/m2 for uncoated paper, suggesting a remarkable improvement in water resistance. Similarly, oil resistance was found to be 12/12 on the kit test scale versus 0/12 for uncoated paper. In addition, the coated paper retained 70–90% of its inherent mechanical properties, and more importantly, the coated paper was recycled via pulp recovery using a standard protocol with a 91.1% yield. [ABSTRACT FROM AUTHOR]

Sensitizers are used to prepare photosensitive materials for ink-printing and thermal-recording media. Typical sensitizers contain an aromatic ring and exhibit aryl hydrocarbon receptor-mediated activity. They can accumulate in aquatic biota, leading to the disruption of ecosystems. Effluent from paper recycling plants has been identified as a source of contamination, and the presence of sensitizers in toilet paper may represent a new source of contamination in aquatic environments. To examine possible sources of contamination by sensitizers, this study investigated the levels of sensitizers in recycled toilet paper. We also studied the prevalence of sensitizers in rivers receiving effluents from sewage treatment plants in Japan, from 2020 to 2022. We detected eight sensitizers and related compounds in both toilet paper and river water samples; their total concentrations ranged from 0.78 to 34 µg/g (mean: 12 µg/g) in toilet paper and 58–1167 µg/L (median: 77 µg/L) in water. In the water samples, sensitizers were partitioned between liquid and suspended solid phases, and in suspended solids, sensitizers accounted for an average of 42% of the total. Correlation analysis showed a high correlation between sensitizer composition in the water from a river receiving sewage treatment plant effluents and toilet paper. Since these compounds were also detected in the river water analyzed in this study, toilet paper should be considered a novel source of sensitizers contamination in sewage treatment systems. [ABSTRACT FROM AUTHOR]

Due to a shortage of resources, exploring new biomass fillers has become critical for paper making. In this study, we reported an eco-friendly strategy for fabricating low-cost and efficient recycled paper with high mechanical properties using corrugated cardboard waste paper and harmless municipal sludge (HMS). First, the characteristics of HMS, including the particle size, pH, specific surface area, organic functional groups and organic component content, were analyzed. Then, the influence of the amount of HMS on the properties of the recycled paper was studied. Finally, the strengthening mechanism of biomass filling recycled paper was discussed. The results showed that HMS, a biomass filler for recycled paper preparation, exhibited excellent physical and chemical properties, with a median particle size of 6.395 μm, a surface area of 39.974 m2 g−1 and organic functional groups. The tensile index of the recycled paper with 30 % HMS was 13.10 Nm/g, which was 16.4 % greater than that of the unfilled paper and showed better thermal stability. This excellent performance could be attributed to the uniform distribution of HMS on the fiber surface, which improved the accessibility of hydrogen bond formation between fibers. Thus, this study proved that HMS was an excellent biomass filler for producing recycled paper. [ABSTRACT FROM AUTHOR]

• Pulp and paper mill sludge (PPMS) landfill sites have GHG assessment challenges. • GHG fluxes measured by chambers with (F +) and without (F-) a frame were compared. • Flux relationships up to 80 % were shown between F- and F + chambers (the standard) • Correction factors for F- chambers were built to estimate fluxes from F + chambers. • The approach can refine GHG inventories on PPMS landfill sites. Assessments of greenhouse gas (GHG) emissions in managed areas are facing various challenges. A non-flow-through, non-steady-state (NFT-NSS) chamber coupled to a frame permanently inserted into the landfilled substrates is a standard method for quantifying GHG emissions in managed areas, such as pulp and paper mill sludge (PPMS) landfill sites. Frequent measurements are needed to minimize uncertainties on GHG emission factors at the landfill site scale. However, maintaining a frame inserted into the substrates for a long time period is often impossible due to landfilling management operations. Therefore, GHG measurements using NFT-NSS chambers placed directly on substrates' surface could be an interesting option. Our objectives were to determine the relationships between CO 2 , CH 4 , and N 2 O fluxes measured with (F +) and without (F-) a frame inserted in the substrates' surface and to develop correction factors for fluxes measured without a frame. Measurements were made at different PPMS landfill sites in the province of Québec, Canada. Stronger GHG flux relationships were observed at the provincial (across sites) than the specific site scale: the variance in GHG fluxes from F- chambers explained up to 80 % of variance in fluxes from F + chambers. The measured CO 2 , CH 4 , and N 2 O fluxes in F- chambers were on average 53, 78, and 63 % lower, respectively, than those estimated by the models at provincial scale. The correction factors developed with this approach could greatly extend the number of sites where in situ GHG measurements can be done and would help refining GHG inventories at the provincial and national levels. [ABSTRACT FROM AUTHOR]

Objectives: Endoscopic ultrasound‐guided tissue acquisition (EUS‐TA) is used for pathological diagnosis and obtaining samples for molecular testing, facilitating the initiation of targeted therapies in patients with pancreatic cancer. However, samples obtained via EUS‐TA are often insufficient, requiring more efforts to improve sampling adequacy for molecular testing. Therefore, this study investigated the use of oil blotting paper for formalin fixation of samples obtained via EUS‐TA. Methods: This prospective study enrolled 42 patients who underwent EUS‐TA for pancreatic cancer between September 2020 and February 2022 at the Osaka International Cancer Institute. After a portion of each sample obtained via EUS‐TA was separated for routine histological evaluation, the residual samples were divided into filter paper and oil blotting paper groups for analysis. Accordingly, filter paper and oil blotting paper were used for the formalin fixation process. The total tissue, nuclear, and cytoplasm areas of each sample were quantitatively evaluated using virtual slides, and the specimen volume and histological diagnosis of each sample were evaluated by an expert pathologist. Results: All cases were cytologically diagnosed as adenocarcinoma. The area ratios of the total tissue, nuclear, and cytoplasmic portions were significantly larger in the oil blotting paper group than in the filter paper group. The frequency of cases with large amount of tumor cells was significantly higher in the oil blotting paper group (33.3%) than in the filter paper group (11.9%) (p = 0.035). Conclusions: Oil blotting paper can increase the sample volume obtained via EUS‐TA on glass slides and improve sampling adequacy for molecular testing. [ABSTRACT FROM AUTHOR]

Purpose: This paper aims to study the application of high-tolerance and flexible indigenous bacteria and fungi, along with the co-metabolism in recycled paper and cardboard mill (RPCM) wastewater treatment (WWT). Design/methodology/approach: The molecular characterization of isolated indigenous bacteria and fungi was performed by 16S rRNA and 18S rRNA gene sequencing, respectively. Glucose was used as a cometabolic substrate to enhance the bioremediation process. Findings: The highest removal efficiency was achieved for both chemical oxygen demand (COD) and color [78% COD and 45% color removal by Pseudomonas aeruginosa RW-2 (MZ603673), as well as approximately 70% COD and 48% color removal by Geotrichum candidum RW-4 (ON024394)]. The corresponding percentages were higher in comparison with the efficiency obtained from the oxidation ditch unit in the full-scale RPCM WWT plant. Originality/value: Indigenous P. aeruginosa RW-2 and G. candidum RW-4 demonstrated effective capability in RPCM WWT despite the highly toxic and low biodegradable nature, especially with the assistance of glucose. [ABSTRACT FROM AUTHOR]

The increase in energy valorization of paper sludge and biomass waste through incineration results in a rise in waste paper fly ash (WPFA), often perceived as hazardous and requiring specific treatment. In this study, natural carbonation technology at a pilot scale was employed to mitigate the hazardous nature of WPFA by enhancing the stabilization of metal and metalloid trace elements (MMTE), particularly barium (Ba) and lead (Pb) leaching. Natural carbonation of WPFA was found to be optimal at a water/solid ratio of 0.3 L/kg under natural temperature and humidity conditions. Batch leaching tests based on thermodynamic equilibrium were used to assess MMTE solubility concerning pH in both non-carbonated and carbonated WPFA at natural pH. After 7 days of natural carbonation, the leaching concentration of Ba and Pb was below the legal limit in France. The concentration of Ba and Pb in carbonated samples decreased by 98.5% and 98%, respectively. Analyses using thermogravimetry, X-ray diffraction, scanning electron microscopy, and energy-dispersive spectroscopy demonstrated the increased formation and quantity of calcite (CaCO3) with longer carbonation times, along with the formation of new minerals as BaCO3 and PbCO3, confirming the immobilization of these elements post-carbonation. The leaching behavior and release potential of carbonated WPFA were further evaluated using the four-stage sequential extraction procedure proposed by the European Commission's Bureau of Reference (BCR). The speciation of Ba and Pb shifted significantly from the soluble substance (F1) at 17.6% and 14.8%, respectively, to the carbonate fraction (F2) at 0.49% and 0.02% after 90 days of carbonation. The percolation water collected during the carbonation process adheres to discharge standards into the sea. [ABSTRACT FROM AUTHOR]

This report presents an investigation into the use of carbon paper electrodes prepared from chitosan-adhered graphene magnetite nanoparticles for the analysis of Cr(VI). The preparation and storage of carbon paper electrodes is a simple process, and these electrodes are easier to replace than electrodes modified by more conventional methods. The electrochemical detection of Cr(VI) using square wave adsorption cathodic dissolution voltammetry (SWAdCSV) with high selectivity and sensitivity, as well as the optimum conditions for the preparation of the electrodes and the electrode parameters affecting the SWAdCSV signal, were the main points of focus of the investigation. Cr(VI) was detected linearly in the range of 4-40 μg L-1 with a detection limit of 2.84 μg L-1. The electrode output precision, calculated as %RSD, was 7.16% (n = 6), and this was the measurement used for the detection of Cr(VI) in standard and test samples with recoveries between 89% and 114%. The results were consistent with those obtained using the standard UV-Vis spectrophotometric method with a paired t-test at 95% confidence level. [ABSTRACT FROM AUTHOR]

Non-enzymatic electrochemical blood glucose sensors often suffer from issues such as requiring an alkaline environment, limited monitoring range, and poor anti-interference properties. Carbon substrates have been demonstrated to improve the performance of non-enzymatic sensors, but complex and energy-consuming manufacturing processes restrict their use. Herein, a simple and green approach for the preparation of 3D porous Au/Au-Pt networks (PAAPNs) is proposed using tissue paper for recycling as the nanomaterial substrate to deposit Au-Pt bimetallic nanoparticles. The unique structure of the PAAPNs sensor allows for low-potential operation (-1.0 V) with a wide monitoring range (-0.25 to 36 mM) in a neutral environment. Moreover, the sensor exhibited excellent selectivity (<10% response of interference) even without the use of an anti-interference outer membrane. Further investigation using density functional theory (DFT) simulation revealed the synergistic effect between Au and Pt in promoting glucose oxidation. Overall, this work provides a simple and low-carbon footprint method for creating carbon substrates from tissue paper for recycling, offering new opportunities for fabricating novel value-added nanomaterials for medical sensing applications. [ABSTRACT FROM AUTHOR]

This study evaluates the impact of sales promotions that are featured in store flyers distributed by prominent retailers and their capacity to attract consumers to their establishments. A distinctive conceptual framework is introduced that scrutinizes the influence of ethically-minded consumer behavior, digital citizenship/literacy, and a retailer's orientation toward environmental sustainability and explicit ecological concerns. A quasi-experimental design was used to formulate four distinct scenarios from a possible set of eight, stemming from the combinations of three variables: 2 Retailer Positioning (green vs. without explicit ecological claims) × 2 Flyer Mediums (paper vs. digital) × 2 Discount Levels (5% discount vs. 30% discount). Through an online survey, a sample of 269 responses was garnered to gauge consumer reactions to these store flyers, evaluating their attitudes and receptiveness. The findings suggest that attitudes toward paper flyers were more favorable when presented by non-green retailers compared to their green counterparts. This can be attributed to a perceived inconsistency between a green brand positioning and the use of paper flyers. Furthermore, the propensity to transition to digital flyers was notably stronger for green retailers compared to non-green retailers, but this inclination was most pronounced when higher discounts were offered. [ABSTRACT FROM AUTHOR]

Past quantitative studies have shown that most media coverage is of men. Here we ask if the scarce coverage that women get is qualitatively different from that of men. We use computer-coded sentiment scores for 14 million person names covered in 1,323 newspapers to investigate the three-way relationship between gender, fame, and sentiment. Additional large-scale data on occupational categories allow us to compare women and men within the same profession and rank. We propose that as women's fame increases their media coverage becomes negative more quickly when compared to men (a "paper cut"), because their violation of gender hierarchies and social expectations about typical feminine behavior evokes disproportionate scrutiny. We find that while overall media coverage is much more positive for women than for men, this difference disappears and even reverses at higher levels of fame. In encyclopedic sentiment data we find no biographic basis for women's disproportionate decline in media coverage sentiment at high fame, consistent with the conjectured double standard in media discourse. [ABSTRACT FROM AUTHOR]

In the field of book heritage, it is important to develop cleaning/disinfecting treatments that can slow down the degradation of paper to prevent evident and irreversible damage. The objectives of the cleaning treatments are to remove external contaminants and oxidation and decomposition products of the paper, but these processes must not modify the unique characteristics of the book heritage resulting in irreversible changes in the structure of the paper. Recently, several innovative cleaning treatments were developed with the aim of being minimally invasive; however, to assess the effect of these treatments on paper, it is necessary to use a diagnostic non-destructive, rapid, and affordable process. In previous work, we used surface scanning Raman spectroscopy to develop a diagnostic protocol able to follow the aging processes of the paper, discriminating between hydrolysis and oxidation. In this paper, we applied this protocol to study the action of different types of treatments (hydrogel and EUV irradiation), evaluating both their effectiveness and impact on paper parameters. The results reported here demonstrate that the developed in operando diagnostic procedure can follow the changes in the paper structure comparing them to the variability due to the intrinsic inhomogeneity of paper, without sample contact in a rapid and effective way. [ABSTRACT FROM AUTHOR]

Developing cost-effective and stable materials for the electrocatalysis of hydrogen evolution reaction (HER) remains challenging. In this study, efficient catalysts for HER were synthesized by integrating the cobalt and molybdenum oxides via electrodeposition, followed by subsequent sulfurization of the as-prepared oxides using chemical vapor deposition (CVD). This methodology allowed the incorporation of both cobalt and molybdenum components into the catalyst in a single step. The as-synthesized CoSx@MoSx/MoOx-based catalysts exhibited excellent hydrogen production performance in acidic media owing to the presence of Co-S and Mo-S bonds in the hybrid structure. Particularly, CoSx@MoSx/MoOx(90@360) and MoSx@CoOx(180@180) displayed the best HER performances with low overpotentials of 80 mV and 150 mV, respectively. The catalysts were highly stable, with their stability preserved for over 1000 cycles with marginal reduction in overall efficiency. Therefore, these findings suggest the potential of CoSx@MoSx/MoOx and MoSx@CoOx composites as ideal candidates for developing low-cost catalysts for electrochemical hydrogen production. [ABSTRACT FROM AUTHOR]

The cellulose fibers that form washi are longer than those of regular paper made from wood pulp. Hence, the mechanical properties of washi can be higher than those of conventional paper. This study evaluated the magnetic, magnetostrictive, and tensile properties of negative magnetostrictive cobalt ferrite (CoFe2O4) particle dispersed handmade washi (washi−CoFe2O4). The CoFe2O4 additives magnetized the washi, which displayed negative magnetostriction with the fiber direction perpendicular to the magnetic field and in the parallel fiber direction. Concerning the mechanical properties, the washi−CoFe2O4 displayed an elongation of up to 77% after yielding. [ABSTRACT FROM AUTHOR]

Carbon paper is one of the most widely used gas diffusion layer substrate materials due to its stable performance, relatively low cost, and easy for subsequent processing. Water-soluble phenolic resin, which is more ecologically friendly than alcohol-soluble phenolic resin, was used to prepare carbon paper as the precursor of the carbon matrix. And the effect of different resin solution concentrations on the properties of carbon paper was explored. The results showed that the graphitization, electrical conductivity and mechanical properties of carbon paper increased with the increase of resin solution concentration. When the concentration of resin solution was 20 wt%, the performance of carbon paper was relatively optimal. The graphitization of the carbon paper reached 65.45%, the porosity reached 80.74%, the resistance value at 1 MPa pressure was only 7.61 mΩ cm2, the tensile strength was 1.57 MPa, and the elastic modulus was 1210.98 MPa. [ABSTRACT FROM AUTHOR]

Carbon paper as a macroporous substrate of gas diffusion layer in proton exchange membrane fuel cells directly impacts the output performance of cells. In this study, we present a straightforward strategy to improve the overall performance of carbon paper by mixing short/long (6mm/10 mm) chopped carbon fibers at an optimal concentration of phenolic resin. The results show that incorporating longer carbon fibers can increase the porosity, conductivity, gas flux, and mechanical properties of carbon paper. The membrane electrode assembly achieved a peak power density of 1182.61 mW cm−2 at 60% RH using carbon paper with a long carbon fiber content of 40 wt% and an impregnation concentration of 10 wt%. This outperforms commercially available carbon paper. Based on electrochemical impedance spectroscopy results, it was confirmed that our carbon paper had a lower mass transfer resistance of only 32.17 mΩ cm−2 under conditions of 2 A cm−2 and 60% RH. This was due to its sparser three−dimensional network-like pore structure which was created by mixing different lengths (6mm/10 mm) of carbon fibers. This work provides new insights into preparing high−performance carbon papers. • The nature of carbon paper is regulated by mixing short/long (6mm/10 mm) CFs ratio. • The long carbon fiber contents of 20–40 wt% present better physical properties. • The optimal carbon papers can mitigate mass transfer resistance. • MEA composed of the optimal CP shows a higher power density than commercial CP. [ABSTRACT FROM AUTHOR]

A facile method is proposed in this work to prepare a carbon paper (CP) with outstanding properties by doping boron to catalyze graphitization at lower temperature. Boron was introduced into CP by impregnating carbon fiber preform into a boron/phenolic resin/ethanol solution, and then CP was obtained after the consecutive procedures of hot pressing, carbonization, and graphitization. Morphology, microstructure, composition, and physical properties of the doped and undoped CPs were thoroughly investigated via various techniques to exam the effects of boron concentration and graphitization temperature. Furthermore, the boron doped CP was fabricated into fuel cell gas diffusion layer (GDL) and membrane electrode assembly (MEA) to evaluate its performance through the single cell performance. The findings indicated CP doping with 2 wt% boron could lower the graphitization temperature by at least 200 °C. The B-doped GDL had a higher power density in comparison with the undoped GDLs made in our lab or from the commercial brands. • The innovative preparation method for carbon paper with high conductivity. • The effect of boron concentration and graphitization temperature on carbon paper. • The single cell performance of B-doped gas diffusion layer. [ABSTRACT FROM AUTHOR]

Buckypaper (BP), a flexible and porous material, exhibits photovoltaic properties when exposed to light. In this study, we employed radio frequency (RF) sputtering of zinc oxide (ZnO) followed by rapid thermal annealing to enhance the photovoltaic response of BP. We investigated the impact of various sputtering parameters, such as the gas flow ratio of argon to oxygen and deposition time, on the morphology, composition, resistivity, and photovoltaic characteristics of ZnO-modified BP. Additionally, the photovoltaic performance of the samples under different illumination modes and wavelengths was compared. It was found that optimal sputtering conditions—argon to oxygen flow ratio of 1:2, deposition time of 20 min, and power of 100 watts—resulted in a ZnO film thickness of approximately 45 nanometers. After annealing at 400 °C for 10 min, the ZnO-modified BP demonstrated a significant increase in photocurrent and photovoltage, along with a reduction in resistivity, compared to unmodified BP. Moreover, under gradient illumination, the ZnO-modified BP exhibited a photovoltage enhancement of 14.70-fold and a photocurrent increase of 13.86-fold, compared to uniform illumination. Under blue light, it showed a higher photovoltaic response than under other colors. The enhancement in photovoltaic response is attributed to the formation of a Schottky junction between ZnO and BP, an increased carrier concentration gradient, and an expanded light absorption spectrum. Our results validate that ZnO sputtering followed by annealing is an effective method for modifying BP for photovoltaic applications such as solar cells and photodetectors. [ABSTRACT FROM AUTHOR]

Size presses on paper machines are used to apply a solution of a polymer - usually starch - to the surface of the sheet and thereby to increase the stiffness, surface strength, and printing quality of the product. This article reviews publications dealing with the size press equipment, the materials, and factors affecting both the operating efficiency and attributes of the resulting paper. The emergence of film-press equipment (e.g. blademetering size presses) in the 1980s has greatly decreased the frequency of web breaks and increased productivity. Starch technology at the size press, though relatively mature, continues to evolve. By adjustment of starch attributes, solids levels, and incorporating other additives, modern papermakers can tune size press outcomes to meet a range of paper product requirements, including strength, hydrophobicity, and the reduction of air permeability. By application of various synthetic polymers, mineral particles, and even nanocellulose in combination with starch or other base polymers, there is potential to extend the technology to meet a range of future needs for paper products. [ABSTRACT FROM AUTHOR]

The main part of companies in Bulgaria are built, however in the 70s, and upgraded last decade. The country supplies around 80 % of its supplies of paper, paperboard and pulp with own production. Integrated treatment of wastes is a priority for realizing closed life cycle of materials. The aim of the present work is to investigate the composition and other important characteristics of biomass wood ash wasted from paper industry. The correlations and associations among the chemical characteristics are also studied to find some basic trends and important relationships between two similar wastes from different enterprises. It was proved that all samples taken contained Ba, Cr, Mn, Ni, Co, Al, Fe, Cu and Zn far below the legal limits for such type of products. A product has a certain anti-acidic effect. The other positive result was that the content of iron is between 34 to 60 mg per 1 kg dry waste. The microscopic photos confirmed that the particles are close to the nano-size materials. The content of the elements C, N, H is in good quantities and ratios, which is a prerequisite for their use as a soil improver. By the results of this study, it was confirmed that all samples produced as a result of the thermal treatment and final low water content achieved are free from pathogen microorganisms and different weed seeds, affecting the yield and soil sustainability. That allows determining the optimal ratio between the used components with a view to obtain products with desired thermal stability and physico-chemical properties as soil improvers. [ABSTRACT FROM AUTHOR]

Old corrugated container (OCC) pulp was fractionated and it was found that the longer fiber fraction represented 76.54% and the short fiber fraction – 21.3% of the OCC pulp. The fiber length was 1.22 mm for the long fiber fraction and 0.6 mm for the short fiber, which was longer and shorter, respectively, than the fiber length of the whole OCC pulp (0.95 mm). In addition to fibers in pulp, the cellulosic microparticles that pass through a mesh screen or a perforated plate with a hole diameter of 76 μm, called fines, also have an impact on the properties of the final paper product. The fines content in both longer and shorter fiber fractions was lower than in the whole OCC pulp, consequently, drainage resistance (°SR) in the longer fiber fraction decreased to 14 from 21 in the whole OCC pulp. The air permeability and papermaking properties of the longer fiber were higher than those corresponding to the whole OCC and shorter fiber pulp. Therefore, the longer fraction of pulps can be used to manufacture test liner products and the shorter fiber fraction – for fluting paper. [ABSTRACT FROM AUTHOR]

The pulp and paper industry is critical to global industrial and economic development. Recently, India's pulp and paper industries have been facing severe competitive challenges. The challenges have impaired the environmental performance and resulted in the closure of several operations. Assessment and prediction of the performance of the Indian pulp and paper industry using various parameters is a critical task for researchers. This study proposes a framework for performance assessment and prediction based on Data Envelopment Analysis (DEA), Artificial Neural Networks, and Deep Learning (DL) to assist industry administration and decision-making. We presented a case study based on eight industries to demonstrate the methodology's applicability. This study analyses and predicts industry performance based on sample data observations over 30 years. The result suggests the DEA-DL-based efficiency prediction has an overall MSE of 0.08 compared with the actual efficiency. Furthermore, the efficiency rankings are compared between the three techniques. The results suggest that the integrated DEA-DL method is primarily accurate in most scenarios with the actual values. The findings of this study provide a comprehensive analysis of environmental performance for policymakers. [ABSTRACT FROM AUTHOR]

Complex polymers represent a challenge for remediating environmental pollution and an opportunity for microbial‐catalysed conversion to generate valorized chemicals. Members of the genus Streptomyces are of interest because of their potential use in biotechnological applications. Their versatility makes them excellent sources of biocatalysts for environmentally responsible bioconversion, as they have a broad substrate range and are active over a wide range of pH and temperature. Most Streptomyces studies have focused on the isolation of strains, recombinant work and enzyme characterization for evaluating their potential for biotechnological application. This review discusses reports of Streptomyces‐based technologies for use in the textile and pulp‐milling industry and describes the challenges and recent advances aimed at achieving better biodegradation methods featuring these microbial catalysts. The principal points to be discussed are (1) Streptomyces' enzymes for use in dye decolorization and lignocellulosic biodegradation, (2) biotechnological processes for textile and pulp and paper waste treatment and (3) challenges and advances for textile and pulp and paper effluent treatment. [ABSTRACT FROM AUTHOR]

Achieving the desired properties of paper such as strength, durability, and printability remains challenging. Paper mills employ calcium carbonate (CaCO3) as a filler to boost paper's brightness, opacity, and printability. However, weak interaction between cellulose fibers and CaCO3 particles creates different issues in the papermaking industry. Therefore, this study explores the influence of various inorganic additives as crosslinkers such as mesoporous SiO2 nanospheres, TiO2 nanoparticles, h-BN nanoflakes, and hydroxylated h-BN nanoflakes (h-BN-OH) on inorganic fillers content in the paper. They were introduced to the paper pulp in the form of a polyethylene glycol (PEG) suspension to enable bonding between the inorganic particles and the paper pulp. Our findings have been revealed based on detailed microscopic and structural analyses, e.g., transmission and scanning electron microscopy, X-ray diffraction, Raman spectroscopy, and N2 adsorption/desorption isotherms. Finally, the inorganic fillers (CaCO3 and respective inorganic additives) content was evaluated following ISO 1762:2001 guidelines. Conducted evaluations allowed us to identify the most efficient crosslinker (SiO2 nanoparticles) in terms of inorganic filler retention. Paper sheets modified with SiO2 enhance the retention of the fillers by ~12.1%. Therefore, we believe these findings offer valuable insights for enhancing the papermaking process toward boosting the quality of the resulting paper. [ABSTRACT FROM AUTHOR]

Aims: Information on breastfeeding and safety of biologics in infants is lacking due to difficulties in case collection. We evaluated methods for determining the concentration of biologics in breast milk using a dry filter method that can simplify the collection, storage and transport of breast milk. Methods: To generate dried filter paper (DFP) samples, approximately 30 μL of breast milk was placed onto a Whatman 903 card and punched out. After extraction, the supernatant was measured using an enzyme‐linked immunosorbent assay. Three concentrations of each drug were prepared in liquid breast milk (LBM) and DFP samples to determine their stability up to 28 days after storage at 2–8°C or −20°C for LBM and 25 ± 5°C for DFP. LBM and DFP samples were also provided by nursing mothers using biologics during lactation, and drug concentrations in both samples were compared. The agreement between the two measurement methods was confirmed by Bland–Altman analysis. Results: Breast milk was provided by 12 mothers who used biologics (tocilizumab, abatacept, etanercept, golimumab, sarilumab and belimumab). The coefficients of variation for within‐run and between‐run precision for the six drugs were within 15% for both LBM and DFP, and accuracy was within 90%–110% of the quality controls. After 28 days, concentrations remained at more than 90%. The difference between the values obtained by each method was within the acceptable range of error (−12.1 to +16.6 ng/mL). Conclusions: A method for determining the concentration of biologics using DFP is expected to help improve pharmacotherapy for lactating women. [ABSTRACT FROM AUTHOR]

Recycled paper has become increasingly used as a raw material in the paper industry. However, hornification limits its application. Herein, the effect of recycling on the mechanical properties and microstructure of khasi pine pulp was systematically studied. The mechanical properties deteriorated and water retention value decreased after recycling. X-ray diffraction and Fourier-transform infrared spectroscopy revealed that cellulose crystallinity increased and partial cocrystallization occurred on cellulose microfibrils. Through the analysis of the morphology of secondary fibers by FQA, the loss of fine fibers caused by each reuse was found. Using the filtration method to prepare the recycled paper reduced the loss of fine fibers and improved the mechanical properties, with the tensile strength of a sample prepared using a sand core filter unit for five cycles (8.37 MPa) being like that of a sample prepared using a paper machine after one cycle. The investigation of the internal structure of the paper showed that the retained fine fibers were bonded between the long fibers, promoting the bonding between the fibers. Fine fibers improve the curling and twisting of fibers to some extent, especially in the first three recycling cycles. The hornification phenomenon of recycled paper was studied from the viewpoint of the fiber components, which is important to promote the development and application prospect of recycled paper. [ABSTRACT FROM AUTHOR]

Highly cited papers showcase high-quality research and encompass significant themes in the field. This study examined a total of 435 highly cited papers based on Essential Citation Indicators in the Web of Science (WoS) category of sport sciences with a bibliometric method. In particular, the bibliometric indicators of the highly cited papers including publication venues, authors, countries, institutions, and the top cited publications were presented and analyzed in detail. An Abstract corpus was constructed to help identify the most frequently explored topics. VOSviewer was employed to visualize the co-occurrence networks of keywords. The study revealed the trending information of important contributors at the levels of journals, authors, countries, and institutes. The top cited publications can be grouped into three categories: guidelines, recommendations based on systematic reviews, and evaluations. The most frequently explored topics based on the Abstract corpus and the most frequently used keywords from VOSviewer mapping overlap to a great extent. Specifically, topics such as meta-analysis, systematic review, sport-related concussion, sedentary behavior, football, rehabilitation, and osteoarthritis are among the most frequently mentioned. The results provide the most updated publication characteristics and hot topics of highly cited papers in sport sciences and offer insights for academic researchers in future research. [ABSTRACT FROM AUTHOR]

Poly(3-hydroxybutyrate) (PHB), a biodegradable polymer, has been studied as a substitute for petroleum-based polymers used for barrier coating to improve the barrier and mechanical properties of paper. In this study, ethyl cellulose (EC), a cellulose derivative, was used to prepare a polymer blend for enhancing the barrier properties of PHB. The prepared PHB/EC blend was then applied as a paper coating material. Additionally, the barrier and mechanical properties of the PHB/EC blend-coated paper based on the PHB/EC mixing ratio and coating weight were analyzed. The results showed that the EC could act as a binder for the PHB/EC blendcoated paper. Consequently, the PHB/EC blend-coated paper exhibited significant improvements in mechanical and barrier properties, including a substantial increase of over 100% in internal bond strength, more than 20% in tensile strength, exceeding 60% enhancement in water resistance, and a remarkable increase of over 90% in air permeability. [ABSTRACT FROM AUTHOR]

This study evaluated the production of marine biodegradable plastics, specifically polyhydroxyalkanoates (PHAs), using waste paper from food containers as a novel material source. The results showed that adding dilute sulfuric acid as a pretreatment may have a negative impact on enzyme hydrolysis efficiency. Without pretreatment, the highest glucose concentration was observed in the 50-min heating group. In the experimental group with 1% dilute sulfuric acid as a pretreatment, the highest average glucose concentration was observed in the 25-min treatment group. In flask scale experiments, the C/N ratio was controlled at 10, 20, and 30. The results showed that when the C/N ratio was 10, the PHA/CDM ratios were 16.3 and 23.6 at 48 and 72 h, respectively. After 96 h of cultivation using hydrolysis liquid from the waste paper container as the sole carbon source in a 5-L scale experiment, the PHA/CDM ratio was 28.7 and the PHA concentration was 0.95 g/L. The potential bacterial strain in this study was confirmed to be a Bacillus genus bacterium after strain identification. The signal peaks indicated that the PHA obtained from the Bacillus sp. production process was PHB. [ABSTRACT FROM AUTHOR]

The flame spread behavior over a filter paper in opposed flow was investigated on the ISS/Kibo, and the results were compared with the flammability map predicted in advance by scale analysis for a two-dimensional flame. The on-orbit experiments were conducted in the solid combustion experimental module (SCEM) as the first combustion test of the FLARE project by JAXA. A filter paper with a length of 130 mm, a width of 40 mm or 20 mm, and a thickness of 0.12 mm was used as the specimen. The opposed flow velocity and the oxygen concentration were varied from 0 cm/s to 25 cm/s, and from 13.5% to 34%, respectively. The ambient pressure is 101.3 kPa. The predicted limiting curve reasonably agreed with the minimum limiting oxygen concentration observed. On the other hand, in extremely slow flows, very robust flames were observed beyond the limiting curve. When the condition reached the limit of two-dimensional flame, the flame front changed from a linear shape to a spherical shape (flamelet) to shorten the preheat zone length, reducing the radiative heat loss to survive. In these cases, the flamelet was sustained for a long time (> 100 s), and a large amount of decomposed gas was released at the periphery of the pyrolysis zone generating a combustible vapor cloud around the spherical flame font. The presence of a long-life robust flamelet and the accumulation of such combustible mist can be fire hazards in microgravity. [ABSTRACT FROM AUTHOR]

Nowadays, the emphasis is on increasing the durability of all products. For this reason, it is also advisable to look into extending the durability of paper products. The main reason for using flax pulp is that flax and cotton pulp are widely used for the production of banknotes due to their higher strength. This paper deals with flax pulp with the addition of nanocellulose, which should further enhance the mechanical properties of the pulp. The tensile strength, breaking length, and tensile energy absorption index were evaluated as the key mechanical properties. At the same time, the effect of the addition of nanocellulose, whether it was added to the pulp mass or applied to the later produced paper as a spray or coating, was tested in comparison to paper without the addition of nanocellulose. The best mechanical properties, i.e., tensile strength, were achieved for the highest addition of 5% of nanocellulose into the pulp, at 24.3 Nm∙g−1, and for the coating application, at 28.7 Nm∙g−1, compared to the flax pulp without the addition, where the tensile strength was 20.5 Nm∙g−1. The results of this research are used for the assessment of nanocellulose as a natural compatible additive to enhance the strength properties of cellulose-based materials. [ABSTRACT FROM AUTHOR]

Though paper is an environmentally friendly alternative to plastic as a packaging material, it lacks antibacterial properties, and some papers have a low resistance to oil or water. In this study, a multifunctional paper-coating material was developed to reduce the use of plastic packaging and enhance paper performance. Natural cellulose nanocrystals (CNCs) with excellent properties were used as the base material for the coating. The CNCs were functionalized into dialdehyde CNCs (DACNCs) through periodate oxidation. The DACNCs were subsequently complexed using erythrosine as a photosensitizer to form an erythrosine–CNC composite (Ery-DACNCs) with photodynamic inactivation. The Ery-DACNCs achieved inactivations above 90% after 30 min of green light irradiation and above 85% after 60 min of white light irradiation (to simulate real-world lighting conditions), indicating photodynamic inactivation effects. The optimal parameters for a layer-by-layer dip coating of kraft paper with Ery-DACNCs were 4.5-wt% Ery-DACNCs and 15 coating layers. Compared to non-coated kraft paper and polyethylene-coated paper, the Ery-DACNC-coated paper exhibited enhanced mechanical properties (an increase of 28% in bursting strength). More than 90% of the bacteria were inactivated after 40 min of green light irradiation, and more than 80% were inactivated after 60 min of white light irradiation. [ABSTRACT FROM AUTHOR]

Development of low-cost, efficient, and stable oxygen evolution electrocatalysts is crucial for the conversion and storage of renewable energy. Therefore, an effective integrated heterostructure catalyst is needed to achieve a lower overpotential during oxygen evolution process. In this paper, cobalt-zinc bimetallic MOF precursors are used as templates to prepare bimetallic cobalt-based selenides with good oxygen evolution catalytic activity and stability on carbon fiber paper. Due to the high specific surface area and porous structure of the coupling structure of nanorods and polyhedra, and the strong electronic coupling between CoSe 2 and ZnSe on nanorods. CoSe 2 -ZnSe/CP exhibits excellent electrocatalytic activity in 1 M KOH solution. It only requires an overpotential of 275 mV to reach the current density of 10 mA cm-2, and the Tafel slope is 68.9 mV dec-1. In addition, after 12 h of continuous operation of CoSe 2 -ZnSe/CP, the activity decay of the catalyst is negligible. This work provides a method for the design of heterogeneous bimetallic selenide integrated oxygen evolution electrocatalysts. [Display omitted] • The CoSe 2 -ZnSe/CP catalyst is obtained by selenization of MOF precursor at high temperature. • The catalyst has unique nanorod-coupled polyhedral morphology and high specific surface area. • The strong electron coupling between CoSe 2 and ZnSe improves the oxygen evolution activity. • CoSe 2 -ZnSe/CP exhibits low overpotential, high exchange current density and fast kinetics. [ABSTRACT FROM AUTHOR]

Georgia Brady Barnhill's book, "Gems of Art on Paper: Illustrated American Fiction and Poetry, 1765–1885," provides a comprehensive and detailed account of the growth of illustrated American fiction and poetry. Barnhill explores the development of the illustration industry, from early experiments to technological advancements, and the evolution of illustrators and craftspeople. The book focuses on a neglected period of book illustration and offers a holistic view of mainstream literary illustration, discussing specific editions, illustration technologies, and important creators. Barnhill's work is a valuable resource for scholars and researchers interested in the history of book illustration in America. [Extracted from the article]

Carbon paper is commonly used for catalytic electrode preparation because of its high conductivity, corrosion resistance, and stability. However, traditional electrode preparation methods are inappropriate for highly hydrophobic carbon paper. In this paper, a high‐activity carbon paper catalytic electrode was prepared using multistrategies cold plasma modification to create atomic structural defects, dope N and Cu elements, and introduce oxygen‐containing functional groups. Analyses show that the bombardment of high‐energy particles caused atomic structural defects. Nitrogen and copper entered the carbon paper through plasma‐induced chemical recombination and physical adsorption, reaching 5.26% and 3.83%, respectively. Ethanol‐based plasma introduced oxygen‐containing functional groups to improve hydrophilicity. Finally, the plasma‐prepared electrode exhibited a reduction efficiency of 87.69% in an electrocatalytic nitrate reduction reaction. [ABSTRACT FROM AUTHOR]

The solar photocatalytic degradation of pulp and paper mill wastewater has been reported by several scientists. However, this is the first time we are reporting for solar photocatalytic hydrogen production from pulp and paper mill wastewater and simultaneous degradation of pollutants. In this work, CuO based photocatalysts and novel square type photocatalytic reactor of 5 L capacity were used. The result shows that the prepared photocatalysts are solar active, efficient in hydrogen recovery and pollutant degradation from the pulp and paper wastewater. The effects of catalyst loading, sacrificial agent, pollutant removal efficiency and stability check were investigated. At 0.25 g/L of CuO/Fe 2 O 3 , 0.2 M of sacrificial agent (Na 2 SO 3 2−) and hydrogen yield of 1000 mL from 1000 mL of wastewater was achieved. The removal efficiency of TSS, TDS, BOD, COD, turbidity and TOC are around 70, 50, 60, 65, 70 and 45% respectively. Reusability study revealed that CuO/Fe 2 O 3 was chemically stable and could be reused successively (five cycles) without significant changes in its photoactivity and intrinsic properties. [Display omitted] • Visible light active CuO mixed with novel metal oxides were employed. • Hydrogen recovery from black liquor, paper mill wastewater were 1000 mL/h/L and 850 mL/h/L. • Efficiency of degradation of pulp & paper wastewater chemicals were around 50–70%. • AcHieved high recovery of hydrogen from pulp & paper wastewater. [ABSTRACT FROM AUTHOR]

Due to the high wastepaper recyclability and water-loop system closure, packaging paper mills struggle with increased fines, causing runnability issues. Cellulase enzymes are a preferred treatment choice for the improvement of the pulp refining in stock preparation area but are not widely used or easy to introduce in the production process. Different cellulase enzymes were tested, and those with the highest activity were introduced to the white-water (WW) samples with the aim to reduce fines content as potentially new enzyme applications on the paper machine. The first portion of the study involved the development of an experiment model to find and confirm the optimal enzyme process parameters (40 °C, pH 5.7, reaction time 3 h, and 0.18%v/v enzyme addition) for laboratory made white-water. The second portion of the study included turbidity, colloidal charge, flow cytometry (FCM), and chemical oxygen demand (COD) analysis on industrial and laboratory made white-water samples at optimized process parameters. Obtained results corresponded to reduced fines content in white-water samples, which justified commercial usage of cellulase enzymes on recycled paper machine short loop and potentially increased machine runnability without negative influence on wastewater treatment plant. [ABSTRACT FROM AUTHOR]

In this paper, by a simple hydrothermal method vertically aligned ZnO nanorod arrays were grown on the carbon fiber paper (CFP) and then through a facile chemical bath deposition method CuO nanosheets were loaded on ZnO nanorod arrays, following by thermal spraying method, carboxylated carbon nanotubes (CCNTs) were successfully integrated with CuO/ZnO@CFP to form a binder-free CuO/ZnO-CCNT@CFP sensor. The sensor shows enhanced sensing activity for baicalein and luteolin determination due to the improved structural integration and synergism of different electrode material components. Remarkably, the CuO/ZnO-CCNT@CFP sensor showed good linear relationships over wide concentration ranges of 0.03–0.70 µM and 0.70–20 µM for baicalein and 0.03–0.45 µM and 0.45–8.5 µM for luteolin detection, with the detection limits of 1.7 nM for baicalein and 0.5 nM for luteolin, respectively. More importantly, the CuO/ZnO-CCNT@CFP sensor was utilized in the simultaneous determination of baicalein and luteolin, delivering linear ranges of 0.4–14 µM (baicalein) and 0.2–6 µM (luteolin) with the limit of detection of 0.05 µM and 0.03 µM, respectively. In addition, the developed CuO/ZnO-CCNT@CFP electrode was further investigated to detect baicalein and luteolin in traditional herbal medicine samples, showing satisfied results in comparison with analytic results from high performance liquid chromatography. [ABSTRACT FROM AUTHOR]

Enzymes derived from microbial sources have gained increasing popularity in industrial applications over the past decades. Despite the high production cost, alkaline proteases have wide applications in industries such as tanneries, food production, and detergents. In recent years, there has been a shift towards utilizing natural carbon sources for cultivating microorganisms and extracting proteases in order to reduce production costs. This study aimed to investigate the biochemical and kinetic properties of protease enzymes obtained from Aspergillus niger cultivated in a paper waste medium and compare with the enzyme produced in a basal medium. Glucose is a more favorable carbon source compared to cellulose, so paper waste was pretreated with cellulose-degrading bacteria to convert cellulose into smaller carbohydrates. After the growth of A. niger in basal and combinational media, the enzymatic properties were compared between the extracted enzymes by using casein as substrate. The results demonstrated that A. niger could produce protease enzymes in the paper waste medium similar to the basal medium with more than 5-fold cost saving. The specific activity of the enzymes isolated from the basal and paper waste media was calculated to be 184.95 ± 10.56 U ml−1 and 169.88 ± 11.05 U ml−1, respectively. Carbon sources did not affect the optimum pH and temperature of the protease enzyme, which were found to be 8 and 37 °C, respectively. This study provides valuable insights into the production of alkaline protease from A. niger using a combinational medium (paper waste pretreated by cellulose-degrading bacteria), offering a cost-effective approach for industrial applications. [ABSTRACT FROM AUTHOR]

Background: The mobile device diffusion has increasingly highlighted the opportunity to collect patient-reported outcomes (PROs) through electronic patient-reported outcomes measurements (ePROMs) during the clinical routine. Despite the ePROMs promises and advantages, the equivalence when a PRO measure is moved from the original paper-and-pencil to the electronic version is still little investigated. This study aims at evaluating equivalence between PROMs and ePROMs self-administration in people with multiple sclerosis (PwMS); in addition, preference of self-administration type was evaluated. Methods: The Manual Ability Measure-36 (MAM-36) and Fatigue Severity Scale (FSS) were selected for the equivalence test. The app ABOUTCOME was developed through a user-centered design approach to administer the questionnaires on tablet. Both paper-and-pencil and electronic versions were randomly self-administered. Intrarater reliability between both versions was evaluated through the intraclass correlation coefficient (ICC, excellent for values ≥ 0.75). Results: Fifty PwMS (35 females) participated to the study (mean age: 54.7±11.0 years, disease course: 27 relapsing-remitting and 23 progressive; mean EDSS: 4.7±1.9; mean disease duration: 13.3±9.5 years). No statistically significant differences were found for the means total scores of MAM-36 (p = 0.61) and FSS (p = 0.78). The ICC value for MAM-36 and FSS was excellent (0.98 and 0.94, respectively). Most of participants preferred the tablet version (84%). Conclusion: The results of the study provide evidence about the equivalence between the paper-and-pencil and electronic versions of PROs administration. In addition, PwMS prefer electronic methods rather than paper because the information can be provided more efficiently and accurately. The results could be easily extended to other MS PROs. [ABSTRACT FROM AUTHOR]

Cellulose was isolated from recycled pulp and paper sludge and used to synthesize cellulose nanocrystals. Response surface methodology and Box-Behnken design model were used to predict, improve, and optimize the cellulose isolation process. The optimal conditions were a reaction temperature of 87.5 °C, 180 min with 4% sodium hydroxide. SEM and TEM results revealed that the isolated cellulose had long rod-like structures of different dimensions than CNCs with short rod-like structures. The crystallinity index from XRD significantly increased from 41.33%, 63.7%, and 75.6% for Kimberly mill pulp sludge (KMRPPS), chemically purified cellulose and cellulose nanocrystals, respectively. The TGA/DTG analysis showed that the isolated cellulosic materials possessed higher thermal stability. FTIR analysis suggested that the chemical structures of cellulose and CNCs were modified by chemical treatment. The cellulose surface was highly hydrophilic compared to the CNCs based on the high water holding capacity of 65.31 ± 0.98% and 83.14 ± 1.22%, respectively. The synthesized cellulosic materials portrayed excellent properties for high-end industrial applications like biomedical engineering, advanced materials, nanotechnology, sustainable packaging, personal care products, environmental remediation, additive manufacturing, etc. [ABSTRACT FROM AUTHOR]

Industrial waste locks are used as raw materials to reduce harmful effects on the environment and improve environmental performance. Marble clay powder can be used as a filling aid and can fill voids in concrete structures. This article will show you how to use a maximum natural sand alternative in concrete with marble powder and quarry dust. The challenge of the 21st century is to change to a new form that can support the natural system. This necessitates a radical rethinking of how to give the community infrastructure and housing. Making a concerted effort to develop novel, innovative, and alternative construction materials may be necessary. Jungles of concrete around cause's impact on the Environment and it would result in climate change. Mankind must avoid the use of things that are detrimental to the environment. So in this paper, it is decided to address the issue by adopting the use of the green concrete concept which is environmentally friendly. Green concrete is concrete made up using industrial wastes such as marble powder, quarry dust, wood ash, paper pulp, etc. Green concrete, which is capable of sustainable development, helps to reduce the consumption of natural resources, energy use, and environmental pollution. Green concrete is more cost‐effective than ordinary concrete and reduces the cost of resultant concrete by 14%–20%. It is also observed that the alkali‐aggregate reaction and sulfate attack resistance of concrete are both significantly improved. Green concrete is a useful tool for lowering environmental pollution and enhancing concrete's resistance to harsh conditions. All stages of infrastructure construction and rehabilitation will follow this trend of using new cement and techniques. Green concrete's adaptability and its performance derivatives will meet a variety of future needs. [ABSTRACT FROM AUTHOR]