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Rocket kerosene plays an important role in the regenerative cooling process of rocket thrust chambers. Its thermal conductivity determines the cooling efficiency and the tendency to coke in rocket kerosene engines. In this paper, graphene nanoplatelets (GNPs) were introduced into rocket kerosene to improve its thermal conductivity. Molecular dynamics simulation was used to investigate the thermal conductivity of the composite system and its underlying thermal conductivity mechanism. Firstly, by studying the effect of the mass fraction of GNPs, it was found that, when the graphene mass fraction increases from 1.14% to 6.49%, the thermal conductivity of the composite system increases from 4.26% to 17.83%, which can be explained by the percolation theory. Secondly, the influence of the size of GNPs on the thermal conductivity of the composite system was studied. Basically, the thermal conductivity was found to increase by increasing the aspect ratio of GNPs, indicating that GNPs with a higher aspect ratio are more conducive to improving the thermal conductivity of rocket kerosene. By carefully analyzing the effect of the size of GNPs on thermal conductivity, it was concluded that the thermal conduction enhancement by adding GNPs is determined by the combined effect of the percolation theory and the Brownian motion. The results of the temperature effect study showed that the ratio of thermal conductivity to rocket kerosene increased from 1.16 to 1.26 and from 1.07 to 1.11 for the composite systems, with graphene sizes of 41.18 Å × 64.00 Å and 24.14 Å × 17.22 Å in the temperature range of 293 K to 343 K, respectively. It is further proved that the Brownian motion of GNPs has a non-negligible effect on the thermal conductivity of the composite system. This work provides microscopic insights into the thermal conduction mechanism of GNPs in nanofluids and will offer practical guidance for improving the thermal conductivity of rocket kerosene. [ABSTRACT FROM AUTHOR]

Nowadays, many types of materials are elaborated for microwave absorption applications. Carbon-based nanoparticles belong to these types of materials. Among these, graphene presents some distinctive features for electromagnetic radiation absorption and thus microwave isolation applications. In this paper, the dielectric characteristics and microwave absorption properties of epoxy resin loaded with graphene particles are presented from 2 GHz to 18 GHz. The influence of various parameters such as particle size (3 µm, 6-8 µm, and 15 µm) and weight ratio (from 5% to 25%) are presented, studied, and discussed. The sample loaded with the smallest graphene size (3 µm) and the highest weight ratio (25%) exhibits high loss tangent (tanδ = 0.36) and a middle dielectric constant ε' = 12-14 in the 8-10 GHz frequency range. As expected, this sample also provides the highest absorption level: from 5 dB/cm at 4 GHz to 16 dB/cm at 18 GHz. [ABSTRACT FROM AUTHOR]

Carbon is one of the most abundant elements on Earth. In addition to the well-known crystallographic modifications such as graphite and diamond, other allotropic carbon modifications such as graphene-based nanomaterials and carbon nanotubes have recently come to the fore. These carbon nanomaterials can be designed to help deliver or target drugs more efficiently and to innovate therapeutic approaches, especially for cancer treatment, but also for the development of new diagnostic agents for malignancies and are expected to help combine molecular imaging for diagnosis with therapies. This paper summarizes the latest designed drug delivery nanosystems based on graphene, graphene quantum dots, graphene oxide, reduced graphene oxide and carbon nanotubes, mainly for anticancer therapy. [ABSTRACT FROM AUTHOR]

This paper investigates the utilization of commercial masterbatches of graphene nanoplatelets to improve the properties of neat polymer and wood fiber composites manufactured by conventional processing methods. The effect of aspect ratio of the graphene platelets (represented by the different number of layers in the nanoplatelet) on the properties of high-density polyethylene (HDPE) is discussed. The composites were characterized for their mechanical properties (tensile, flexural, impact) and physical characteristics (morphology, crystallization, and thermal stability). The effect of the addition of nanoplatelets on the thermal conductivity and diffusivity of the reinforced polymer with different contents of reinforcement was also investigated. In general, the mechanical performance of the polymer was enhanced at the presence of either of the reinforcements (graphene or wood fiber). The improvement in mechanical properties of the nanocomposite was notable considering that no compatibilizer was used in the manufacturing. The use of a masterbatch can promote utilization of nano-modified polymer composites on an industrial scale without modification of the currently employed processing methods and facilities. [ABSTRACT FROM AUTHOR]

Graphene-based materials are widely studied to enable significant improvements in electroanalytical devices requiring new generations of robust, sensitive and low-cost electrodes. In this paper, we present a direct one-step route to synthetize a functional nitrogen-doped graphene film onto a Ni-covered silicon electrode substrate heated at high temperature, by pulsed laser deposition of carbon in the presence of a surrounding nitrogen atmosphere, with no post-deposition transfer of the film. With the ferrocene methanol system, the functionalized electrode exhibits excellent reversibility, close to the theoretical value of 59 mV, and very high sensitivity to hydrogen peroxide oxidation. Our electroanalytical results were correlated with the composition and nanoarchitecture of the N-doped graphene film containing 1.75 at % of nitrogen and identified as a few-layer defected and textured graphene film containing a balanced mixture of graphitic-N and pyrrolic-N chemical functions. The absence of nitrogen dopant in the graphene film considerably degraded some electroanalytical performances. Heat treatment extended beyond the high temperature graphene synthesis did not significantly improve any of the performances. This work contributes to a better understanding of the electrochemical mechanisms of doped graphene-based electrodes obtained by a direct and controlled synthesis process. [ABSTRACT FROM AUTHOR]